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Safety Data Sheet EN

Hydrazine sulfate

CAS 10034-93-2
EC 233-110-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hydrazine sulfate
Product Code
201860000; 201861000; 201865000
Chemical Name
Hydrazine sulfate
Synonyms
Hydrazinium Sulfate; Hydrazine dihydrogen sulfate salt; Hydrazine hydrogen sulfate; Hydrazine monosulfate

Regulatory Identifiers

CAS Number
10034-93-2 Check regulations →
EC Number
233-110-4 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

F

Fisher Scientific UK

distributor

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

T

Thermo Fisher Scientific

distributor

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

Emergency Contacts

Information US

001-800-227-6701

Information Europe

+32 14 57 52 11

Emergency Number US

001-201-796-7100

Emergency Number Europe

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H311
Acute Tox. Cat. 3 H331
Skin Corr. Cat. 1C H314
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317
Carc. Cat. 1B H350
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H350 May cause cancer
H410 Very toxic to aquatic life with long lasting effects

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Hydrazine sulfate EC: 233-110-4 10034-93-2 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes.

Symptoms: May cause allergic skin reaction. Symptoms of allergic reaction may include rash, itching, swelling, tingling of the hands and feet.

Eye contact

In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Symptoms: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation.

Immediate Medical Attention

Immediate medical attention is required for all exposure routes.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO₂, dry chemical, dry sand, alcohol-resistant foam.

Unsuitable media

No information available.

Specific hazards

The product causes burns of eyes, skin and mucous membranes.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required. Evacuate personnel to safe areas. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid dust formation.

Environmental

Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains.

Cleanup methods

Sweep up and shovel into suitable containers for disposal.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not ingest. If swallowed then seek immediate medical assistance. Do not breathe (dust, vapor, mist, gas). Avoid dust formation.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place.

Hygiene

Handle in accordance with good industrial hygiene and safety practice.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Natural rubber, Nitrile rubber, Neoprene, PVC. Breakthrough time: See manufacturers recommendations. EU standard: EN 374. Glove comments: (minimum requirement). Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information). Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Eyes

Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Particulates filter conforming to EN 143. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Particle filtering: EN149:2001. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Long sleeved clothing.

Environmental

Prevent product from entering drains. Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Cloud Point
---
Vapor Pressure
No data available
Flammability
No information available
Density
No data available
Ph
1.5 (5% aq.sol)
State Under Standard Conditions
---
Decomposition Temperature
>254°C
Solidification Point
---
Colour Intensity
---
Physical State Data
solid
Molecular Weight
130.12
Flash Point
No information available
Physical State
Solid
Dynamic Viscosity
---
Lower Explosive Limit
No data available
Kinematic Viscosity
---
Voc Content
---
Upper Explosive Limit
No data available
Metal Corrosion
---
Solubility In Fat
---
Solubility
No information available
Solubility In Water
30 g/L (20°C)
Bulk Density
No data available
Auto Ignition Temperature
No data available
Softening Point
---
Vapor Density
Not applicable
Freezing Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Melting Point
254 °C / 489.2 °F
Explosive Limits
---
Colour
---
Odor Threshold
No data available
Evaporation Rate
Not applicable - Solid
Partition Coefficient
---
Boiling Point
No information available
Appearance
White
Properties Status
---
Odor
Odorless
Form
---
Relative Density
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous polymerization does not occur.

Avoid

Incompatible products. Excess heat.

Incompatible

Bases. Reducing Agent. Oxidizing agent.

Decomposition

Nitrogen oxides (NOx). Sulfur oxides. Thermal decomposition can lead to release of irritating gases and vapors.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2923
Shipping Name
CORROSIVE SOLID, TOXIC, N.O.S.
Transport Class
8
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Hydrazine sulfate known by?

Hydrazine sulfate is also known as: Hydrazinium Sulfate; Hydrazine dihydrogen sulfate salt; Hydrazine hydrogen sulfate; Hydrazine monosulfate

What is the hazard signal word for Hydrazine sulfate?

The signal word is danger.

What is the physical form of Hydrazine sulfate?

Hydrazine sulfate is a solid appearing as white . It has odorless odor.

What is the solubility of Hydrazine sulfate?

No information available

What is Hydrazine sulfate used for?

Laboratory chemicals.

What are the hazard statements for Hydrazine sulfate?

This substance has 5 hazard statements:

  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled
  • H314: Causes severe skin burns and eye damage
  • H317: May cause an allergic skin reaction
  • H350: May cause cancer
  • H410: Very toxic to aquatic life with long lasting effects

What is the melting point of Hydrazine sulfate?

The melting point is 254 °C / 489.2 °F and the boiling point is No information available.