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Safety Data Sheet EN

tri-Potassium citrate monohydrate suitable for use as excipient EMPROVE® exp Ph Eur,BP,USP,FCC,E 332

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
tri-Potassium citrate monohydrate suitable for use as excipient EMPROVE® exp Ph Eur,BP,USP,FCC,E 332
Product Code
104956

Regulatory Identifiers

CAS Number
N/A
REACH No.
A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) No 1907/2006, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

Identified Uses

Pharmaceutical production, Cosmetic raw material

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

64271 Darmstadt, Germany

+49 6151 72-0

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Not Classified

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Formula: C₆H₈K₃O₇ * H₂O (Hill); Molar mass: 324,42 g/mol; CAS-No. 6100-05-6; EC-No. 212-755-5

Chemical Name CAS Number Concentration Hazardous
tri-Potassium citrate monohydrate suitable for use as excipient EMPROVE® exp Ph Eur,BP,USP,FCC,E 332 EC: 212-755-5 6100-05-6 --- No

The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air.

Skin contact

wash off with plenty of water. Remove contaminated clothing.

Eye contact

rinse out with plenty of water.

Ingestion

make victim drink water (two glasses at most). Consult doctor if feeling unwell.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Carbon dioxide (CO2), Foam, Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Development of hazardous combustion gases or vapours possible in the event of fire.

Firefighter Protection

In the event of fire, wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not empty into drains.

Cleanup methods

Take up dry. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Observe label precautions.

Storage

Tightly closed. Dry.

Hygiene

Change contaminated clothing. Wash hands after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, Break through time: > 480 min; splash contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, Break through time: > 480 min. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 741 Dermatrill® L (full contact), KCL 741 Dermatrill® L (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Safety glasses

Respiratory

required when dusts are generated. Recommended Filter type: P1 filter. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Environmental

Do not empty into drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
white
Colour Intensity
---
Form
solid
Odor
odourless
Odor Threshold
No information available.
Ph
7,5 - 9,0 at 50 g/l 20 °C
Melting Point
> 180 °C Elimination of water of crystallisation
Boiling Point
No information available.
Flash Point
No information available.
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No information available.
Vapor Pressure
No information available.
Vapor Density
---
Relative Density
1,98 g/cm³ at 20 °C
Bulk Density
ca.950 kg/m³
Density
---
Flammability
---
Upper Explosive Limit
No information available.
Lower Explosive Limit
No information available.
Explosive Limits
---
Auto Ignition Temperature
No information available.
Decomposition Temperature
> 230 °C
Solubility
---
Partition Coefficient
log Pow: -0,28 (calculated) (anhydrous substance)
Solubility In Water
640 g/l at 25 °C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No information available.
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Hazardous reactions

no information available

Avoid

Strong heating (decomposition).

Incompatible

no information available

Decomposition

no information available

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for tri-Potassium citrate monohydrate suitable for use as excipient EMPROVE® exp Ph Eur,BP,USP,FCC,E 332?

The signal word is no signal word.

What is the physical form of tri-Potassium citrate monohydrate suitable for use as excipient EMPROVE® exp Ph Eur,BP,USP,FCC,E 332?

tri-Potassium citrate monohydrate suitable for use as excipient EMPROVE® exp Ph Eur,BP,USP,FCC,E 332 is a solid with white color. It has odourless odor.

What is tri-Potassium citrate monohydrate suitable for use as excipient EMPROVE® exp Ph Eur,BP,USP,FCC,E 332 used for?

Pharmaceutical production, Cosmetic raw material

What is the melting point of tri-Potassium citrate monohydrate suitable for use as excipient EMPROVE® exp Ph Eur,BP,USP,FCC,E 332?

The melting point is > 180 °C Elimination of water of crystallisation and the boiling point is No information available..