Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- VORANOL™ WK 3138 Polyol
- Chemical Name
- Glycerol propylene oxide polymer
Regulatory Identifiers
- CAS Number
- 25791-96-2 Check regulations →
- REACH No.
- Exempt
Identified Uses
Component(s) for the manufacture of urethane polymers. For industrial use.
Manufacturers & Suppliers
DOW BENELUX B.V.
manufacturer
HERBERT H.DOWWEG 5 HOEK 4542 NM TERNEUZEN NETHERLANDS
(31) 115 67 2626
Emergency Contacts
Emergency Contact
00 32 3575 0330
Belgium Poison Center
070/245.245
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
Manage your Safety Data Sheets
Organize and access chemical safety data with ease
Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| Glycerol propylene oxide polymer | 25791-96-2 | 99% | No |
Notes
If present in this product, any not classified components disclosed above for which no country specific OEL value(s) is(are) indicated under Section 8, are being disclosed as voluntarily disclosed components.
First Aid Measures
Emergency procedures for chemical exposure incidents
Move person to fresh air and keep comfortable for breathing; consult a physician.
Wash off with plenty of water. Suitable emergency safety shower facility should be immediately available.
Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist.
If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel.
Immediate Medical Attention
If burn is present, treat as any thermal burn, after decontamination. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.
Medical Treatment
If burn is present, treat as any thermal burn, after decontamination. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Do not use direct water stream. May spread fire.
Container may rupture from gas generation in a fire situation. Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.
Keep people away. Isolate fire and deny unnecessary entry. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container. Do not use direct water stream. May spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Contain fire water run-off if possible.
Firefighter Protection
Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, see Section 8 of the safety data sheet.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Spilled material may cause a slipping hazard. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.
Collect in suitable and properly labeled containers.
Related Products
Similar products with comparable safety profiles
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Keep container closed. This material is hygroscopic in nature. Product shipped/handled hot can cause thermal burns. Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion.
Protect from atmospheric moisture. Store in a dry place. Avoid prolonged exposure to heat and air.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations.
Chemical protective gloves should not be needed when handling this material. Consistent with general hygienic practice for any material, skin contact should be minimized. Use gloves with insulation for thermal protection (EN 407), when needed.
Use safety glasses (with side shields). Safety glasses (with side shields) should be consistent with EN 166 or equivalent. When handling hot material: Use chemical goggles. Chemical goggles should be consistent with EN 166 or equivalent. Wear a face-shield which allows use of chemical goggles, or wear a full-face respirator (meeting standard EN 136), to protect face and eyes when there is any likelihood of splashes.
Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions, no respiratory protection should be needed; however, if material is heated or sprayed, use an approved air-purifying respirator. Use the following CE approved air-purifying respirator: Organic vapor cartridge with a particulate pre-filter, type AP2 (meeting standard EN 14387).
No precautions other than clean body-covering clothing should be needed. When handling hot material, protect skin from thermal burns. Selection of specific items will depend on the operation.
See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
Stable under recommended storage conditions.
No data available
Will not occur by itself.
Product can oxidize at elevated temperatures. Generation of gas during decomposition can cause pressure in closed systems.
Avoid contact with oxidizing materials. Avoid contact with: Strong acids. Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates generates heat.
Decomposition products depend upon temperature, air supply and the presence of other materials.. Decomposition products can include and are not limited to:. Carbon dioxide.. Alcohols.. Ethers.. Hydrocarbons.. Ketones.. Polymer fragments..
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- Not applicable
- Shipping Name
- Not regulated for transport
- Transport Class
- Not applicable
- Packing Group
- Not applicable
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for VORANOL™ WK 3138 Polyol?
The signal word is no signal word.
What is the physical form of VORANOL™ WK 3138 Polyol?
VORANOL™ WK 3138 Polyol is a liquid. appearing as clear with clear color. It has characteristic odor.
What is VORANOL™ WK 3138 Polyol used for?
Component(s) for the manufacture of urethane polymers. For industrial use.
What is the melting point of VORANOL™ WK 3138 Polyol?
The melting point is No test data available and the boiling point is decomposes prior to boiling.