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Safety Data Sheet EN

Non-Spillable Lead Acid Battery

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Non-Spillable Lead Acid Battery
Synonyms
Industrial Battery, Traction Battery, Stationary Battery, Deep Cycle Battery

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

H

Hawker Powersource

manufacturer

P.O. Box 808, Ooltewah, TN 37363

423-238-0361

H

Hawker Powersource Canada Corporate Office

manufacturer

3-61 Parr Boulevard, Bolton, Ontario, L7E 4E3

423-238-0361

Emergency Contacts

Hawker Powersource, Inc. Environmental, Health & Safety Dept.

423-238-0361

CHEMTREC

800-424-9300

CHEMTREC

703-527-3877

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4
Skin Corr. Cat. 1A
Eye Dam. Cat. 1
Repr. Cat. 1A
Carc. Cat. 1B
Carc. Cat. 1A
Carc. Cat. 1A
STOT RE Cat. 2
Aquatic Chronic Cat. 1
Aquatic Acute Cat. 1
Expl. Cat. 3

GHS Pictograms

GHS01 - Explosive

GHS01

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H203 Explosive, fire, blast, or projection hazard.
H242 May form explosive air/gas mixture during charging.
H302 + H312 + H332 Harmful if swallowed, inhaled, or contact with skin
H314 Causes severe skin burns and serious eye damage.
H318 Causes skin irritation, serious eye damage.
H350 May cause cancer if ingested or inhaled.
H360 May damage fertility or the unborn child if ingested or inhaled.
H362 May cause harm to breast-fed children
H372 Causes damage to central nervous system, blood and kidneys through prolonged or repeated exposure.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood
P210 Keep away from heat./sparks/open flames/hot surfaces. No smoking
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P261 Irritating to eyes, respiratory system, and skin.
P263 Avoid contact during pregnancy/while nursing
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing, eye protection/face protection.
P280 Contact with internal components may cause irritation or severe burns. Avoid contact with internal acid.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Inorganic lead and electrolyte (sulfuric acid) are the primary components of every battery manufactured by Hawker. Other ingredients may be present dependent upon battery type. Contact your Hawker representative for additional information.

Chemical Name CAS Number Concentration Hazardous
Polyvinylchloride 9002-86-2 --- No
Polycarbonate, Hard Rubber, Polyethylene 9002-88-4 --- No
Silicon Dioxide (Gel batteries only) 7631-86-9 1 - 5% No
Sheet Molding Compound (Glass reinforced polyester) --- --- No
* Antimony 7440-36-0 2% No
* Arsenic 7440-38-2 0.2% No
* Calcium 7440-70-2 0.04% No
* Tin 7440-31-5 0.2% No
Electrolyte (Sulfuric Acid (H2SO4/H2O)) 7664-93-9 10 - 30% No
Case Material: --- 5 - 10% No
Lead 7439-92-1 45 - 60% No
Lead Dioxide 1309-60-0 15 - 25% No
Polypropylene 9003-07-0 --- No
Polystyrene 9003-53-6 --- No
Styrene Acrylonitrile 9003-54-7 --- No
Acrylonitrile Butadiene Styrene 9003-56-9 --- No
Styrene Butadiene 9003-55-8 --- No

Notes

Other ingredients may be present dependent upon battery type. Contact your Hawker representative for additional information.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Sulfuric Acid: Remove to fresh air immediately. If breathing is difficult, give oxygen. Consult a physician. Lead: Remove from exposure, gargle, wash nose and lips; consult physician.

Skin contact

Sulfuric Acid: Flush with large amounts of water for at least 15 minutes; remove contaminated clothing completely, including shoes. If symptoms persist, seek medical attention. Wash contaminated clothing before reuse. Discard contaminated shoes. Lead: Wash immediately with soap and water.

Eye contact

Sulfuric Acid and Lead: Flush immediately with large amounts of water for a least 15 minutes while lifting lids. Seek immediate medical attention if eyes have been exposed directly to acid.

Ingestion

Sulfuric Acid: Give large quantities of water; do not induce vomiting or aspiration into the lungs may occur and can cause permanent injury or death; consult a physician. Lead: Consult physician immediately.

Immediate Medical Attention

Consult a physician for all exposure routes. Seek immediate medical attention if eyes have been exposed directly to acid.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2; foam; dry chemical. Use appropriate media for surrounding fire.

Unsuitable media

Do not use carbon dioxide directly on cells.

Specific hazards

Highly flammable hydrogen gas is generated during charging and operation of batteries. Water applied to electrolyte generates heat and causes it to spatter. Strings of series connected batteries may still pose risk of electric shock even when charging equipment is shut down.

Instructions

If batteries are on charge, shut off power. Keep sparks or other sources of ignition away from batteries. Do not allow metallic materials to simultaneously contact negative and positive terminals of cells and batteries. Follow manufacturer's instructions for installation and service.

