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Safety Data Sheet EN

Nitric acid 69% for analysis EMPARTA® ACS

CAS 7697-37-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Nitric acid 69% for analysis EMPARTA® ACS
Product Code
101832
Chemical Name
Nitric acid

Regulatory Identifiers

CAS Number
7697-37-2 Check regulations →

Identified Uses

Reagent for analysis, Chemical production

Uses advised against

This product is not intended for consumer use.

Manufacturers & Suppliers

M

Millipore

manufacturer

S

Sigma-Aldrich Chemie GmbH

manufacturer

Eschenstrasse 5, D-82024 TAUFKIRCHEN

+49 (0)89 6513-1130

Emergency Contacts

CHEMTREC Deutschland

0800 181 7059

CHEMTREC weltweit

+49 (0)696 43508409

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Ox. Liq. Cat. 3 H272
Met. Corr. Cat. 1 H290
Acute Tox. Cat. 3 H331
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS03 - Oxidizing

GHS03

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H272 May intensify fire; oxidizer.
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P220 Keep away from clothing and other combustible materials.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
nitric acid EC: 231-714-2 7697-37-2 --- Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Call in physician. Call a physician immediately. Immediately call in ophthalmologist.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Not combustible. Has a fire-promoting effect due to release of oxygen. Ambient fire may liberate hazardous vapours.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid substance contact. Do not breathe vapors, aerosols. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not empty into drains.

Cleanup methods

Clean up affected area.

Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® H', Merck Art. No. 101595)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Observe label precautions. Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Tightly closed. Do not store near combustible materials. Keep locked up or in an area accessible only to qualified or authorized persons. Recommended storage temperature see product label.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Viton®, Minimum layer thickness: 0,7 mm, Break through time: > 480 min, Material tested: Vitoject® (KCL 890 / Aldrich Z677698, Size M). Splash contact: Material: Latex gloves, Minimum layer thickness: 0,6 mm, Break through time: > 120 min, Material tested: Lapren® (KCL 706 / Aldrich Z677558, Size M). This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Tightly fitting safety goggles

Respiratory

Recommended Filter type: Filter E-(P3). The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

acid-resistant protective clothing

Environmental

Do not empty into drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Bulk Density
---
Lower Explosive Limit
---
Odor Threshold
---
Flash Point
No data available
Metal Corrosion
---
Voc Content
---
Explosive Limits
---
Vapor Pressure
9,4 hPa at 20 °C
Cloud Point
---
Colour
colorless
Relative Evaporation Rate
---
Partition Coefficient
Not applicable for inorganic substances
Decomposition Temperature
---
Solidification Point
---
Vapor Density
---
Relative Density
---
State Under Standard Conditions
---
Ph
< 1 at 20 °C
Solubility
---
Dynamic Viscosity
No data available
Freezing Point
---
Appearance
---
Flammability
---
Auto Ignition Temperature
---
Colour Intensity
---
Solubility In Fat
---
Properties Status
---
Physical State Data
liquid
Density
1,41 g/cm³ at 20 °C
Evaporation Rate
---
Upper Explosive Limit
---
Odor
stinging
Kinematic Viscosity
No data available
Physical State
liquid
Softening Point
---
Boiling Point
122 °C at 1.013 hPa
Melting Point
Melting point: -41 °C
Crystallisation Point
---
Molecular Weight
---
Form
---
Solubility In Water
at 20 °C soluble
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

No data available

Reactivity

strong oxidising agent

Hazardous reactions

Risk of explosion with: Acetone, acetonitrile, acetylcholine, Alcohols, arsenic hydride, Organic Substances, Benzene, phosphides, anilines, Amines, Halogenated hydrocarbon, Diethyl ether, dimethyl ether, hydrazines, Nitro compounds, Sulfides, Dioxane, acetic acid, Acetic anhydride, ethanol, Ethylene glycol, Fluorine, Hydrazine hydrate, lithium silicide, organic solvents, Manganese, Cyanides, Powdered metals, Methanol, petrol, phosphorus hydrogen, anhydrides, Reducing agents, sulphur dioxide, thiocyanates, Titanium, Impurities, hydrogen peroxide, Tin, sugars, xylene, carbon/soot, oils, dichloromethane, rubber, formaldehyde, potassium chlorate with Organic Substances, mercury(II) nitrate with ethanol, Organic Substances with sulfuric acid, Nitrobenzene with sulfuric acid, potassium permanganate with Alcohols, glycerol with sulfuric acid. Risk of ignition or formation of inflammable gases or vapours with: Amines, Ammonia, combustible substances, Aldehydes, furfuryl alcohol, hydrogen iodide, Potassium, Lithium, Magnesium, phosphides, sodium, hydrides, phosphorus, pyridine, hydrogen sulphide. Violent reactions possible with: Nitriles, antimony, arsenic, Boron, ferric oxide, alkalines, sodium hypochlorite, formic acid, halogen-halogen compounds, Germanium, glycerol, nitrides, Sodium hydroxide solution, Sodium hydroxide, sulfuric acid, selenium, Bismuth, chlorates.

Avoid

No data available

Incompatible

Acetone, acetonitrile, acetylcholine, Alcohols, arsenic hydride, Organic Substances, Benzene, phosphides, anilines, Amines, Halogenated hydrocarbon, Diethyl ether, dimethyl ether, hydrazines, Nitro compounds, Sulfides, Dioxane, acetic acid, Acetic anhydride, ethanol, Ethylene glycol, Fluorine, Hydrazine hydrate, lithium silicide, organic solvents, Manganese, Cyanides, Powdered metals, Methanol, petrol, phosphorus hydrogen, anhydrides, Reducing agents, sulphur dioxide, thiocyanates, Titanium, Impurities, hydrogen peroxide, Tin, sugars, xylene, carbon/soot, oils, dichloromethane, rubber, formaldehyde, potassium chlorate, mercury(II) nitrate, sulfuric acid, Nitrobenzene, potassium permanganate, glycerol, Nitriles, antimony, arsenic, Boron, ferric oxide, alkalines, sodium hypochlorite, formic acid, halogen-halogen compounds, Germanium, nitrides, Sodium hydroxide solution, Sodium hydroxide, selenium, Bismuth, chlorates, Ammonia, combustible substances, Aldehydes, furfuryl alcohol, hydrogen iodide, Potassium, Lithium, Magnesium, sodium, hydrides, phosphorus, pyridine, hydrogen sulphide.

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2031
Shipping Name
NITRIC ACID
Transport Class
8 (5.1)
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Nitric acid 69% for analysis EMPARTA® ACS?

The signal word is danger.

What is the physical form of Nitric acid 69% for analysis EMPARTA® ACS?

Nitric acid 69% for analysis EMPARTA® ACS is a liquid with colorless color. It has stinging odor.

What is Nitric acid 69% for analysis EMPARTA® ACS used for?

Reagent for analysis, Chemical production

What are the hazard statements for Nitric acid 69% for analysis EMPARTA® ACS?

This substance has 4 hazard statements:

  • H272: May intensify fire; oxidizer.
  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.
  • H331: Toxic if inhaled.

What is the melting point of Nitric acid 69% for analysis EMPARTA® ACS?

The melting point is Melting point: -41 °C and the boiling point is 122 °C at 1.013 hPa.