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Safety Data Sheet EN

DOWANOL™ PMA Glycol Ether Acetate

CAS 108-65-6
EC 203-603-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DOWANOL™ PMA Glycol Ether Acetate
Chemical Name
2-methoxy-1-methylethyl acetate

Regulatory Identifiers

CAS Number
108-65-6 Check regulations →
EC Number
203-603-9 Check regulations →
REACH No.
01-2119475791-29

Identified Uses

Manufacture: Manufacture of substance. Use at industrial sites: Use in process chemicals. Formulation or re-packing: Formulation & (re)packing of substances and mixtures. Use at industrial sites: Use in coatings. Widespread use by professional workers: Use in coatings. Consumer use: Use in coatings. Use at industrial sites: Use in cleaning agents. Widespread use by professional workers: Use in cleaning agents. Consumer use: Use in cleaning agents. Widespread use by professional workers: Use in agrochemicals. Consumer use: Use in agrochemicals. Use at industrial sites: Use in Can and Coil Coatings, industrial. Use in coatings.

Manufacturers & Suppliers

D

DOW BENELUX B.V.

national supplier

HERBERT H.DOWWEG 5 HOEK 4542 NM TERNEUZEN NETHERLANDS

(31) 115 67 2626

Emergency Contacts

Emergency Contact

31-(0)115 694982

24-Hour

Emergency Contact

00 32 3575 0330

Belgium Poison Center

070/245.245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3 H226
STOT SE Cat. 3 H336

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapour.
H336 May cause drowsiness or dizziness.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing mist or vapours.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
2-methoxy-1-methylethyl acetate EC: 203-603-9 108-65-6 99.5% Yes
2-methoxypropyl acetate EC: 274-724-2 70657-70-4 0.3% Yes

Notes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move person to fresh air and keep comfortable for breathing; consult a physician.

Skin contact

Wash off with plenty of water.

Eye contact

Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist. Suitable emergency eye wash facility should be available in work area.

Ingestion

Rinse mouth with water. No emergency medical treatment necessary.

Immediate Medical Attention

No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

Medical Treatment

Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water fog or fine spray.. Dry chemical fire extinguishers.. Carbon dioxide fire extinguishers.. Foam.. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective..

Unsuitable media

No data available

Specific hazards

Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur..

Instructions

Keep people away. Isolate fire and deny unnecessary entry.. Stay upwind. Keep out of low areas where gases (fumes) can accumulate.. Burning liquids may be extinguished by dilution with water.. Do not use direct water stream. May spread fire.. Eliminate ignition sources.. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage..

Firefighter Protection

Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance..

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. No smoking in area. Isolate area. Keep unnecessary and unprotected personnel from entering the area. Keep personnel out of low areas. Refer to section 7, Handling, for additional precautionary measures. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.

Small spill

Absorb with materials such as: Sand. Vermiculite. Collect in suitable and properly labeled containers.

Large spill

Contain spilled material if possible. Pump with explosion-proof equipment. If available, use foam to smother or suppress. Pump into suitable and properly labeled containers.

Environmental

Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.

Cleanup methods

Absorb with materials such as: Sand. Vermiculite. Collect in suitable and properly labeled containers. Pump into suitable and properly labeled containers.

Materials: Sand. Vermiculite.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with eyes. Wash thoroughly after handling. Keep away from heat, sparks and flame. No smoking, open flames or sources of ignition in handling and storage area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion. This product is a poor conductor of electricity and can become electrostatically charged, even in bonded or grounded equipment. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Handling operations that can promote accumulation of static charges include but are not limited to mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations.

Storage

Store away from direct sunlight. Minimize sources of ignition, such as static build-up, heat, spark or flame.

Hygiene

Wash thoroughly after handling.

Fire prevention

Keep away from heat, sparks and flame. No smoking, open flames or sources of ignition in handling and storage area.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations.

