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Safety Data Sheet EN

Petroleum ether

CAS 64742-49-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Petroleum ether
Product Code
32247

Regulatory Identifiers

CAS Number
64742-49-0 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Laboratory chemicals, Manufacture of substances

Uses advised against

For R&D use only. Not for pharmaceutical, household or other uses.

Manufacturers & Suppliers

M

Merck Life Science BV/SRL

manufacturer

Brusselsesteenweg 288, B-3090 OVERIJSE

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Skin Irrit. Cat. 2 H315
Muta. Cat. 1B H340
Carc. Cat. 1B H350
Asp. Tox. Cat. 1 H304

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H340 May cause genetic defects.
H350 May cause cancer.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P331 Do NOT induce vomiting.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Naphtha (petroleum), hydrotreated light EC: 265-151-9 64742-49-0 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: caution if victim vomits. Keep airways free. Call a physician immediately.

Symptoms: Risk of aspiration! Pulmonary failure possible after aspiration of vomit.

Immediate Medical Attention

Call in physician. Call in ophthalmologist. Call a physician immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

alcohol resistant foam, dry chemical powder or carbon dioxide.

Unsuitable media

Large amounts of water are ineffective.

Specific hazards

Combustible. Pay attention to flashback. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures.

Instructions

Cool containers with large amounts of water.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Take up carefully with liquid-absorbent material. Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
clear, liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colorless
Colour Intensity
---
Form
---
Odor
No data available
Odor Threshold
---
Ph
No data available
Melting Point
Melting point/range: < -80 °C - (External MSDS)
Boiling Point
50 - 70 °C
Flash Point
< -40 °C at ca.1.013,25 hPa - closed cup - ASTM D 56
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
<= 2.400 hPa at 37,8 °C
Vapor Density
---
Relative Density
0,62 - 0,88 at 15 °C
Bulk Density
---
Density
0,664 g/cm3 at 15 °C
Flammability
No data available
Upper Explosive Limit
7 %(V)
Lower Explosive Limit
1 %(V)
Explosive Limits
---
Auto Ignition Temperature
245 °C
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
No data available
Solubility In Water
immiscible
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature). Stable under recommended storage conditions.

Reactivity

Vapors may form explosive mixture with air.

Hazardous reactions

No data available

Avoid

Heat, flames and sparks. Extremes of temperature and direct sunlight. Warming.

Incompatible

Oxidizing agents, Strong oxidizing agents

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1268
Shipping Name
PETROLEUM DISTILLATES, N.O.S.
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Petroleum ether?

The signal word is danger.

What is the physical form of Petroleum ether?

Petroleum ether is a clear, liquid with colorless color. It has no data available odor.

What is Petroleum ether used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Petroleum ether?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapor.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H340: May cause genetic defects.
  • H350: May cause cancer.

What is the melting point of Petroleum ether?

The melting point is Melting point/range: < -80 °C - (External MSDS) and the boiling point is 50 - 70 °C.