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Safety Data Sheet EN

Perfluorooctanoic acid

CAS 335-67-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Perfluorooctanoic acid
Product Code
171468
Chemical Name
Perfluorooctanoic acid

Regulatory Identifiers

CAS Number
335-67-1 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration or the annual tonnage does not require a registration.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

S

Sigma-Aldrich Chemie GmbH

manufacturer

Eschenstrasse 5, D-82024 TAUFKIRCHEN

+49 (0)89 6513-1130

Emergency Contacts

CHEMTREC Deutschland

0800 181 7059

CHEMTREC weltweit

+49 (0)696 43508409

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H332
Skin Corr. Cat. 1C H314
Eye Dam. Cat. 1 H318
Carc. Cat. 2 H351
Repr. Cat. 1B H360D
Lact. H362
STOT RE Cat. 1 H372
Persistent, bioaccumulative and toxic EUH440

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 + H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H351 Suspected of causing cancer.
H360D May damage the unborn child.
H362 May cause harm to breast-fed children.
H372 Causes damage to organs (Liver) through prolonged or repeated exposure.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust.
P263 Avoid contact during pregnancy and while nursing.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P391 Collect spillage.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
pentadecafluorooctanoic acid EC: 206-397-9 335-67-1 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Immediately call in physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Foam, Carbon dioxide (CO2), Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Suppress (knock down) gases/vapours/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up carefully. Dispose of properly. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Material : Nitrile rubber, Break through time : 480 min, Glove thickness : 0,11 mm, Protective index : Full contact, Manufacturer : KCL 741 Dermatril® L; Material : Nitrile rubber, Break through time : 480 min, Glove thickness : 0,11 mm, Protective index : Splash contact, Manufacturer : KCL 741 Dermatril® L. Remarks : This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter : Filter type P3. The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Acid-resistant protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Voc Content
---
State Under Standard Conditions
---
Relative Density
---
Evaporation Rate
No data available
Crystallisation Point
---
Freezing Point
---
Bulk Density
---
Properties Status
---
Odor Threshold
---
Colour Intensity
---
Solubility In Water
3,4 g/l (20 °C)
Upper Explosive Limit
No data available
Appearance
---
Physical State Data
solid
Kinematic Viscosity
No data available
Solidification Point
---
Dynamic Viscosity
5,72 mPa.s (60 °C)
Relative Evaporation Rate
---
Decomposition Temperature
> 300 °C
Softening Point
---
Solubility
---
Metal Corrosion
---
Ph
2,6 (20 °C) Concentration: 1 g/l
Boiling Point
189 °C (981 hPa)
Molecular Weight
414,07 g/mol
Lower Explosive Limit
No data available
Auto Ignition Temperature
No data available
Melting Point
55 - 56 °C
Explosive Limits
---
Form
flakes
Vapor Pressure
0,69 hPa (25 °C)
Density
1,8 g/cm3 (20 °C)
Colour
colourless
Cloud Point
---
Odor
stinging
Physical State
solid
Flash Point
No data available
Vapor Density
---
Partition Coefficient
log Pow: 6,30 Method: (calculated) Potential bioaccumulation (Lit.)
Flammability
No data available
Solubility In Fat
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Hazardous reactions

Violent reactions possible with: Strong oxidizing agents, Strong acids, Bases

Avoid

no information available

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3261
Shipping Name
CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (pentadecafluorooctanoic acid)
Transport Class
8
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Perfluorooctanoic acid?

The signal word is danger.

What is the physical form of Perfluorooctanoic acid?

Perfluorooctanoic acid is a solid with colourless color. It has stinging odor.

What is Perfluorooctanoic acid used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Perfluorooctanoic acid?

This substance has 6 hazard statements:

  • H302 + H332: Harmful if swallowed or if inhaled.
  • H314: Causes severe skin burns and eye damage.
  • H351: Suspected of causing cancer.
  • H360D: May damage the unborn child.
  • H362: May cause harm to breast-fed children.
  • H372: Causes damage to organs (Liver) through prolonged or repeated exposure.

What is the melting point of Perfluorooctanoic acid?

The melting point is 55 - 56 °C and the boiling point is 189 °C (981 hPa).