TUDALEN 4529

Remove casualty to a quiet and well ventilated place if safe to do so. Obtain medical assistance if breathing remains difficult. If casualty is unconscious and not breathing: Ensure that there is no obstruction to breathing and give artificial respiration by trained personnel. If necessary, give external cardiac massage and obtain medical advice. If casualty is unconscious and breathing, place in the recovery position. Administer oxygen if necessary.

Symptoms: irritation of the respiratory tract due to excess fume, mists or vapour exposure.

Remove contaminated clothing, contaminated footwear and dispose of safely. Seek medical attention if skin irritation, swelling or redness develops and persists. When using high-pressure equipment, injection of product can occur. If high-pressure injuries occur, immediately seek professional medical attention. Do not wait for symptoms to develop. Do not put ice on the burn. Remove non-sticking garments carefully. DO NOT attempt to remove portions of clothing glued to burnt skin but cut round them. For minor thermal burns, cool the burn. Hold the burned area under cold running water for at least five minutes, or until the pain subsides. Body hypothermia must be avoided. Seek medical attention in all cases of serious burns. Wash affected area with soap and water. May cause burn in case of contact with product at high temperature.

Symptoms: dry skin, irritation in case of repeated or prolonged exposure.

If hot product is splashed into the eye, it should be cooled down immediately to dissipate heat, under cold running water for at least 5 minutes. Immediately obtain specialist medical assessment and treatment for the casualty. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. If irritation, blurred vision or swelling occurs and persists, obtain medical advice from a specialist.

Symptoms: slight irritation. May cause burn in case of contact with product at high temperature.

Do not give anything by mouth to an unconscious person. If vomiting occurs, the head should be kept low so that the vomit does not enter the lungs (aspiration). Once vomiting ceases, place the person in the recovery position with the legs slightly raised. Always assume that aspiration has occurred. Seek professional medical attention or send the casualty to a hospital. Do not wait for symptoms to develop. Do not induce vomiting.

Symptoms: few or no symptoms expected. If any, nausea and diarrhoea might occur.

Foam (trained personnel only). Water fog (trained personnel only). Dry chemical powder. Carbon dioxide. Other inert gases (subject to regulations). Sand or earth.

Do not use direct water jets on the burning product; they could cause splattering and spread the fire. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.

Incomplete combustion is likely to give rise to a complex mixture of airborne solid and liquid particulates, gases, including carbon monoxide + unidentified organic and inorganic compounds.

Stop or contain leak at the source if this possible without risk. Avoid direct contact with released material. Stay upwind. Keep non-involved personnel away from the area of spillage. Alert emergency personnel.

Normal antistatic working clothes. In case of small spillages in closed waters (i.e. ports), contain product with floating barriers or other equipment.

Full body suit of chemically resistant and antistatic material. Cautiously covered with foam, if available, to limit fire risk. If possible, large spillages in open waters should be contained with floating barriers or other mechanical means.

Prevent product from entering sewers, rivers or other bodies of water.

Collect free product with suitable means. Absorb spilled product with suitable non-combustible materials. Collect spilled product by absorbing with specific floating absorbents. Collect the product by skimming or other suitable mechanical means.

Materials: Suitable non-combustible materials, specific floating absorbents

Obtain special instructions before use. Avoid contact with skin. Avoid breathing fume/mist. Do not ingest. Avoid splash filling of bulk volumes when handling hot liquid product. Prevent the risk of slipping. Use and store only outdoors or in a well-ventilated area. Avoid contact with the product. Avoid release to the environment. Take precautionary measures against static electricity. Use adequate personal protective equipment as required.

Keep only in original container. Keep containers tightly closed and properly labelled.

Do not eat, drink or smoke when using this product. Contaminated materials should not be allowed to accumulate in the workplaces and should never be kept inside the pockets. Keep away from food and beverages. Wash the hands thoroughly after handling. Change contaminated clothes at the end of working shift.

Keep away from sources of ignition - No smoking. Take precautionary measures against static electricity.

If heating is necessary, keep the temperature to a minimum and absorb vapours. Storage and handling temperatures should be kept as low as feasible to minimize fume production. Where hot product is handled in confined spaces, effective local ventilation must be provided. Do not enter empty storage tanks until measurements of available oxygen have been carried out.

Use safety gloves of following materials: NBR (nitrile) / neopren / viton (permeationslevel 5 - 6), Cat. II according to norm EN 388. Hot/molten product: Heat resistant gloves with long cuffs, or gauntlets. Product at ambient temperature (dust): Wear suitable gloves tested to EN374. Gloves must be periodically inspected and changed in case of wear, perforations or contaminations.

Closed goggles. If splashing is likely, full head and face protection (protective shield and/or safety goggles) should be used.

Respiratory equipment in case of nebulosity or aerosol: Use a mask with a filter type A2, A2/P2 or ABEK. If necessary, approved respiratory protection equipment shall be used when handling hot product in confined spaces: enclosed face mask with cartridge/filter type "A" or self-contained breathing apparatus (SCBA). If exposure levels cannot be determined or estimated with adequate confidence, or an oxygen deficiency is possible, only SCBA's should be used.

Oil-resistant and hardly inflammable protective clothing. Hot/molten product: Wear protective clothing for operations with hot material: heat resistant coveralls (with trousers legs over boots and sleeves over cuffs of gloves), heat resistant heavy duty antiskid boots (e. g. leather). Product at ambient temperature (dust): Long-sleeved coveralls, work boots. Coveralls should be changed at the end of the work shift and cleaned as necessary to avoid transfer of product to clothes or underwear. For loading/unloading operations: wear safety helmet, if necessary integrated full face visor. In case of hot/molten product: with integrated full face visor.

This substance is stable under all ordinary circumstances at ambient temperatures, and if released into the environment.

Decomposition starting at higher temperature (>350°C)

A mixture with nitrates or other strong oxidisers (e.g. chlorates, perchlorates, liquid oxygen) may create an explosive mass.

Excessive heating above the maximum recommended handling and storage temperature may cause degradation of the substance and evolution of irritant vapours and fumes.

Contact with strong oxidizers (peroxides, chromates, etc.) may cause a fire hazard. A mixture with nitrates or other strong oxidisers (e.g. chlorates, perchlorates, liquid oxygen) may create an explosive mass.

Combustion (incomplete) will likely generate oxides of carbon, sulphur and nitrogen, as well as additional undetermined organic compounds of the same elements. None under normal conditions at ambient temperatures.

Surplus (unused) or off-spec substance can be recovered or re-conditioned (according to specific characteristics and composition), or can be disposed of as waste.

Disposal can be carried out directly, or by delivery to qualified waste handlers. Contain and dispose of waste according to local regulations.