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Safety Data Sheet EN

LOCTITE UK 180 B 2-PART POLYURETHANE, PART B known as MACROPLAST UK 180B

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LOCTITE UK 180 B 2-PART POLYURETHANE, PART B known as MACROPLAST UK 180B
Product Code
1219068

Regulatory Identifiers

CAS Number
N/A

Identified Uses

2-Component polyurethane adhesive

Uses advised against

None identified

Manufacturers & Suppliers

Henkel Corporation logo

Henkel Corporation

manufacturer

One Henkel Way, Rocky Hill, Connecticut 06067

+1 (860) 571-5100

www.henkelna.com

Emergency Contacts

Poison Control Center

1-877-671-4608

Poison Control Center

1-303-592-1711

CHEMTREC

1-800-424-9300

CHEMTREC

1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4
Skin Irrit. Cat. 2
Eye Irrit. Cat. 2A
Resp. Sens. Cat. 1
Skin Sens. Cat. 1
STOT RE Cat. 1

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 CAUSES SKIN IRRITATION.
H317 MAY CAUSE AN ALLERGIC SKIN REACTION.
H319 CAUSES SERIOUS EYE IRRITATION.
H332 HARMFUL IF INHALED.
H334 MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H372 CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.

Precautionary Statements

P261 Do not breathe vapors, mist, or spray.
P264 Wash affected area thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves, eye protection, and face protection.
P285 In case of inadequate ventilation wear respiratory protection.
P304 + P341 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or physician if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P337 + P313 If eye irritation persists: Get medical attention.
P342 + P311 If experiencing respiratory symptoms: Call a poison center or physician.
P352 IF ON SKIN: Wash with plenty of water.
P362 Take off contaminated clothing.
P501 Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Methylenebis(phenylisocyanate) 101-68-8 60 - 100% No
Glyceridic oil --- 10 - 30% No
Methylene bisphenyl isocyanate 26447-40-5 0.1 - 1% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Symptoms: Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours.

Skin contact

Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. For severe exposures, get under safety shower after removing clothing. Wash clothing before reuse.

Symptoms: Irritation.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Symptoms: Workplace vapors have produced reversible corneal epithelial edema impairing vision.

Ingestion

Do not induce vomiting. Never give anything by mouth to an unconscious person.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Eyes: Stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid preparation frequently. Skin: Treat symptomatically as for contact dermatitis or thermal burns. Respiratory: Treat symptomatically and supportively.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam, dry chemical or carbon dioxide.

Unsuitable media

Water or fog may cause frothing which can be violent especially if sprayed into containers of hot or burning liquid.

Specific hazards

MDI vapors and other irritating, highly toxic gases may be generated by thermal decomposition or combustion. At temperatures above 204.4°C (400°F), polymeric MDI can polymerize and decompose which can cause pressure build-up in closed containers. Explosive rupture is possible. The product may undergo spontaneous polymerization at high temperatures. Polymerization is exothermic and may cause damage to the container and/or release of thermal decomposition products. Sealed containers at elevated temperatures or contaminated with water may rupture explosively.

Instructions

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Firefighter Protection

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

isolate the hazard area and deny entry to unnecessary and unprotected personnel. Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up.

Small spill

For minor spills, absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed containers, transport to well ventilated area (outside) and treat with neutralizing solution: mixture of 80% water and 20% non-ionic surfactant Tergitol TMN-10; or 90% water, 3-8% concentrated ammonia and 2% detergent. Add about ten parts of neutralizer per part of isocyanate, with mixing. Allow to stand uncovered for 48 hours to let carbon dioxide escape.

Large spill

Large quantities may be pumped into closed, but not sealed containers for disposal.

Environmental

Do not allow product to enter sewer or waterways.

Cleanup methods

absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed containers, transport to well ventilated area (outside) and treat with neutralizing solution

Materials: sawdust or other absorbent

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Exposure to vapors of heated MDI can be extremely dangerous. Use only with adequate ventilation. Protect from moisture. Keep container closed. Employee education and training in the safe use and handling of this compound are required under the OSHA Hazard Communication Standard.

Storage

Store between 16 °C (60.8 °F) and 37 °C (98.6 °F). Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Store away from heat, sparks, flames, or other sources of ignition. Store original or opened drums absolutely dry and always close it air-tight.

Hygiene

Wash thoroughly after handling.

Fire prevention

Store away from heat, sparks, flames, or other sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Brown
Colour Intensity
---
Form
---
Odor
Negligible
Odor Threshold
Not available.
Ph
Not applicable
Melting Point
Not determined
Boiling Point
204.4 °C (399.9 °F)(decomposition point)
Flash Point
> 110 °C (> 230°F) Setaflash Closed Cup
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not determined
Vapor Pressure
Not determined
Vapor Density
Not determined
Relative Density
Not determined
Bulk Density
---
Density
---
Flammability
Not applicable
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
Not determined
Decomposition Temperature
Not available.
Solubility
---
Partition Coefficient
Not determined
Solubility In Water
Reacts slowly with water to liberate carbon dioxide gas.
Solubility In Fat
---
Molecular Weight
---
Voc Content
Not available.
Metal Corrosion
---
Dynamic Viscosity
Not available.
Kinematic Viscosity
Not available.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions of storage and use.

Reactivity

Not available.

Hazardous reactions

Contact with moisture, other materials that react with isocyanates, or temperatures above 350°F (177°C), may cause polymerization. Uncontrolled polymerization may cause rapid evolution of heat and increase in pressure that could result in violent rupture of sealed storage vessels or containers.

Avoid

Avoid moisture. Container can be pressurised by carbon dioxide due to reaction with humid air and/or water. Prolonged heating at temperatures above 150°C. Protect from direct sunlight. Freezing conditions. Keep away from heat, ignition sources and incompatible materials. Contamination with water.

Incompatible

Amines. Alcohols. Acids. Bases. Reaction with water, formation of CO2

Decomposition

Oxides of carbon. Hydrogen cyanide. Oxides of nitrogen. Irritating organic vapours. Isocyanate vapors

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
RQ, Environmentally hazardous substance, liquid, n.o.s.
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LOCTITE UK 180 B 2-PART POLYURETHANE, PART B known as MACROPLAST UK 180B?

The signal word is danger.

What is the physical form of LOCTITE UK 180 B 2-PART POLYURETHANE, PART B known as MACROPLAST UK 180B?

LOCTITE UK 180 B 2-PART POLYURETHANE, PART B known as MACROPLAST UK 180B is a liquid with brown color. It has negligible odor.

What is LOCTITE UK 180 B 2-PART POLYURETHANE, PART B known as MACROPLAST UK 180B used for?

2-Component polyurethane adhesive

What are the hazard statements for LOCTITE UK 180 B 2-PART POLYURETHANE, PART B known as MACROPLAST UK 180B?

This substance has 6 hazard statements:

  • H315: CAUSES SKIN IRRITATION.
  • H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
  • H319: CAUSES SERIOUS EYE IRRITATION.
  • H332: HARMFUL IF INHALED.
  • H334: MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
  • H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.

What is the melting point of LOCTITE UK 180 B 2-PART POLYURETHANE, PART B known as MACROPLAST UK 180B?

The melting point is Not determined and the boiling point is 204.4 °C (399.9 °F)(decomposition point).