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Safety Data Sheet EN

Methyl sulfoxide

CAS 67-68-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Methyl sulfoxide
Product Code
AC610970000, AC610971000
Synonyms
Dimethyl sulfoxide; DMSO

Regulatory Identifiers

CAS Number
67-68-5 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use.

Manufacturers & Suppliers

F

Fisher Scientific Company

manufacturer

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

A

Acros Organics

manufacturer

One Reagent Lane, Fair Lawn, NJ 07410

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 4

GHS Pictograms

Hazard Statements

H227 Combustible liquid

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P370 + P378 In case of fire: Use CO2, dry chemical, or foam to extinguish
P403 + P235 Store in a well-ventilated place. Keep cool
P501 Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
Dimethyl sulfoxide 67-68-5 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Get medical attention immediately if symptoms occur. If not breathing, give artificial respiration.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Do NOT induce vomiting. Get medical attention.

Immediate Medical Attention

Get medical attention immediately if symptoms occur.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

No information available

Specific hazards

Combustible material. Containers may explode when heated. Thermal decomposition can lead to release of irritating gases and vapors.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Should not be released into the environment.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of ignition. Avoid contact with skin, eyes or clothing. Avoid ingestion and inhalation.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks and flame.

Hygiene

Avoid contact with skin, eyes or clothing. Avoid ingestion and inhalation.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.

Hands

Wear appropriate protective gloves

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Particle filter.

Skin/Body

Wear appropriate protective clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Colorless
Colour Intensity
---
Form
---
Odor
Odorless
Odor Threshold
No information available
Ph
No information available
Melting Point
18.4 °C / 65.1 °F
Boiling Point
189 °C / 372.2 °F
Flash Point
87 °C / 188.6 °F Method - No information available
Freezing Point
---
Softening Point
No data available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No information available
Vapor Pressure
0.55 mbar @ 20°C
Vapor Density
2.7 (Air = 1.0)
Relative Density
---
Bulk Density
Not applicable
Density
1.100
Flammability
Combustible liquid (On basis of test data)
Upper Explosive Limit
42 Vol%
Lower Explosive Limit
2.6 Vol%
Explosive Limits
---
Auto Ignition Temperature
301 °C / 573.8 °F
Decomposition Temperature
>190°C
Solubility
---
Partition Coefficient
Dimethyl sulfoxide: -1.35
Solubility In Water
Soluble
Solubility In Fat
---
Molecular Weight
78.13
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
1.98 mPa.s @ 25°C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Hygroscopic.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. Thermal decomposition can take place above 189°C / 372°F.

Avoid

Incompatible products. Excess heat. Exposure to moist air or water. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents, Strong acids, Strong bases, Alkali metals

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO2), Sulfur oxides, Sulfides, Formaldehyde

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Freshwater Algae: EC50 96h 12350 - 25500 mg/L; Freshwater Fish: 40 g/L LC50 96 h, 33-37 g/L LC50 96 h; Microtox: 16000 mg/L EC50 Pseudomonas putida 16 h, 32 g/L EC50 Tetrahymena pyriformis 24 h, 77 mg/L EC50 Photobacterium phosphoreum 5 min; Water Flea: EC50 24h 7000 mg/L

Persistence and degradability

Persistence is unlikely

Bioaccumulative potential

No information available.

Mobility in soil

Will likely be mobile in the environment due to its water solubility.

12.3 Bioaccumulative potential

| Component | log Pow | | --- | --- | | Dimethyl sulfoxide | -1.35 |
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
NA1993
Shipping Name
Combustible liquid, n.o.s.
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Methyl sulfoxide known by?

Methyl sulfoxide is also known as: Dimethyl sulfoxide; DMSO

What is the hazard signal word for Methyl sulfoxide?

The signal word is warning.

What is the physical form of Methyl sulfoxide?

Methyl sulfoxide is a liquid with colorless color. It has odorless odor.

What is Methyl sulfoxide used for?

Laboratory chemicals.

What are the hazard statements for Methyl sulfoxide?

This substance has 1 hazard statement:

  • H227: Combustible liquid

What is the melting point of Methyl sulfoxide?

The melting point is 18.4 °C / 65.1 °F and the boiling point is 189 °C / 372.2 °F.