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Safety Data Sheet EN

Petroleum ether 40/60

CAS 64742-49-0
EC 931-254-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Petroleum ether 40/60
Product Code
L14649
Chemical Name
Petroleum ether 40/60
Synonyms
Ligroine

Regulatory Identifiers

CAS Number
64742-49-0 Check regulations →
EC Number
931-254-9 Check regulations →

Identified Uses

Laboratory chemicals, Sector of use: SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites, Product category: PC21 - Laboratory chemicals, Process categories: PROC15 - Use as a laboratory reagent, Environmental release category: ERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)

Uses advised against

No Information available

Manufacturers & Suppliers

T

Thermo Fisher (Kandel) GmbH

manufacturer

Erlenbachweg 2, 76870 Kandel, Germany

+49 (0) 721 84007 280

Fisher Scientific AG logo

Fisher Scientific AG

distributor

Neuhofstrasse 11, CH 4153 Reinach

+41 (0) 56 618 41 11

https://www.fishersci.ch/ch/en/customer-help-support/forms/email-us.html

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

Tox Info Suisse

145

24hr

Tox Info Suisse

+41-44 251 51 51

Chemtrec

0800 564 402

24h

Chemtrec

+41-43 508 20 11

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Asp. Tox. Cat. 1 H304
Skin Irrit. Cat. 2 H315
STOT SE Cat. 3 H336
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H225 Highly flammable liquid and vapor
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H336 May cause drowsiness or dizziness
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P280 Wear protective gloves/protective clothing
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P312 Call a POISON CENTER or doctor if you feel unwell

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Naphtha, petroleum, hydrotreated light EC: 931-254-9 64742-49-0 100% Yes
Hexane EC: 203-777-6 110-54-3 --- Yes

UVCB Hydrocarbons; C6, isoalkanes, < 5% n-Hexane; Reach Registration Number 01-2119484651-34

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Symptoms: Risk of serious damage to the lungs (by aspiration).

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Call a physician or poison control center immediately. If vomiting occurs naturally, have victim lean forward.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO₂, dry chemical, dry sand, alcohol-resistant foam. Water mist may be used to cool closed containers.

Unsuitable media

Do not use a solid water stream as it may scatter and spread fire.

Specific hazards

Flammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated. Thermal decomposition can lead to release of irritating gases and vapors.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required.

Environmental

Do not flush into surface water or sanitary sewer system.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place.

Hygiene

Handle in accordance with good industrial hygiene and safety practice.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Nitrile rubber, Viton (R). Breakthrough time: See manufacturers recommendations. EU standard: EN 374. Glove comments: (minimum requirement)

Eyes

Wear safety glasses with side shields (or goggles) (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: low boiling organic solvent Type AX Brown conforming to EN371. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141. When RPE is used a face piece Fit Test should be conducted

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure. Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination.

Environmental

Prevent product from entering drains. Do not allow material to contaminate ground water system.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Decomposition Temperature
No data available
Ph
No information available
Flash Point
-45 °C / -49 °F (Method - No information available)
Relative Density
---
Molecular Weight
---
Bulk Density
Not applicable
Lower Explosive Limit
1 vol%
Flammability
Highly flammable
Softening Point
---
Physical State
Liquid
Vapor Pressure
250 hPa @ 250 °C
Boiling Point
40 - 70 °C / 104 - 158 °F
Freezing Point
---
Cloud Point
---
Dynamic Viscosity
---
Physical State Data
liquid
Partition Coefficient
Hexane 4.11
Vapor Density
>1 @ 101 kPa (Air = 1.0)
Evaporation Rate
13 (Butyl acetate = 1.0)
Solubility In Fat
---
Melting Point
---
Solubility In Water
Insoluble
Solidification Point
---
Odor Threshold
No data available
Properties Status
---
Auto Ignition Temperature
230 °C / 446 °F
Upper Explosive Limit
7.4 vol%
Form
---
Voc Content
---
Odor
Petroleum distillates
Colour Intensity
---
Metal Corrosion
---
Relative Evaporation Rate
---
Density
0.65
Solubility
---
Colour
---
Appearance
Colorless
Crystallisation Point
---
Explosive Limits
---
State Under Standard Conditions
---
Kinematic Viscosity
0.45 mm2/s at 25 °C (ASTM D445)
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous Polymerization does not occur.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents.

Decomposition

Carbon monoxide (CO). Carbon dioxide (CO₂).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1268
Shipping Name
Petroleum distillates, n.o.s.
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Petroleum ether 40/60 known by?

Petroleum ether 40/60 is also known as: Ligroine

What is the hazard signal word for Petroleum ether 40/60?

The signal word is danger.

What is the physical form of Petroleum ether 40/60?

Petroleum ether 40/60 is a liquid appearing as colorless . It has petroleum distillates odor.

What is Petroleum ether 40/60 used for?

Laboratory chemicals, Sector of use: SU3 - Industrial uses: Uses of substances as such or in preparations at industrial sites, Product category: PC21 - Laboratory chemicals, Process categories: PROC15 - Use as a laboratory reagent, Environmental release category: ERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)

What are the hazard statements for Petroleum ether 40/60?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H304: May be fatal if swallowed and enters airways
  • H315: Causes skin irritation
  • H336: May cause drowsiness or dizziness
  • H411: Toxic to aquatic life with long lasting effects