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Safety Data Sheet EN

Hexyl alcohol

CAS 111-27-3
EC 203-852-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hexyl alcohol
Product Code
433860000; 433860010; 433861000
Chemical Name
Hexyl alcohol
Synonyms
1-Hexanol

Regulatory Identifiers

CAS Number
111-27-3 Check regulations →
EC Number
203-852-3 Check regulations →
REACH No.
01-2119487967-12

Identified Uses

Laboratory chemicals. Sector of use: SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites. Product category: PC21 - Laboratory chemicals. Process categories: PROC15 - Use as a laboratory reagent. Environmental release category: ERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)

Uses advised against

No Information available

Manufacturers & Suppliers

T

Thermo Fisher Scientific

manufacturer

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

F

Fisher Scientific UK

manufacturer

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

F

Fisher Scientific AG

distributor

Neuhofstrasse 11, CH 4153 Reinach

+41 (0) 56 618 41 11

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

Tox Info Suisse

145

24hr

Tox Info Suisse

+41-44 251 51 51

Chemtrec

0800 564 402

24h

Chemtrec

+41-43 508 20 11

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapor
H302 + H312 Harmful if swallowed or in contact with skin
H319 Causes serious eye irritation

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P280 Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P312 Call a POISON CENTER or doctor if you feel unwell

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
1-Hexanol EC: 203-852-3 111-27-3 95% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Get medical attention.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

Do not use a solid water stream as it may scatter and spread fire.

Specific hazards

Flammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated. Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources of ignition.

Instructions

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Avoid release to the environment.

Cleanup methods

Soak up with inert absorbent material.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Ensure adequate ventilation. Use spark-proof tools and explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Do not get in eyes, on skin, or on clothing. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks and flame. Flammables area.

Hygiene

Handle in accordance with good industrial hygiene and safety practice.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Nitrile rubber (>480 minutes, 0.35 mm, Level 6, EN374-3), Butyl rubber (>480 minutes, 0.5 mm, EN 374), Neoprene gloves (>480 minutes, 0.5 mm), Viton (R) (>480 minutes, 0.3 mm).

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Organic gases and vapours filter Type A Brown conforming to EN14387. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure. Inspect gloves before use. Observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination.

Environmental

Prevent product from entering drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Relative Evaporation Rate
---
Physical State
Liquid
Form
---
Boiling Point
156 - 157 °C / 312.8 - 314.6 °F
Kinematic Viscosity
---
Solidification Point
---
Colour Intensity
---
Upper Explosive Limit
7.7 vol%
Decomposition Temperature
No data available
Freezing Point
---
Physical State Data
liquid
Dynamic Viscosity
5.3 mPa.s at 20 °C
Density
0.814
Melting Point
-52 °C / -61.6 °F
Partition Coefficient
1.8 (log Pow)
Appearance
Colorless
Molecular Weight
102.18
Odor
sweet
Relative Density
---
Flash Point
59 °C / 138.2 °F
Odor Threshold
10 ppm
Solubility In Fat
---
Properties Status
---
Bulk Density
Not applicable
Crystallisation Point
---
Colour
---
Solubility In Water
6 g/L (25°C)
Solubility
---
Explosive Limits
---
Flammability
Flammable
Auto Ignition Temperature
292 - °C / 557.6 - °F
Evaporation Rate
---
Cloud Point
---
Voc Content
---
Ph
Not applicable
Lower Explosive Limit
1.2 vol%
Metal Corrosion
---
Vapor Pressure
1.3 mbar @ 20 °C
Softening Point
No data available
State Under Standard Conditions
---
Vapor Density
3.52
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. None under normal processing.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition. Protect from direct sunlight.

Incompatible

Strong oxidizing agents. Strong acids.

Decomposition

Carbon monoxide (CO). Carbon dioxide (CO₂).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2282
Shipping Name
HEXANOLS
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Hexyl alcohol known by?

Hexyl alcohol is also known as: 1-Hexanol

What is the hazard signal word for Hexyl alcohol?

The signal word is warning.

What is the physical form of Hexyl alcohol?

Hexyl alcohol is a liquid appearing as colorless . It has sweet odor.

What is Hexyl alcohol used for?

Laboratory chemicals. Sector of use: SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites. Product category: PC21 - Laboratory chemicals. Process categories: PROC15 - Use as a laboratory reagent. Environmental release category: ERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)

What are the hazard statements for Hexyl alcohol?

This substance has 3 hazard statements:

  • H226: Flammable liquid and vapor
  • H302 + H312: Harmful if swallowed or in contact with skin
  • H319: Causes serious eye irritation

What is the melting point of Hexyl alcohol?

The melting point is -52 °C / -61.6 °F and the boiling point is 156 - 157 °C / 312.8 - 314.6 °F.