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Safety Data Sheet EN

DOWANOL™ PMA Glycol Ether Acetate

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DOWANOL™ PMA Glycol Ether Acetate

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Industrial solvent for cleaner and coating formulations.

Manufacturers & Suppliers

T

THE DOW CHEMICAL COMPANY

manufacturer

2211 H.H. DOW WAY MIDLAND MI 48674 UNITED STATES

800-258-2436

Emergency Contacts

CHEMTREC

+1 800-424-9300

24-Hour Emergency Contact

Emergency Contact

800-424-9300

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3
STOT SE Cat. 3

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapour.
H336 May cause drowsiness or dizziness.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P261 Avoid breathing mist or vapours.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell.
In case of fire: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide to extinguish.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Propylene glycol methyl ether acetate 108-65-6 99.5 - 100% No
Methoxy-1-propanol acetate 70657-70-4 0.01 - 0.3% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move person to fresh air and keep comfortable for breathing; consult a physician.

Skin contact

Wash off with plenty of water.

Eye contact

Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist. Suitable emergency eye wash facility should be available in work area.

Ingestion

Rinse mouth with water. No emergency medical treatment necessary.

Immediate Medical Attention

Consult a physician if effects occur after inhalation or eye contact. No emergency medical treatment necessary for ingestion.

Medical Treatment

Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.

Unsuitable media

No data available

Specific hazards

During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Violent steam generation or eruption may occur upon application of direct water stream to hot liquids. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur.

Instructions

Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Burning liquids may be extinguished by dilution with water. Do not use direct water stream. May spread fire. Eliminate ignition sources. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage.

Firefighter Protection

Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Keep out of sewers. No smoking in area. Isolate area. Keep unnecessary and unprotected personnel from entering the area. Keep personnel out of low areas. Refer to section 7, Handling, for additional precautionary measures. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.

Small spill

Absorb with materials such as: Sand. Vermiculite. Collect in suitable and properly labeled containers.

Large spill

Contain spilled material if possible. Pump with explosion-proof equipment. If available, use foam to smother or suppress. Pump into suitable and properly labeled containers.

Environmental

Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.

Cleanup methods

Absorb with materials such as: Sand. Vermiculite. Collect in suitable and properly labeled containers. Pump into suitable and properly labeled containers.

Materials: Sand. Vermiculite.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with eyes. Wash thoroughly after handling. Keep away from heat, sparks and flame. No smoking, open flames or sources of ignition in handling and storage area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Electrically ground and bond all equipment. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. This product is a poor conductor of electricity and can become electrostatically charged, even in bonded or grounded equipment. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Handling operations that can promote accumulation of static charges include but are not limited to mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations.

Storage

Store away from direct sunlight. Minimize sources of ignition, such as static build-up, heat, spark or flame.

Hygiene

Wash thoroughly after handling.

Fire prevention

Keep away from heat, sparks and flame. No smoking, open flames or sources of ignition in handling and storage area.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations.

Hands

Use gloves chemically resistant to this material when prolonged or frequently repeated contact could occur. Examples of preferred glove barrier materials include: Butyl rubber. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Eyes

Use chemical goggles.

Respiratory

Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions no respiratory protection should be needed; however, if discomfort is experienced, use an approved air-purifying respirator. The following should be effective types of air-purifying respirators: Organic vapor cartridge.

Skin/Body

When prolonged or frequently repeated contact could occur, use protective clothing chemically resistant to this material. Selection of specific items such as faceshield, boots, apron, or full-body suit will depend on the task.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Colorless
Colour Intensity
---
Form
---
Odor
Ether
Odor Threshold
No test data available
Ph
No test data available
Melting Point
Not applicable to liquids
Boiling Point
145.8 °C (294.4 °F)
Flash Point
closed cup 45.5 °C (113.9 °F)
Freezing Point
-66 °C (-87 °F)
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No test data available
Vapor Pressure
2.66 mmHg at 20 °C (68 °F)
Vapor Density
---
Relative Density
0.964 at 25 °C (77 °F)
Bulk Density
---
Density
0.967 g/cm3 at 20 °C (68 °F)
Flammability
Not applicable to liquids; Not expected to be a static-accumulating flammable liquid.
Upper Explosive Limit
7.0 % vol
Lower Explosive Limit
1.5 % vol
Explosive Limits
---
Auto Ignition Temperature
333 °C (631 °F)
Decomposition Temperature
No test data available
Solubility
---
Partition Coefficient
log Pow: 1.2
Solubility In Water
247 g/L
Solubility In Fat
---
Molecular Weight
132.2 g/mol
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
1.1 mPa.s at 25 °C (77 °F)
Kinematic Viscosity
1.23 mm2/s at 20 °C (68 °F)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions. See Storage, Section 7.

Reactivity

No data available

Hazardous reactions

Polymerization will not occur.

Avoid

Product can oxidize at elevated temperatures. Avoid static discharge. Flammable vapors can be released at elevated temperatures.

Incompatible

Avoid contact with oxidizing materials. Avoid contact with: Strong acids. Strong oxidizers.

Decomposition

Decomposition products depend upon temperature, air supply and the presence of other materials.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN 3272
Shipping Name
Esters, n.o.s.(Propylene glycol monomethyl ether acetate)
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for DOWANOL™ PMA Glycol Ether Acetate?

The signal word is warning.

What is the physical form of DOWANOL™ PMA Glycol Ether Acetate?

DOWANOL™ PMA Glycol Ether Acetate is a liquid. with colorless color. It has ether odor.

What is DOWANOL™ PMA Glycol Ether Acetate used for?

Industrial solvent for cleaner and coating formulations.

What are the hazard statements for DOWANOL™ PMA Glycol Ether Acetate?

This substance has 2 hazard statements:

  • H226: Flammable liquid and vapour.
  • H336: May cause drowsiness or dizziness.

What is the melting point of DOWANOL™ PMA Glycol Ether Acetate?

The melting point is Not applicable to liquids and the boiling point is 145.8 °C (294.4 °F).

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