Firefighter Protection

Use positive pressure, self-contained breathing apparatus. Wear acid-resistant clothing, gloves, face and eye protection. Avoid breathing vapors.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Stop flow of material, contain/absorb small spills with dry sand, earth, and vermiculite. Do not use combustible materials. If possible, carefully neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc.

Small spill

contain/absorb small spills with dry sand, earth, and vermiculite

Environmental

Acid must be managed in accordance with local, state, and federal requirements. Consult state environmental agency and/or federal EPA.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Unless involved in recycling operations, do not breach the casing or empty the contents of the battery. Handle carefully and avoid tipping, which may allow electrolyte leakage. Keep containers tightly closed when not in use. If battery case is broken, avoid contact with internal components. Keep vent caps on and cover terminals to prevent short circuits. Place cardboard between layers of stacked automotive batteries to avoid damage and short circuits. Use banding or stretch wrap to secure items for shipping. Wear face and eye protection when near batteries being charged.

Storage

Store batteries in cool, dry, well-ventilated areas with impervious surfaces and adequate containment in the event of spills. Batteries should also be stored under roof for protection against adverse weather conditions. Separate from incompatible materials.

Hygiene

Prohibit smoking.

Fire prevention

Keep away from fire, sparks and heat. Prohibit smoking and avoid creation of flames and sparks nearby.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Decomposition Temperature
---
Kinematic Viscosity
---
Crystallisation Point
---
Flammability
---
Physical State
liquid
Melting Point
---
Relative Evaporation Rate
---
Softening Point
---
Bulk Density
---
Freezing Point
---
Odor
sharp, penetrating, pungent odor
Metal Corrosion
---
Physical State Data
liquid
Odor Threshold
---
Relative Density
1.215 to 1.350
Solubility In Water
100%
Solubility In Fat
---
Cloud Point
---
State Under Standard Conditions
---
Auto Ignition Temperature
---
Dynamic Viscosity
---
Solubility
---
Vapor Density
Greater than 1 (AIR = 1)
Colour
---
Form
---
Voc Content
---
Flash Point
Below room temperature (as hydrogen gas)
Lower Explosive Limit
4.1% (Hydrogen)
Solidification Point
---
Properties Status
---
Colour Intensity
---
Boiling Point
203 - 240° F
Ph
~1 to 2
Explosive Limits
---
Density
---
Appearance
Manufactured article: no apparent odor. Electrolyte is a clear liquid with a sharp, penetrating, pungent odor.
Vapor Pressure
10 mm Hg
Molecular Weight
---
Partition Coefficient
---
Evaporation Rate
Less than 1 (Butyl Acetate = 1)
Upper Explosive Limit
74.2% (Hydrogen)
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

This product is stable under normal conditions at ambient temperature.

Hazardous reactions

Will not occur

Avoid

Prolonged overcharge; sources of ignition

Incompatible

Sulfuric Acid: combustibles, organic materials, strong reducing agents, metals, sulfur trioxide gas, strong oxidizers, water. Lead Compounds: strong acids, bases, halides, halogenates, potassium nitrate, permanganate, peroxides, nascent hydrogen, reducing agents. Arsenic compounds: strong oxidizers; bromine azide.

Decomposition

Sulfuric Acid: Sulfur trioxide, carbon monoxide, sulfuric acid mist, sulfur dioxide, and hydrogen sulfide. Lead Compounds: toxic metal fume, vapor, or dust; arsine gas.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2800
Shipping Name
BATTERIES, WET, NON-SPILLABLE
Transport Class
8
IMDG

Battery terminals must be protected against short circuits.

IATA

Battery Terminals must be protected against short Circuits. The words " NOT RESTRICTED" , SPECIAL PROVISION A67" must be provided on an airway bill when air waybill is issued.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Non-Spillable Lead Acid Battery known by?

Non-Spillable Lead Acid Battery is also known as: Industrial Battery, Traction Battery, Stationary Battery, Deep Cycle Battery

What is the hazard signal word for Non-Spillable Lead Acid Battery?

The signal word is danger.

What is the physical form of Non-Spillable Lead Acid Battery?

Non-Spillable Lead Acid Battery is a liquid appearing as manufactured article: no apparent odor. electrolyte is a clear liquid with a sharp, penetrating, pungent odor. . It has sharp, penetrating, pungent odor odor.

What are the hazard statements for Non-Spillable Lead Acid Battery?

This substance has 9 hazard statements:

  • H203: Explosive, fire, blast, or projection hazard.
  • H242: May form explosive air/gas mixture during charging.
  • H302 + H312 + H332: Harmful if swallowed, inhaled, or contact with skin
  • H314: Causes severe skin burns and serious eye damage.
  • H318: Causes skin irritation, serious eye damage.
  • H350: May cause cancer if ingested or inhaled.
  • H360: May damage fertility or the unborn child if ingested or inhaled.
  • H362: May cause harm to breast-fed children
  • H372: Causes damage to central nervous system, blood and kidneys through prolonged or repeated exposure.