Hands

Use gloves chemically resistant to this material when prolonged or frequently repeated contact could occur. Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Butyl rubber. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to EN 374) is recommended. Glove thickness alone is not a good indicator of the level of protection a glove provides against a chemical substance as this level of protection is also highly dependent on the specific composition of the material that the glove is fabricated from. The thickness of the glove must, depending on model and type of material, generally be more than 0.35 mm to offer sufficient protection for prolonged and frequent contact with the substance. As an exception to this general rule it is known that multilayer laminate gloves may offer prolonged protection at thicknesses less than 0.35 mm. Other glove materials with a thickness of less than 0.35 mm may offer sufficient protection when only brief contact is expected. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Eyes

Use chemical goggles. Chemical goggles should be consistent with EN 166 or equivalent.

Respiratory

Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions no respiratory protection should be needed; however, if discomfort is experienced, use an approved air-purifying respirator. Use the following CE approved air-purifying respirator: Organic vapor cartridge, type A (boiling point >65 °C, meeting standard EN 14387).

Skin/Body

When prolonged or frequently repeated contact could occur, use protective clothing chemically resistant to this material. Selection of specific items such as faceshield, boots, apron, or full-body suit will depend on the task.

Environmental

See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Kinematic Viscosity
1,23 mm2/s at 20 °C
Flammability
Not applicable to liquids; Not expected to be a static-accumulating flammable liquid.
Freezing Point
-66 °C
Odor Threshold
No test data available
Colour Intensity
---
Upper Explosive Limit
7,0 % vol
Metal Corrosion
---
Odor
Ether
Partition Coefficient
log Pow: 1,2 Measured
Form
---
Softening Point
---
Solubility In Fat
---
Cloud Point
---
State Under Standard Conditions
---
Decomposition Temperature
No test data available
Explosive Limits
---
Solubility In Water
247 g/L
Appearance
---
Lower Explosive Limit
1,5 % vol
Crystallisation Point
---
Voc Content
---
Ph
No test data available
Physical State
Liquid.
Density
0,967 g/cm3 at 20 °C
Properties Status
---
Bulk Density
---
Dynamic Viscosity
1,1 mPa.s at 25 °C
Vapor Density
---
Boiling Point
145,8 °C
Solubility
---
Molecular Weight
132,2 g/mol
Physical State Data
liquid
Solidification Point
---
Relative Density
0,964 at 25 °C
Melting Point
Not applicable to liquids
Relative Evaporation Rate
---
Colour
Colorless
Auto Ignition Temperature
333 °C
Flash Point
45,5 °C
Vapor Pressure
355 Pa at 20 °C
Evaporation Rate
No test data available
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

No data available

Hazardous reactions

Polymerization will not occur.

Avoid

Product can oxidize at elevated temperatures. Avoid static discharge. Flammable vapors can be released at elevated temperatures.

Incompatible

Oxidizing materials. Strong acids. Strong oxidizers.

Decomposition

Decomposition products depend upon temperature, air supply and the presence of other materials.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN 3272
Shipping Name
ESTERS, N.O.S.(Propylene glycol monomethyl ether acetate)
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for DOWANOL™ PMA Glycol Ether Acetate?

The signal word is warning.

What is the physical form of DOWANOL™ PMA Glycol Ether Acetate?

DOWANOL™ PMA Glycol Ether Acetate is a liquid. with colorless color. It has ether odor.

What is DOWANOL™ PMA Glycol Ether Acetate used for?

Manufacture: Manufacture of substance. Use at industrial sites: Use in process chemicals. Formulation or re-packing: Formulation & (re)packing of substances and mixtures. Use at industrial sites: Use in coatings. Widespread use by professional workers: Use in coatings. Consumer use: Use in coatings. Use at industrial sites: Use in cleaning agents. Widespread use by professional workers: Use in cleaning agents. Consumer use: Use in cleaning agents. Widespread use by professional workers: Use in agrochemicals. Consumer use: Use in agrochemicals. Use at industrial sites: Use in Can and Coil Coatings, industrial. Use in coatings.

What are the hazard statements for DOWANOL™ PMA Glycol Ether Acetate?

This substance has 2 hazard statements:

  • H226: Flammable liquid and vapour.
  • H336: May cause drowsiness or dizziness.

What is the melting point of DOWANOL™ PMA Glycol Ether Acetate?

The melting point is Not applicable to liquids and the boiling point is 145,8 °C.

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