Eni Blasia 220

In case of disturbances owing to inhalation of vapours or mists, remove the victim from exposure; keep at rest; if necessary, seek medical attention.

Symptoms: Irritation to airways, nausea and dizziness (in case of overexposure to sprays and mists).

Take off contaminated clothing and shoes. Wash thoroughly with soap and water. If inflammation or irritation persists, seek medical advice. In case of burns, cool affected part with cold running water for at least 10 min. Cover with gauze or clean cloth. Ask for medical assistance or bring to a hospital. Do not apply salves or other substances, unless by doctor's advice. Body hypothermia must be avoided. Do not put ice on the burn.

Symptoms: Contact with hot product may cause thermal burns.

Rinse eyes thoroughly for at least 15 minutes. Keep eyelids well apart. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation persists, seek medical advice. In case of burns, cool affected part with cold running water for at least 10 min. Cover with gauze or clean cloth. Ask for medical assistance or bring to a hospital. Do not apply salves or other substances, unless by doctor's advice.

Symptoms: Temporary reddening and irritation. Contact with hot product or vapours may cause burns.

Do not induce vomiting to avoid aspiration into the lungs. Keep at rest. If the person is conscious, rinse mouth with water without swallowing. Keep at rest. Call for medical assistance or bring to an hospital. If the casualty is unconscious, place in the recovery position. In case of spontaneous vomiting, keep head low, to avoid the risk of aspiration into the lungs. Do not give anything by mouth to an unconscious person.

Symptoms: Nausea, discomfort and gastric disturbances.

Small-size fires: carbon dioxide, dry chemicals, foam, sand or earth. Large fires: foam or water fog (mist). These means should be used by trained personnel only. Other extinguishing gases (according to regulations).

Do not use water jets. They could cause splattering, and spread the fire. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.

This product is combustible, but not classified as Flammable. The creation of flammable vapour mixtures takes place at temperatures which are higher than normal ambient levels. The vapours are flammable and may form explosive mixtures with air.

Shut off source of product, if possible. Spilled product which is not burning should be covered with sand or foam. Move containers away from the fire area if this can be done without risk. Use water sprays to cool containers and surfaces exposed to the flames. If the fire cannot be controlled, evacuate area.

Stop or contain leak at the source, if safe to do so. Eliminate all ignition sources if safe to do so (e.g. electricity, sparks, fires, flares). Avoid accidental sprays on hot surfaces or electrical contacts. Avoid direct contact with released material. Keep upwind. Keep non-involved personnel away from the area of spillage. Alert emergency personnel. Except in case of small spillages, the feasibility of any actions should always be assessed and advised, if possible, by a trained, competent person in charge of managing the emergency. If required, notify relevant authorities according to all applicable regulations.

Do not let the product accumulate in confined or underground spaces. Do not let the product flow into sewers or water courses, or in any way contaminate the environment. In case of contamination of environment compartments (soil, subsoil, surface or underground waters), remove contaminated soil when possible, and in any case treat all involved compartments in accordance with local regulations. The site should have a spill plan to ensure that adequate safeguards are in place to minimize the impact of episodic releases.

Recover free liquid and waste materials in suitable waterproof and oil-resistant containers. Clean contaminated area.

Materials: suitable waterproof, oil resistant containers

Ensure that all relevant regulations regarding handling and storage facilities of flammable products are followed. Use and store only outdoors or in a well-ventilated area. During transfer operations, ensure that all equipment and containers are correctly grounded. Avoid the build-up of electric charges. Emptied containers can contain combustible product residues. Do not cut, weld, drill, burn or incinerate empty containers or drums, unless they have been drained and cleaned. Before entering storage tanks and commencing any operation in a confined area (e.g. tunnels), carry out an adequate clean-up, and check the atmosphere for oxygen content, flammability, and the presence of sulphur compounds. Do not use compressed air for filling, discharging, or handling operations. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Store in dry, well-ventilated area. Keep away from open flames, hot surfaces and sources of ignition. Do not smoke.

Avoid contact with skin. Do not breathe fume/ mist/ vapours. Do not ingest. Do not smoke. Do not eat and do not drink during use. Do not clean hands with dirty or oil-soaked rags. Do not re-use clothes, if they are still contaminated. Keep away from food and beverages.

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. During transfer operations, ensure that all equipment and containers are correctly grounded. Avoid the build-up of electric charges.

Ensure that there is a suitable ventilation system. Before entering storage tanks and commencing any operation in a confined area (e.g. tunnels), check the atmosphere for oxygen content, presence of hydrogen sulphide (H2S) and SOx, and flammability. See also Section 16, "Other information".

When there is a risk of contact with the skin, use waterproof gloves, resistant to chemical products. Gloves must be felt-lined. Adequate materials: nitrile (NBR) or PVC with a protection index > 5 (permeation time > 240 mins). Use gloves respecting all the conditions and within the limits set by the manufacturer. Replace gloves immediately in case of cuts, holes or other signs of damages or degradation. If necessary, refer to the EN 374 standard.

When there is a risk of contact with the eyes, use safety goggles or other means of protection (face shield). If necessary, refer to national standards or to the EN 166 standard.

Independently from other possible actions (technical modifications, operating procedures, and other means to limit the exposure of workers), personal protection equipment can be used according to necessity. Open or well ventilated spaces: in presence of oil mists and if the product is handled without adequate containment means: use full or half-face masks with filter for mists/aerosols (P). In case there is a significant presence of vapours (e.g. through handling at high temperature), use full or half-face masks with a filter for organic vapours (A), and H2S (B) where applicable. (EN 136/140/145). Combination filter device (DIN EN 141). Approved respiratory protection equipment shall be used in spaces where hydrogen sulphide may accumulate: full face mask with cartridge/filter type "B" (grey for inorganic vapours including H2S) or self-contained breathing apparatus (SCBA). (EN 136/140/145). Closed or confined areas (e.g. tank interiors): the use of protection measures for airways (masks or self-contained breathing apparatus), must be assessed according to the specific activity, as well as level and duration of predicted exposure.

Long-sleeved overalls. If necessary, refer to the EN 340 and related standards, for definition of characteristics and performance according to the risk rating of the area. Antistatic non-skid safety shoes or boots, chemical resistant, if necessary heat resistant and insulated.

Do not discharge the product into the environment. Storage areas/installations should be designed with adequate bunds so as to prevent ground and water pollution in case of leaks or spills. Prevent discharge of undissolved substance to or recover from onsite wastewater. Onsite wastewater treatment required. Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or reclaimed.

Stable product, according to its intrinsic properties.

This mixture does not offer any further hazard for reactivity, except what is reported in the following paragraphs.

None (in normal conditions of storage and handling). Contact with strong oxidizers (peroxides, chromates, etc.) or alkali metals may cause a fire hazard.

Sensitivity to heat, friction or shock cannot be assessed in advance.

strong oxidizers (peroxides, chromates, etc.) or alkali metals

Under normal conditions of storage and use, hazardous decomposition products should not be produced. Thermal decomposition generates : Carbon dioxide, Carbon monoxide, Toxic fumes. In exceptional cases (i.e prolonged storage in tanks contaminated with water, and presence of anaerobic sulfate-reducing microbial colonies), the product may undergo a degradation and generate small amounts of sulfur compounds, including H2S.