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Safety Data Sheet EN

4-Bromo-3-methylaniline

CAS 6933-10-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
4-Bromo-3-methylaniline
Product Code
167500000; 167500100; 167500500; 167502500
Chemical Name
4-Bromo-3-methylaniline
Synonyms
4-Bromo-m-toluidine

Regulatory Identifiers

CAS Number
6933-10-4 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

T

Thermo Fisher Scientific

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

F

Fisher Scientific UK

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

F

Fisher Scientific AG

distributor

Neuhofstrasse 11, CH 4153 Reinach

+41 (0) 56 618 41 11

Emergency Contacts

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

Tox Info Suisse

145

24hr

Tox Info Suisse

+41-44 251 51 51

Chemtrec

0800 564 402

24h

Chemtrec

+41-43 508 20 11

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
STOT SE Cat. 3 H335

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
4-Bromo-m-toluidine EC: 230-056-3 6933-10-4 95% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required. If not breathing, give artificial respiration.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable media

No information available.

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Should not be released into the environment. See Section 12 for additional Ecological Information.

Cleanup methods

Sweep up and shovel into suitable containers for disposal.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use only under a chemical fume hood. Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation.

Storage

Keep container tightly closed in a dry and well-ventilated place.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source

Hands

Protective gloves. Glove material: Natural rubber, Nitrile rubber, Neoprene, PVC. Breakthrough time: See manufacturers recommendations. EU standard: EN 374. Glove comments: (minimum requirement)

Eyes

Wear safety glasses with side shields (or goggles) Goggles (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Particulates filter conforming to EN 143. Small scale/Laboratory use: Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask: Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141. When RPE is used a face piece Fit Test should be conducted.

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure. Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatibility, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination.

Environmental

No information available.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Crystallisation Point
---
Solubility In Water
Insoluble
Boiling Point
240 °C / 464 °F @ 760 mmHg
Odor Threshold
No data available
Solidification Point
---
Evaporation Rate
Not applicable - Solid
Flammability
No information available
Kinematic Viscosity
---
Appearance
---
Ph
No data available
Freezing Point
---
Bulk Density
No data available
Flash Point
No data available
Upper Explosive Limit
---
Relative Evaporation Rate
---
Solubility
Insoluble
Auto Ignition Temperature
No data available
Metal Corrosion
---
Density
No data available
State Under Standard Conditions
---
Molecular Weight
186.05
Vapor Density
Not applicable
Physical State
Solid
Colour Intensity
---
Explosive Limits
---
Properties Status
---
Partition Coefficient
---
Lower Explosive Limit
---
Voc Content
---
Odor
Characteristic
Physical State Data
solid
Cloud Point
---
Form
---
Softening Point
No data available
Melting Point
79 - 83 °C / 174.2 - 181.4 °F
Relative Density
---
Vapor Pressure
No data available
Solubility In Fat
---
Colour
---
Decomposition Temperature
No data available
Dynamic Viscosity
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous Polymerization: No information available. Hazardous Reactions: None under normal processing.

Avoid

Incompatible products. Excess heat. Avoid dust formation.

Incompatible

Strong oxidizing agents. Strong acids.

Decomposition

Carbon monoxide (CO). Carbon dioxide (CO₂). Nitrogen oxides (NOx). Hydrogen bromide.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2811
Shipping Name
Toxic solid, organic, n.o.s.
Transport Class
6.1
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 4-Bromo-3-methylaniline known by?

4-Bromo-3-methylaniline is also known as: 4-Bromo-m-toluidine

What is the hazard signal word for 4-Bromo-3-methylaniline?

The signal word is warning.

What is the physical form of 4-Bromo-3-methylaniline?

4-Bromo-3-methylaniline is a solid . It has characteristic odor.

What is the solubility of 4-Bromo-3-methylaniline?

Insoluble

What is 4-Bromo-3-methylaniline used for?

Laboratory chemicals.

What are the hazard statements for 4-Bromo-3-methylaniline?

This substance has 4 hazard statements:

  • H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
  • H315: Causes skin irritation
  • H319: Causes serious eye irritation
  • H335: May cause respiratory irritation

What is the melting point of 4-Bromo-3-methylaniline?

The melting point is 79 - 83 °C / 174.2 - 181.4 °F and the boiling point is 240 °C / 464 °F @ 760 mmHg.