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Safety Data Sheet EN

VORANOL™ RH 360 Polyol

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
VORANOL™ RH 360 Polyol
Chemical Name
Reaction mass of sucrose propoxylated and glycerine propoxylated

Regulatory Identifiers

CAS Number
N/A
REACH No.
01-2119458874-24-0006, 01-2119458874-24-0008, 01-2119484612-36-0010, 01-2119484612-36-0011

Identified Uses

Component(s) for the manufacture of urethane polymers. For industrial use.

Manufacturers & Suppliers

D

DOW EUROPE GMBH

BACHTOBELSTRASSE 4 8810 HORGEN SWITZERLAND

31 115 67 2626

D

DOW BENELUX B.V.

HERBERT H.DOWWEG 5 HOEK 4542 NM TERNEUZEN NETHERLANDS

(31) 115 67 2626

Emergency Contacts

Emergency Contact

00 41 447 28 2820

24-Hour

Emergency Contact

00 31 115 69 4982

national poisoning information center (NVIC)

088 755 8000

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Not Classified

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
N/A --- 100% No

Notes

If present in this product, any not classified components disclosed above for which no country specific OEL value(s) is(are) indicated under Section 8, are being disclosed as voluntarily disclosed components.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move person to fresh air and keep comfortable for breathing; consult a physician.

Skin contact

Wash off with plenty of water. Suitable emergency safety shower facility should be immediately available.

Eye contact

Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist.

Ingestion

If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel.

Immediate Medical Attention

If burn is present, treat as any thermal burn, after decontamination. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

Medical Treatment

If burn is present, treat as any thermal burn, after decontamination. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.

Unsuitable media

Do not use direct water stream. May spread fire.

Specific hazards

Container may rupture from gas generation in a fire situation. Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.

Instructions

Keep people away. Isolate fire and deny unnecessary entry. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container. Do not use direct water stream. May spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Contain fire water run-off if possible. Fire water run-off, if not contained, may cause environmental damage. Review the "Accidental Release Measures" and the "Ecological Information" sections of this (M)SDS.

Firefighter Protection

Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, see Section 8 of the safety data sheet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Isolate area. Refer to section 7, Handling, for additional precautionary measures. Keep unnecessary and unprotected personnel from entering the area. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.

Environmental

Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.

Cleanup methods

Collect in suitable and properly labeled containers. Wash the spill site with water.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with eyes. Wash thoroughly after handling. Use with adequate ventilation. Keep container closed. This material is hygroscopic in nature. Product shipped/handled hot can cause thermal burns. Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion.

Storage

Protect from atmospheric moisture. Store in a dry place. Avoid prolonged exposure to heat and air.

Hygiene

Wash thoroughly after handling.

Fire prevention

Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations.

Hands

Chemical protective gloves should not be needed when handling this material. Consistent with general hygienic practice for any material, skin contact should be minimized. Use gloves with insulation for thermal protection (EN 407), when needed.

Eyes

Use safety glasses (with side shields). Safety glasses (with side shields) should be consistent with EN 166 or equivalent. When handling hot material: Use chemical goggles. Chemical goggles should be consistent with EN 166 or equivalent. Wear a face-shield which allows use of chemical goggles, or wear a full-face respirator (meeting standard EN 136), to protect face and eyes when there is any likelihood of splashes.

Respiratory

Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions, no respiratory protection should be needed; however, if material is heated or sprayed, use an approved air-purifying respirator. Use the following CE approved air-purifying respirator: Organic vapor cartridge with a particulate pre-filter, type AP2 (meeting standard EN 14387).

Skin/Body

No precautions other than clean body-covering clothing should be needed. When handling hot material, protect skin from thermal burns. Selection of specific items will depend on the operation.

Environmental

See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Melting Point
No test data available
Vapor Pressure
negligible at ambient temperature, Literature
Appearance
---
Boiling Point
Literature decomposes prior to boiling
Flash Point
>200 °C
Odor
Characteristic
Density
1,085 g/cm3 at 25 °C Literature
Flammability
Not applicable, liquid; Not expected to be a static-accumulating flammable liquid.
Solubility In Water
Literature soluble
Metal Corrosion
---
Cloud Point
---
Lower Explosive Limit
No test data available
Relative Evaporation Rate
---
State Under Standard Conditions
---
Form
---
Solidification Point
---
Molecular Weight
No test data available
Physical State
Liquid.
Auto Ignition Temperature
No test data available
Explosive Limits
---
Solubility
---
Vapor Density
---
Properties Status
---
Dynamic Viscosity
3 000 mPa.s at 25 °C Literature
Kinematic Viscosity
2500 - 3500 cSt at 25 °C Literature
Ph
5,0 - 7,0 DOWM 101495
Odor Threshold
No test data available
Solubility In Fat
---
Relative Density
>=1 at 25 °C / 25 °C Literature
Decomposition Temperature
No test data available
Colour
Colorless to yellow
Physical State Data
liquid
Colour Intensity
---
Bulk Density
---
Freezing Point
No test data available
Softening Point
---
Partition Coefficient
log Pow: -3,38 - -0,73 Estimated.
Crystallisation Point
---
Evaporation Rate
No test data available
Upper Explosive Limit
No test data available
Voc Content
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

No data available

Hazardous reactions

Will not occur by itself.

Avoid

Product can oxidize at elevated temperatures. Generation of gas during decomposition can cause pressure in closed systems.

Incompatible

Avoid contact with oxidizing materials. Avoid contact with: Strong acids. Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates generates heat.

Decomposition

Decomposition products depend upon temperature, air supply and the presence of other materials.. Decomposition products can include and are not limited to.: Carbon dioxide.. Alcohols.. Ethers.. Hydrocarbons.. Ketones.. Polymer fragments..

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
Not applicable
Shipping Name
Not regulated for transport
Transport Class
Not applicable
Packing Group
Not applicable
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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for VORANOL™ RH 360 Polyol?

The signal word is no signal word.

What is the physical form of VORANOL™ RH 360 Polyol?

VORANOL™ RH 360 Polyol is a liquid. with colorless to yellow color. It has characteristic odor.

What is VORANOL™ RH 360 Polyol used for?

Component(s) for the manufacture of urethane polymers. For industrial use.

What is the melting point of VORANOL™ RH 360 Polyol?

The melting point is No test data available and the boiling point is Literature decomposes prior to boiling.

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