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Safety Data Sheet EN

DOWANOL™ PMA Glycol Ether Acetate

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DOWANOL™ PMA Glycol Ether Acetate

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Industrial solvent for cleaner and coating formulations.

Manufacturers & Suppliers

T

THE DOW CHEMICAL COMPANY

manufacturer

2211 H.H. DOW WAY, MIDLAND MI 48674, UNITED STATES

800-258-2436

Emergency Contacts

CHEMTREC

+1 800-424-9300

24-Hour

Emergency Contact

800-424-9300

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3
STOT SE Cat. 3

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapour.
H336 May cause drowsiness or dizziness.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P261 Avoid breathing mist or vapours.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P370 + P378 In case of fire: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide to extinguish.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Synonyms: propylene glycol methyl ether acetate

Chemical Name CAS Number Concentration Hazardous
Propylene glycol methyl ether acetate 108-65-6 99.5 - 100% No
Methoxy-1-propanol acetate 70657-70-4 0.01 - 0.3% No

Product name: DOWANOL™ PMA Glycol Ether Acetate Issue Date: 07/08/2025

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move person to fresh air and keep comfortable for breathing; consult a physician.

Skin contact

Wash off with plenty of water.

Eye contact

Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist.

Ingestion

Rinse mouth with water. No emergency medical treatment necessary.

Immediate Medical Attention

If effects occur, consult a physician, preferably an ophthalmologist.

Medical Treatment

No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.

Unsuitable media

No data available

Specific hazards

Violent steam generation or eruption may occur upon application of direct water stream to hot liquids. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur.

Instructions

Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Burning liquids may be extinguished by dilution with water. Do not use direct water stream. May spread fire. Eliminate ignition sources. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage.

Firefighter Protection

Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Isolate area. Keep unnecessary and unprotected personnel from entering the area. Keep personnel out of low areas.

Small spill

Absorb with materials such as: Sand. Vermiculite. Collect in suitable and properly labeled containers.

Large spill

Contain spilled material if possible. Pump with explosion-proof equipment. If available, use foam to smother or suppress. Pump into suitable and properly labeled containers.

Environmental

Prevent from entering into soil, ditches, sewers, waterways and/or groundwater.

Cleanup methods

Absorb with materials such as: Sand. Vermiculite. Collect in suitable and properly labeled containers. Pump with explosion-proof equipment.

Materials: Sand. Vermiculite.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with eyes. Wash thoroughly after handling. Keep away from heat, sparks and flame. No smoking, open flames or sources of ignition in handling and storage area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Electrically ground and bond all equipment. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion. This product is a poor conductor of electricity and can become electrostatically charged, even in bonded or grounded equipment. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Handling operations that can promote accumulation of static charges include but are not limited to mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations.

Storage

Store away from direct sunlight. Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in the following material(s): Carbon steel. Stainless steel. Phenolic lined steel drums. Do not store in: Aluminum. Copper. Galvanized iron. Galvanized steel.

Hygiene

Wash thoroughly after handling.

Fire prevention

Keep away from heat, sparks and flame. No smoking, open flames or sources of ignition in handling and storage area.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Auto Ignition Temperature
333 °C (631 °F) Literature
Physical State
Liquid.
Solubility
---
Physical State Data
liquid
Upper Explosive Limit
7.0 % vol Literature
Lower Explosive Limit
1.5 % vol Literature
Partition Coefficient
log Pow: 1.2 Measured
Colour Intensity
---
Metal Corrosion
---
Softening Point
---
Colour
Colorless
Vapor Density
---
Odor Threshold
No test data available
Boiling Point
145.8 °C (294.4 °F) Literature
Kinematic Viscosity
1.23 mm2/s at 20 °C (68 °F) Literature
Vapor Pressure
2.66 mmHg at 20 °C (68 °F) Literature
Density
0.967 g/cm3 at 20 °C (68 °F) Literature
Solidification Point
---
Bulk Density
---
Cloud Point
---
Odor
Ether
Melting Point
Not applicable to liquids
Crystallisation Point
---
Flash Point
closed cup 45.5 °C (113.9 °F) ASTM D3828
Solubility In Water
247 g/L Literature
Decomposition Temperature
No test data available
Appearance
---
Relative Evaporation Rate
---
State Under Standard Conditions
---
Flammability
Not expected to be a static-accumulating flammable liquid.
Dynamic Viscosity
1.1 mPa.s at 25 °C (77 °F) Literature
Molecular Weight
132.2 g/mol Literature
Voc Content
---
Ph
No test data available
Explosive Limits
---
Solubility In Fat
---
Freezing Point
-66 °C (-87 °F) Literature
Properties Status
---
Form
---
Evaporation Rate
No test data available
Relative Density
0.964 at 25 °C (77 °F) Literature
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions. See Storage, Section 7.

Reactivity

No data available

Hazardous reactions

Polymerization will not occur.

Avoid

Product can oxidize at elevated temperatures. Avoid static discharge. Flammable vapors can be released at elevated temperatures.

Incompatible

Avoid contact with oxidizing materials. Avoid contact with: Strong acids. Strong oxidizers.

Decomposition

Decomposition products depend upon temperature, air supply and the presence of other materials..

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

Acute toxicity to fish LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, 134 mg/l, Method Not Specified.

Toxicity

Acute toxicity to aquatic invertebrates EC50, Daphnia magna (Water flea), 48 Hour, 408 mg/l, Method Not Specified.

Toxicity

ErC50, Pseudokirchneriella subcapitata (microalgae), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 201 or Equivalent

Persistence and degradability

Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material has inherent, ultimate biodegradability according to OECD test (s) guidelines (reaches > 60 or 70% biodegradation in OECD test(s). 10-day Window: Pass Biodegradation: 83 % Exposure time: 28 d Method: OECD Test Guideline 301F or Equivalent 10-day Window: Not applicable Biodegradation: 100 % Exposure time: 28 d Method: OECD Test Guideline 302B or Equivalent Theoretical Oxygen Demand: 1.82 mg/mg

Bioaccumulative potential

Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 1.2 Measured

Mobility in soil

Partition coefficient (Koc): 1.7 Estimated.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Incinerator or other thermal destruction device.

Disposal

For unused & uncontaminated product, the preferred options include sending to a licensed, permitted: Incinerator or other thermal destruction device.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3272
Shipping Name
Esters, n.o.s.(Propylene glycol monomethyl ether acetate)
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for DOWANOL™ PMA Glycol Ether Acetate?

The signal word is warning.

What is the physical form of DOWANOL™ PMA Glycol Ether Acetate?

DOWANOL™ PMA Glycol Ether Acetate is a liquid. with colorless color. It has ether odor.

What is DOWANOL™ PMA Glycol Ether Acetate used for?

Industrial solvent for cleaner and coating formulations.

What are the hazard statements for DOWANOL™ PMA Glycol Ether Acetate?

This substance has 2 hazard statements:

  • H226: Flammable liquid and vapour.
  • H336: May cause drowsiness or dizziness.

What is the melting point of DOWANOL™ PMA Glycol Ether Acetate?

The melting point is Not applicable to liquids and the boiling point is 145.8 °C (294.4 °F) Literature.