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Safety Data Sheet EN

Benzoic acid

CAS 65-85-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Benzoic acid
Product Code
242381
Chemical Name
Benzoic acid

Regulatory Identifiers

CAS Number
65-85-0 Check regulations →
REACH No.
01-2119455536-33-XXXX

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

M

Merck Life Science BV/SRL

manufacturer

Brusselsesteenweg 288, B-3090 OVERIJSE

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318
STOT RE Cat. 1 H372

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 Causes skin irritation.
H318 Causes serious eye damage.
H372 Causes damage to organs (Lungs) through prolonged or repeated exposure if inhaled.

Precautionary Statements

P260 Do not breathe dust.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314 Get medical advice/ attention if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Benzoic acid EC: 200-618-2 65-85-0 --- Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water Foam Carbon dioxide (CO2) Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides. Combustible. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up dry. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. Splash contact: Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P2. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Crystallisation Point
---
Partition Coefficient
log Pow: 1,88 - Bioaccumulation is not expected.
Solubility In Water
No data available
Upper Explosive Limit
No data available
Relative Density
No data available
Vapor Density
---
Relative Evaporation Rate
---
Odor Threshold
---
Colour
white
Cloud Point
---
Vapor Pressure
No data available
Physical State
crystalline
Dynamic Viscosity
No data available
Boiling Point
249 °C - lit.
Solubility
---
Evaporation Rate
---
Solubility In Fat
---
Decomposition Temperature
No data available
Properties Status
---
Ph
2,8 at 25 °C
Explosive Limits
---
Molecular Weight
---
Flash Point
Not applicable
Kinematic Viscosity
No data available
Solidification Point
---
Auto Ignition Temperature
No data available
Physical State Data
solid
Flammability
No data available
Freezing Point
---
Voc Content
---
Lower Explosive Limit
No data available
Density
1,26 g/cm³ at 15 °C
Odor
No data available
Melting Point
121 - 125 °C - lit.
Appearance
---
Metal Corrosion
---
Bulk Density
---
Form
---
Colour Intensity
---
State Under Standard Conditions
---
Softening Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Hazardous reactions

Risk of ignition or formation of inflammable gases or vapours with: Fluorine. Exothermic reaction with: bases, Strong oxidizing agents, Strong bases, nitrites, strong reducing agents.

Avoid

no information available

Incompatible

Fluorine, bases, Strong oxidizing agents, Strong bases, nitrites, strong reducing agents

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Benzoic acid?

The signal word is danger.

What is the physical form of Benzoic acid?

Benzoic acid is a crystalline with white color. It has no data available odor.

What is Benzoic acid used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Benzoic acid?

This substance has 3 hazard statements:

  • H315: Causes skin irritation.
  • H318: Causes serious eye damage.
  • H372: Causes damage to organs (Lungs) through prolonged or repeated exposure if inhaled.

What is the melting point of Benzoic acid?

The melting point is 121 - 125 °C - lit. and the boiling point is 249 °C - lit..