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Safety Data Sheet EN

3,3'-Diaminobenzidine tetrahydrochloride hydrate

CAS 868272-85-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
3,3'-Diaminobenzidine tetrahydrochloride hydrate
Product Code
D5637
Chemical Name
3,3'-Diaminobenzidine tetrahydrochloride hydrate

Regulatory Identifiers

CAS Number
868272-85-9 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration or the annual tonnage does not require a registration.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

S

Sigma

manufacturer

M

Merck Life Science BV

distributor

Ildefonse Vandammestraat 5/7B, B-1560 HOEILAART

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Eye Irrit. Cat. 2 H319
Muta. Cat. 2 H341
Carc. Cat. 1B H350

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H341 Suspected of causing genetic defects.
H350 May cause cancer.

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Biphenyl-3,3',4,4'-tetrayltetraammonium tetrachloride EC: 231-018-9 868272-85-9 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Foam, Carbon dioxide (CO2), Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas. Combustible. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P3. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solubility In Water
soluble
Flash Point
---
Crystallisation Point
---
Ph
---
Evaporation Rate
---
Density
---
Appearance
---
Relative Density
---
Boiling Point
---
Lower Explosive Limit
---
Odor
No data available
Physical State
powder
Decomposition Temperature
---
Properties Status
---
Softening Point
---
Cloud Point
---
Molecular Weight
---
Freezing Point
---
Form
---
Odor Threshold
---
Solidification Point
---
Flammability
---
Melting Point
Melting point/ range: 280 °C
Colour Intensity
---
Solubility
---
Auto Ignition Temperature
---
Vapor Density
---
Colour
off-white
Upper Explosive Limit
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Bulk Density
---
Partition Coefficient
log Pow: 1,232 - Bioaccumulation is not expected. n-octanol/water
Explosive Limits
---
Relative Evaporation Rate
---
State Under Standard Conditions
---
Physical State Data
solid
Kinematic Viscosity
No data available
Voc Content
---
Vapor Pressure
---
Solubility In Fat
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Hazardous reactions

No data available

Avoid

Exposure to light may affect product quality. Exposure to moisture may affect product quality.

Incompatible

Strong oxidizing agents

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 3,3'-Diaminobenzidine tetrahydrochloride hydrate?

The signal word is danger.

What is the physical form of 3,3'-Diaminobenzidine tetrahydrochloride hydrate?

3,3'-Diaminobenzidine tetrahydrochloride hydrate is a powder with off-white color. It has no data available odor.

What is 3,3'-Diaminobenzidine tetrahydrochloride hydrate used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for 3,3'-Diaminobenzidine tetrahydrochloride hydrate?

This substance has 4 hazard statements:

  • H302: Harmful if swallowed.
  • H319: Causes serious eye irritation.
  • H341: Suspected of causing genetic defects.
  • H350: May cause cancer.

What is the melting point of 3,3'-Diaminobenzidine tetrahydrochloride hydrate?

The melting point is Melting point/ range: 280 °C .