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Safety Data Sheet EN

LOCTITE 4204FL

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LOCTITE 4204FL
Product Code
2680645

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Cyanoacrylate

Uses advised against

None identified

Manufacturers & Suppliers

Henkel Corporation logo

Henkel Corporation

manufacturer

One Henkel Way, Rocky Hill, Connecticut 06067

+1 (860) 571-5100

http://www.henkelna.com

Emergency Contacts

Poison Control Center

1-877-671-4608

Poison Control Center

1-303-592-1711

CHEMTREC

1-800-424-9300

CHEMTREC

1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 4
Eye Irrit. Cat. 2B
STOT SE Cat. 3

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

EUH202 BONDS SKIN IN SECONDS.
H319 CAUSES EYE IRRITATION.
H335 MAY CAUSE RESPIRATORY IRRITATION.
COMBUSTIBLE LIQUID.

Precautionary Statements

P210 Keep away from heat, sparks, open flames, hot surfaces - no smoking.
P233 Keep container tightly closed.
P235 Keep cool.
P264 Wash affected area thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves, eye protection, and face protection.
P304 + P341 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312 Call a POISON CENTER or physician if you feel unwell.
P337 + P313 If eye irritation persists: Get medical attention.
P338 Remove contact lenses, if present and easy to do. Continue rinsing.
P351 IF IN EYES: Rinse cautiously with water for several minutes.
P370 + P378 In case of fire: Use foam, dry chemical or carbon dioxide to extinguish.
P403 Store in a well-ventilated place.
P405 Store locked up.
P501 Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.
Avoid breathing vapors, mist, or spray.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Ethyl 2-cyanoacrylate 7085-85-0 80 - 100% Yes
Treated fumed silica 67762-90-7 1 - 5% Yes
Phthalic anhydride 85-44-9 0.1 - 1% Yes

IDH number: 2680645 Product name: LOCTITE 4204FL

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms develop and persist, get medical attention.

Skin contact

Do not pull bonded skin apart. Soak in warm soapy water. Gently peel apart using a blunt instrument. If skin is burned due to the rapid generation of heat by a large drop, seek medical attention. If lips are bonded, apply warm water to the lips and encourage wetting and pressure from saliva in mouth. Peel or roll lips apart. Do not pull lips apart with direct opposing force.

Symptoms: Skin may be burned due to the rapid generation of heat by a large drop.

Eye contact

Immediately flush with plenty of water for at least 15 minutes. Get medical attention. If eyelids are bonded closed, release eyelashes with warm water by covering with a wet pad. Do not force eye open. Keep eye covered until debonding is complete, usually within 1-3 days. Medical attention should be sought in case solid particles of polymerized cyanoacrylate trapped behind the eyelid caused abrasive damage.

Symptoms: Cyanoacrylate will bond to eye protein and will cause a lachrymatory effect.

Ingestion

Ensure breathing passages are not obstructed. Saliva will separate any solidified product in several hours. Prevent the patient from swallowing any separated mass.

Symptoms: The product will polymerize rapidly and bond to the mouth making it almost impossible to swallow.

Immediate Medical Attention

If symptoms develop and persist, get medical attention. If skin is burned due to the rapid generation of heat by a large drop, seek medical attention. Medical attention should be sought in case solid particles of polymerized cyanoacrylate trapped behind the eyelid caused abrasive damage.

Medical Treatment

Surgery is not necessary to separate accidentally bonded tissues. Experience has shown that bonded tissues are best treated by passive, non-surgical first aid. If rapid curing has caused thermal burns they should be treated symptomatically after adhesive is removed.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray (fog), foam, dry chemical or carbon dioxide.

Instructions

Wear a self-contained breathing apparatus with a full face piece operated in pressure-demand or other positive pressure mode.

Firefighter Protection

Wear a self-contained breathing apparatus with a full face piece operated in pressure-demand or other positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Isolate the hazard area and deny entry to unnecessary and unprotected personnel.

Environmental

Ventilate area. Do not allow product to enter sewer or waterways.

Cleanup methods

Do not use cloths for mopping up. Flood with water to complete polymerization and scrape off the floor.

Materials: Water

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Avoid contact with fabric or paper goods. Contact with these materials may cause rapid polymerization which can generate smoke and strong irritating vapors, and cause thermal burns.

Storage

Not available.

Hygiene

Wash thoroughly after handling.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Colorless to light yellow
Colour Intensity
---
Form
---
Odor
Sharp
Odor Threshold
Not available.
Ph
Not available.
Melting Point
Not available.
Boiling Point
Not available.
Flash Point
80 - 93 °C (176°F - 199.4 °F) ASTM D3278
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Not available.
Vapor Density
Not available.
Relative Density
1.1 at 20 °C (68°F)
Bulk Density
---
Density
---
Flammability
Not applicable
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
Not available.
Solubility
---
Partition Coefficient
Not available.
Solubility In Water
Not available.
Solubility In Fat
---
Molecular Weight
---
Voc Content
< 2 %
Metal Corrosion
---
Dynamic Viscosity
Not available.
Kinematic Viscosity
Not available.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

Not available.

Hazardous reactions

Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and alcohols.

Avoid

Spontaneous polymerization.

Incompatible

Water, amines, alkalis and alcohols.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3334
Shipping Name
Aviation regulated liquid, n.o.s. (Cyanoacrylate ester)
Transport Class
9
Packing Group
III
IATA

Primary packs containing less than 500ml are unregulated by this mode of transport and may be shipped unrestricted.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LOCTITE 4204FL?

The signal word is warning.

What is the physical form of LOCTITE 4204FL?

LOCTITE 4204FL is a liquid with colorless to light yellow color. It has sharp odor.

What is LOCTITE 4204FL used for?

Cyanoacrylate

What are the hazard statements for LOCTITE 4204FL?

This substance has 4 hazard statements:

  • EUH202: BONDS SKIN IN SECONDS.
  • H319: CAUSES EYE IRRITATION.
  • H335: MAY CAUSE RESPIRATORY IRRITATION.
  • COMBUSTIBLE LIQUID.

What is the melting point of LOCTITE 4204FL?

The melting point is Not available. and the boiling point is Not available..