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Safety Data Sheet EN

LEAD ACID BATTERIES: DEEP CYCLE & INDUSTRIAL

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LEAD ACID BATTERIES: DEEP CYCLE & INDUSTRIAL
Synonyms
Industrial Battery, Traction Battery, Stationary Battery, Deep Cycle Battery

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Batteries, wet, filled with acid

Manufacturers & Suppliers

CROWN BATTERY MANUFACTURING COMPANY logo

CROWN BATTERY MANUFACTURING COMPANY

manufacturer

P.O. Box 990 1445 Majestic Drive, Fremont Ohio, 43420

419.334.7181

http://www.crownbattery.com

Emergency Contacts

CHEMTREC

800.424.9300

CHEMTREC

703.527.3887

CANUTEC

613.996.6666

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Toxicity (Oral/Dermal/Inhalation) Cat. 4
Skin Corrosion/Irritation Cat. 1A
Eye Damage Cat. 1
Reproductive Cat. 1A
Carcinogenicity (lead compounds) Cat. 1B
Carcinogenicity (arsenic) Cat. 1A
Carcinogenicity (acid mist) Cat. 1A
Specific Target Organ Toxicity (repeated exposure) Cat. 2
Aquatic Chronic 1
Aquatic Acute 1
Explosive Chemical Cat. 3

GHS Pictograms

GHS01 - Explosive

GHS01

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H203 Explosive, fire, blast or projection hazard
H302 + H312 + H332 Harmful if swallowed, inhaled, or in contact with skin.
H314 Acid causes severe skin burns and eye damage.
H314 Contact with internal components may cause irritation or severe burns.
H318 Causes skin irritation, serious eye damage.
H335 Irritating to eyes, respiratory system, and skin.
H350 May cause cancer if ingested or inhaled.
H360 May damage fertility or the unborn child if ingested or inhaled.
H362 May cause harm to breast-fed children.
H372 Causes damage to central nervous system, blood and kidneys through prolonged or repeated exposure if ingested or inhaled.
May form explosive air/gas mixture during charging.

Precautionary Statements

P102 Keep out of reach of children.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 No smoking
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P263 Avoid contact during pregnancy/while nursing.
P264 Wash thoroughly after handling.
P264 Avoid contact with internal acid.
P270 Do not eat drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing, eye protection/face protection.
P303 Rinse skin with water/shower.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER or doctor/physician.
P312 Call a poison center/doctor if you feel unwell.
P314 If exposed/concerned, or if you feel unwell seek medical attention/advice.
P330 IF SWALLOWED OR CONSUMED: rinse mouth.
P331 Do NOT induce vomiting.
P338 Remove contact lenses, if present and easy to do.
P338 Continue rinsing.
P351 IF IN EYES: Rinse cautiously with water for several minutes.
P361 + P364 IF ON CLOTHING OR SKIN (or hair): Remove/Take off immediately all contaminated clothing and wash it before reuse.
P405 Store locked up, in a well-ventilated area, in accordance with local and national regulation.
P501 Dispose of contents/container in accordance with local and national regulation.
Keep away from heat/sparks/open flames/hot surfaces.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Lead and Lead Compounds 7439-92-1 50 - 75% No
Antimony 7440-36-0 0.1% No
Sulfuric Acid 7664-93-9 5 - 15% No
Inert Components (Separator Material) --- 1 - 2% No
Water 7732-18-5 23 - 25% No
Arsenic 7440-38-2 0.1% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Sulfuric Acid: Remove to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Consult a physician. Lead: Remove from exposure, gargle, wash nose and lips; consult physician.

Skin contact

Sulfuric Acid: Flush with large amounts of water for at least 15 minutes; remove contaminated clothing completely, including shoes. If symptoms persist, seek medical attention. Wash contaminated clothing before reuse. Discard contaminated shoes. Lead: Wash immediately with soap and water.

Eye contact

Sulfuric Acid and Lead: Flush immediately with large amounts of water for at least 15 minutes while lifting lids; Seek immediate medical attention if eyes have been exposed directly to acid.

Ingestion

Sulfuric Acid: Give large quantities of water; Do NOT induce vomiting or aspiration into the lungs may occur and can cause permanent injury or death; consult physician. Lead: Consult physician immediately.

Immediate Medical Attention

Consult a physician for inhalation, ingestion, and if symptoms persist after skin contact. Seek immediate medical attention if eyes have been exposed directly to acid.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2; foam; dry chemical. Use appropriate media for surrounding fire

Unsuitable media

Do not use carbon dioxide directly on cells.

Specific hazards

Highly flammable hydrogen gas is generated during charging and operation of batteries. If ignited by burning cigarette, naked flame or spark, may cause battery explosion with dispersion of casing fragments and corrosive liquid electrolyte.

Instructions

Use positive pressure, self-contained breathing apparatus. Beware of acid splatter during water application. If batteries are on charge, shut off power to the charging equipment, but note that strings of series connected batteries may still pose risk of electric shock even when charging equipment is shut down.

Firefighter Protection

Wear acid-resistant clothing, gloves, face and eye protection.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Stop flow of material, contain/absorb small spills with dry sand, earth or vermiculite. Do not use combustible materials. If possible, carefully neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc.

