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Safety Data Sheet EN

LOCTITE UR S117 known as MACROPLAST SIA-117

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LOCTITE UR S117 known as MACROPLAST SIA-117

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Polyurethane adhesive

Uses advised against

This product is for industrial use only.

Manufacturers & Suppliers

Henkel Corporation logo

Henkel Corporation

manufacturer

One Henkel Way, Rocky Hill, Connecticut 06067

+1 (860) 571-5100

http://www.henkelina.com

Emergency Contacts

Poison Control Center

1-877-671-4608

Poison Control Center

1-303-592-1711

CHEMTREC

1-800-424-9300

CHEMTREC

1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4
Skin Irrit. Cat. 2
Eye Irrit. Cat. 2A
Resp. Sens. Cat. 1
Skin Sens. Cat. 1
STOT SE Cat. 3
STOT RE Cat. 1

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 CAUSES SKIN IRRITATION.
H317 MAY CAUSE AN ALLERGIC SKIN REACTION.
H319 CAUSES SERIOUS EYE IRRITATION.
H332 HARMFUL IF INHALED.
H334 MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335 MAY CAUSE RESPIRATORY IRRITATION.
H372 CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.

Precautionary Statements

P260 Do not breathe vapors, mist, or spray.
P264 Wash affected area thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves, eye protection, and face protection.
P284 [In case of inadequate ventilation] wear respiratory protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P337 + P313 If eye irritation persists: Get medical attention.
P342 + P311 If experiencing respiratory symptoms: Call a poison center or physician.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Oxirane, methyl-, polymer with oxirane, ether with 1,2,3-propanetriol (3:1), polymer with 1,1'-methylenebis[isocyanatobenzene] 112898-48-3 60 - 80% Yes
Methylene bisphenyl isocyanate 26447-40-5 10 - 30% Yes

Notes

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Symptoms: Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours.

Skin contact

Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. For severe exposures, get under safety shower after removing clothing. Wash clothing before reuse.

Symptoms: irritation

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Symptoms: Workplace vapors have produced reversible corneal epithelial edema impairing vision.

Ingestion

Do not induce vomiting. Never give anything by mouth to an unconscious person.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Eyes: Stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid preparation frequently. Skin: Treat symptomatically as for contact dermatitis or thermal burns. Respiratory: Treat symptomatically and supportively.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam, dry chemical or carbon dioxide.

Unsuitable media

Not available.

Specific hazards

Sealed containers at elevated temperatures or contaminated with water may rupture explosively. During a fire, MDI vapors and other irritating, highly toxic gases may be generated by thermal decomposition or combustion. At temperatures above 204.4°C (400°F), polymeric MDI can polymerize and decompose which can cause pressure build-up in closed containers. Explosive rupture is possible.

Instructions

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Firefighter Protection

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel.

Small spill

absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed containers, transport to well ventilated area (outside) and treat with neutralizing solution

Large spill

Large quantities may be pumped into closed, but not sealed containers for disposal.

Environmental

Do not allow product to enter sewer or waterways.

Cleanup methods

Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up.

Materials: sawdust or other absorbent

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Exposure to vapors of heated MDI can be extremely dangerous. Use only with adequate ventilation. Protect from moisture. Keep container closed. Employee education and training in the safe use and handling of this compound are required under the OSHA Hazard Communication Standard.

Storage

Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Store away from heat, sparks, flames, or other sources of ignition. Do not let moisture contaminate this material.

Hygiene

Wash thoroughly after handling.

Fire prevention

Store away from heat, sparks, flames, or other sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Off white
Colour Intensity
---
Form
---
Odor
Solvent
Odor Threshold
Not available.
Ph
Not applicable
Melting Point
Not available.
Boiling Point
Not determined
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Not determined
Vapor Density
---
Relative Density
1.1
Bulk Density
---
Density
---
Flammability
Not applicable
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
Not determined
Decomposition Temperature
Not available.
Solubility
Reacts slowly with water to liberate carbon dioxide gas.
Partition Coefficient
Not available.
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
0 g/l
Metal Corrosion
---
Dynamic Viscosity
4,000 - 6,500 cp
Kinematic Viscosity
Not available.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions of storage and use.

Reactivity

Not available.

Hazardous reactions

Contact with moisture, other materials that react with isocyanates, or temperatures above 350° F (177° C), may cause polymerization.

Avoid

Keep away from heat, ignition sources and incompatible materials. Contamination with water. Avoid moisture. Extremes of temperature and direct sunlight.

Incompatible

Water. Alcohols. Amines. Ammonia. Strong acids and strong bases.

Decomposition

Irritating organic vapours. Oxides of carbon. Oxides of nitrogen. Hydrogen cyanide. MDI vapors and aerosols. Isocyanates.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LOCTITE UR S117 known as MACROPLAST SIA-117?

The signal word is danger.

What is the physical form of LOCTITE UR S117 known as MACROPLAST SIA-117?

LOCTITE UR S117 known as MACROPLAST SIA-117 is a liquid with off white color. It has solvent odor.

What is the solubility of LOCTITE UR S117 known as MACROPLAST SIA-117?

Reacts slowly with water to liberate carbon dioxide gas.

What is LOCTITE UR S117 known as MACROPLAST SIA-117 used for?

Polyurethane adhesive

What are the hazard statements for LOCTITE UR S117 known as MACROPLAST SIA-117?

This substance has 7 hazard statements:

  • H315: CAUSES SKIN IRRITATION.
  • H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
  • H319: CAUSES SERIOUS EYE IRRITATION.
  • H332: HARMFUL IF INHALED.
  • H334: MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
  • H335: MAY CAUSE RESPIRATORY IRRITATION.
  • H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.

What is the melting point of LOCTITE UR S117 known as MACROPLAST SIA-117?

The melting point is Not available. and the boiling point is Not determined.