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Safety Data Sheet EN

Hydrazine

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hydrazine
Product Code
32728

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

Alfa Aesar, A Johnson Matthey Company / Johnson Matthey Catalog Company, Inc. logo

Alfa Aesar, A Johnson Matthey Company / Johnson Matthey Catalog Company, Inc.

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

http://www.alfa.com

Emergency Contacts

Health, Safety and Environmental Department

(978) 521-6300

CHEMTREC

(800) 424-9300

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 2
Skin Sens. Cat. 1A
Carc. Cat. 1A
Skin Corr. Cat. 1A
Flam. Liq. Cat. 3
Aquatic Acute Cat. 1

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapour.
H300 Fatal if swallowed.
H310 Fatal in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H330 Fatal if inhaled.
H350 May cause cancer.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P284 Wear respiratory protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P341 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P310 Immediately call a POISON CENTER or doctor/physician.
P320 Specific treatment is urgent (see label).
P321 Specific treatment (see label).
P322 Specific measures (see label).
P330 Rinse mouth.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P361 Remove/Take off immediately all contaminated clothing.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use for extinction: CO2, powder or water spray.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Chemical characterization: hydrazine

Chemical Name CAS Number Concentration Hazardous
hydrazine EC: 206-114-9 302-01-2 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.

Skin contact

Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Ingestion

Do not induce vomiting; immediately call for medical help. Seek immediate medical advice.

Immediate Medical Attention

Seek immediate medical advice.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

Firefighter Protection

Wear self-contained respirator. Wear fully protective impervious suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation. Keep away from ignition sources.

Environmental

Do not allow material to be released to the environment without proper governmental permits.

Cleanup methods

Absorb with liquid-binding material. Use neutralizing agent.

Materials: sand, diatomite, acid binders, universal binders, sawdust

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle under protective gas. Keep container tightly sealed. Open and handle container with care.

Storage

Store in cool, dry place in tightly closed containers. Store under inert gas.

Fire prevention

Keep ignition sources away. Protect against electrostatic charges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves

Eyes

Safety glasses, Tightly sealed goggles, Full face protection

Respiratory

Use suitable respirator when high concentrations are present.

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solubility
---
Melting Point
1.4°C (35°F)
Colour Intensity
---
Lower Explosive Limit
4.7 Vol %
Flash Point
38°C (100°F)
Kinematic Viscosity
---
Properties Status
---
Solubility In Water
1000 g/l
Molecular Weight
---
Upper Explosive Limit
100 Vol %
Bulk Density
---
Metal Corrosion
---
Voc Content
---
Vapor Pressure
13 hPa (10 mm Hg)
Boiling Point
113.5°C (236°F)
Vapor Density
---
Physical State Data
liquid
Ph
---
Auto Ignition Temperature
270°C (518°F)
Appearance
---
Odor Threshold
---
Solubility In Fat
---
Softening Point
---
Flammability
---
Odor
Ammonia-like
Decomposition Temperature
Not determined
Colour
Colorless
Dynamic Viscosity
---
Relative Density
---
Partition Coefficient
---
Solidification Point
---
Relative Evaporation Rate
---
Cloud Point
---
Crystallisation Point
---
Physical State
Liquid
State Under Standard Conditions
---
Freezing Point
---
Evaporation Rate
---
Form
Liquid
Explosive Limits
---
Density
1.011 g/cm³
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Decomposition will not occur if used and stored according to specifications.

Reactivity

Forms explosive gas mixture with air, Reacts with various metals, Explosive reaction with oxidizing agents such as calcium chloride and or peroxides, Reacts with acids

Hazardous reactions

Forms explosive gas mixture with air, Reacts with various metals, Explosive reaction with oxidizing agents such as calcium chloride and or peroxides, Reacts with acids

Avoid

Decomposition will not occur if used and stored according to specifications.

Incompatible

Oxidizing agents, Oxygen, Metal powders, Organic materials

Decomposition

Nitrogen oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Consult state, local or national regulations to ensure proper disposal.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2029
Shipping Name
HYDRAZINE, ANHYDROUS
Transport Class
8
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hydrazine?

The signal word is danger.

What is the physical form of Hydrazine?

Hydrazine is a liquid with colorless color. It has ammonia-like odor.

What are the hazard statements for Hydrazine?

This substance has 8 hazard statements:

  • H226: Flammable liquid and vapour.
  • H300: Fatal if swallowed.
  • H310: Fatal in contact with skin.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H330: Fatal if inhaled.
  • H350: May cause cancer.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of Hydrazine?

The melting point is 1.4°C (35°F) and the boiling point is 113.5°C (236°F).