Small spill

contain/absorb small spills with dry sand, earth or vermiculite

Environmental

Do not allow discharge of un-neutralized acid to sewer.

Cleanup methods

neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc.

Materials: soda ash, sodium bicarbonate, lime

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Unless involved in recycling operations, do not breach the casing or empty the contents of the battery. Handle carefully and avoid tipping, which may allow electrolyte leakage. There may be increasing risk of electric shock from strings of connected batteries. Keep containers tightly closed when not in use. If battery case is broken, avoid contact with internal components. Keep vent caps on and cover terminals to prevent short circuits. Place cardboard between layers of stacked automotive batteries to avoid damage and short circuits. Keep away from combustible materials, organic chemicals, reducing substances, metals, strong oxidizers and water. Use banding or stretch wrap to secure items for shipping.

Storage

Store batteries under roof in cool, dry, well-ventilated areas separated from incompatible materials and from activities that may create flames, spark, or heat.

Hygiene

Wear face and eye protection when near batteries being charged.

Fire prevention

Prohibit smoking and avoid creation of flames and sparks nearby.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Store and handle in well-ventilated area. If mechanical ventilation is used, components must be acid-resistant. Handle batteries cautiously, do not tip to avoid spills. Make certain vent caps are on securely. Charge batteries in areas with adequate ventilation. General dilution ventilation is acceptable.

Hands

If battery case is damaged, use rubber or plastic acid-resistant gloves with elbow-length gauntlet.

Eyes

Wear protective clothing, eye and face protection, when filling, charging or handling batteries. If battery case is damaged, use chemical goggles or face shield. Chemically impervious apron and face shield recommended when adding water or electrolyte to batteries.

Respiratory

None required under normal conditions. When concentrations of sulfuric acid mist are known to exceed PEL, use NIOSH or MSHA-approved respiratory protection.

Skin/Body

If battery case is damaged, use rubber or plastic acid-resistant gloves with elbow-length gauntlet, acid-resistant apron, clothing and boots. Chemically impervious apron and face shield recommended when adding water or electrolyte to batteries.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Manufactured article; no apparent odor. Electrolyte is a clear liquid with a sharp, penetrating, pungent odor.
Colour
---
Colour Intensity
---
Form
---
Odor
sharp, penetrating, pungent odor
Odor Threshold
---
Ph
~1 to 2
Melting Point
---
Boiling Point
203 - 240° F
Flash Point
Below room temperature (as hydrogen gas)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Less than 1
Vapor Pressure
10 mm Hg
Vapor Density
Greater than 1
Relative Density
1.215 to 1.350
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
74.2% (Hydrogen)
Lower Explosive Limit
4.1% (Hydrogen)
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
100%
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

This product is stable under normal conditions at ambient temperature.

Hazardous reactions

Will not occur.

Avoid

Prolonged overcharge at high current; sources of ignition.

Incompatible

Electrolyte: combustibles, organic materials, strong reducing agents, metals, sulfur trioxide gas, strong oxidizers, and water. Lead Compounds: strong acids, bases, halides, halogenates, potassium nitrate, permanganate, peroxides, nascent hydrogen, and reducing agents. Arsenic Compounds: Strong oxidizers; bromine azide.

Decomposition

Electrolyte: Sulfur Trioxide, Sulfuric Acid Mist, Sulfur Dioxide and Hydrogen Sulfide. Lead Compounds: toxic metal fume, vapor, or dust; arsine gas.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2794
Shipping Name
Batteries, wet, filled with acid
Transport Class
8
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is LEAD ACID BATTERIES: DEEP CYCLE & INDUSTRIAL known by?

LEAD ACID BATTERIES: DEEP CYCLE & INDUSTRIAL is also known as: Industrial Battery, Traction Battery, Stationary Battery, Deep Cycle Battery

What is the hazard signal word for LEAD ACID BATTERIES: DEEP CYCLE & INDUSTRIAL?

The signal word is danger.

What is the physical form of LEAD ACID BATTERIES: DEEP CYCLE & INDUSTRIAL?

LEAD ACID BATTERIES: DEEP CYCLE & INDUSTRIAL is a liquid appearing as manufactured article; no apparent odor. electrolyte is a clear liquid with a sharp, penetrating, pungent odor. . It has sharp, penetrating, pungent odor odor.

What is LEAD ACID BATTERIES: DEEP CYCLE & INDUSTRIAL used for?

Batteries, wet, filled with acid

What are the hazard statements for LEAD ACID BATTERIES: DEEP CYCLE & INDUSTRIAL?

This substance has 11 hazard statements:

  • H203: Explosive, fire, blast or projection hazard
  • H302 + H312 + H332: Harmful if swallowed, inhaled, or in contact with skin.
  • H314: Acid causes severe skin burns and eye damage.
  • H314: Contact with internal components may cause irritation or severe burns.
  • H318: Causes skin irritation, serious eye damage.
  • H335: Irritating to eyes, respiratory system, and skin.
  • H350: May cause cancer if ingested or inhaled.
  • H360: May damage fertility or the unborn child if ingested or inhaled.
  • H362: May cause harm to breast-fed children.
  • H372: Causes damage to central nervous system, blood and kidneys through prolonged or repeated exposure if ingested or inhaled.
  • May form explosive air/gas mixture during charging.