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Safety Data Sheet EN

Methyl methanesulfonate

CAS 66-27-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Methyl methanesulfonate
Product Code
129925
Chemical Name
Methyl methanesulfonate

Regulatory Identifiers

CAS Number
66-27-3 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

A

Aldrich

manufacturer

S

Sigma-Aldrich Chemie GmbH

manufacturer

Eschenstrasse 5, D-82024 TAUFKIRCHEN

+49 (0)89 6513-1130

Emergency Contacts

CHEMTREC Deutschland

0800 181 7059

CHEMTREC weltweit

+49 (0)696 43508409

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Skin Sens. Cat. 1 H317
Muta. Cat. 1B H340
Carc. Cat. 2 H351
Repr. Cat. 2 H361fd
STOT RE Cat. 2 H373
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H301 Toxic if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H340 May cause genetic defects.
H351 Suspected of causing cancer.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H373 May cause damage to organs (Lungs) through prolonged or repeated exposure if inhaled.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
methyl methanesulphonate EC: 200-625-0 66-27-3 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water Foam Carbon dioxide (CO2) Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not inhale substance/mixture. For precautions see section 2.2.

Storage

Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: butyl-rubber, Minimum layer thickness: 0,7 mm, Break through time: 480 min, Material tested: Butoject® (KCL 898). Splash contact: Material: Chloroprene, Minimum layer thickness: 0,65 mm, Break through time: 10 min, Material tested: KCL 720 Camapren®. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

Recommended Filter type: Filter A-(P3). The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Bulk Density
---
Auto Ignition Temperature
---
Partition Coefficient
---
Flammability
---
Explosive Limits
---
Lower Explosive Limit
---
Odor Threshold
---
Melting Point
20 °C
Colour Intensity
---
Dynamic Viscosity
---
Solubility
---
Vapor Pressure
0,8 hPa at 59 °C
Physical State
clear, liquid
Freezing Point
---
Solubility In Fat
---
Solubility In Water
200 g/l at 20 °C - completely soluble
Softening Point
---
Odor
pungent
Kinematic Viscosity
---
Properties Status
---
Relative Evaporation Rate
---
Decomposition Temperature
---
Voc Content
---
Appearance
---
Boiling Point
202 - 203 °C - lit.
Evaporation Rate
---
Vapor Density
---
Molecular Weight
---
Ph
---
Crystallisation Point
---
Physical State Data
liquid
Relative Density
---
Colour
light yellow
Metal Corrosion
---
Cloud Point
---
Upper Explosive Limit
---
Density
1,3 g/cm³ at 25 °C - lit.
Form
---
Flash Point
104 °C - closed cup
State Under Standard Conditions
---
Solidification Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical.

Hazardous reactions

Violent reactions possible with: Strong oxidizing agents, Strong acids, Bases

Avoid

Strong heating.

Incompatible

no information available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2810
Shipping Name
TOXIC LIQUID, ORGANIC, N.O.S. (methyl methanesulphonate)
Transport Class
6.1
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Methyl methanesulfonate?

The signal word is danger.

What is the physical form of Methyl methanesulfonate?

Methyl methanesulfonate is a clear, liquid with light yellow color. It has pungent odor.

What is Methyl methanesulfonate used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Methyl methanesulfonate?

This substance has 9 hazard statements:

  • H301: Toxic if swallowed.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H340: May cause genetic defects.
  • H351: Suspected of causing cancer.
  • H361fd: Suspected of damaging fertility. Suspected of damaging the unborn child.
  • H373: May cause damage to organs (Lungs) through prolonged or repeated exposure if inhaled.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Methyl methanesulfonate?

The melting point is 20 °C and the boiling point is 202 - 203 °C - lit..