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Safety Data Sheet EN

Non-Spillable Lead Acid Battery

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Non-Spillable Lead Acid Battery
Chemical Name
Electric Storage Battery
Synonyms
Industrial Battery, Traction Battery, Stationary Battery, Deep Cycle Battery

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

E

EnerSys

manufacturer

P.O. Box 14145 2366 Bernville Road Reading, PA 19612-4145

E

EnerSys

manufacturer

3-61 Parr Boulevard Bolton, Ontario L7E 4E3

Emergency Contacts

EnerSys' Environmental, Health & Safety Dept.

610-208-1996

CHEMTREC

800-424-9300

24-Hour

CHEMTREC

703-527-3877

24-Hour

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4
Skin Corr. Cat. 1A
Eye Dam. Cat. 1
Repr. Cat. 1A
Carc. Cat. 1B
Carc. Cat. 1A
Carc. Cat. 1A
STOT RE Cat. 2
Aquatic Chronic Cat. 1
Aquatic Acute Cat. 1
Expl. Cat. 1.3

GHS Pictograms

GHS01 - Explosive

GHS01

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H362 May cause harm to breast-fed children
Causes severe skin burns and serious eye damage.
May damage fertility or the unborn child if ingested or inhaled.
May cause cancer if ingested or inhaled.
Causes damage to central nervous system, blood and kidneys through prolonged or repeated exposure.
May form explosive air/gas mixture during charging.
Explosive, fire, blast, or projection hazard.
Harmful if swallowed, inhaled, or contact with skin
Causes skin irritation, serious eye damage.

Precautionary Statements

Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear protective gloves/protective clothing, eye protection/face protection.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Contact with internal components may cause irritation or severe burns. Avoid contact with internal acid.
Irritating to eyes, respiratory system, and skin.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood
Avoid contact during pregnancy/while nursing
Keep away from heat./sparks/open flames/hot surfaces. No smoking

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Inorganic lead and electrolyte (sulfuric acid) are the primary components of every battery manufactured by EnerSys. Other ingredients may be present dependent upon battery type.

Chemical Name CAS Number Concentration Hazardous
Lead 7439-92-1 45 - 60% No
Lead Dioxide 1309-60-0 15 - 25% No
Antimony 7440-36-0 2% No
Arsenic 7440-38-2 0.2% No
Calcium 7440-70-2 0.04% No
Tin 7440-31-5 0.2% No
Electrolyte (Sulfuric Acid (H2SO4/H2O)) 7664-93-9 10 - 30% No
Polypropylene 9003-07-0 5 - 10% No
Polystyrene 9003-53-6 5 - 10% No
Styrene Acrylonitrile 9003-54-7 5 - 10% No
Acrylonitrile Butadiene Styrene 9003-56-9 5 - 10% No
Styrene Butadiene 9003-55-8 5 - 10% No
Polyvinylchloride 9002-86-2 5 - 10% No
Polycarbonate, Hard Rubber, Polyethylene 9002-88-4 5 - 10% No
Silicon Dioxide (Gel batteries only) 7631-86-9 1 - 5% No
N/A --- --- No

Contact your EnerSys representative for additional information.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Sulfuric Acid: Remove to fresh air immediately. If breathing is difficult, give oxygen. Consult a physician. Lead: Remove from exposure, gargle, wash nose and lips; consult physician.

Skin contact

Sulfuric Acid: Flush with large amounts of water for at least 15 minutes; remove contaminated clothing completely, including shoes. If symptoms persist, seek medical attention. Wash contaminated clothing before reuse. Discard contaminated shoes. Lead: Wash immediately with soap and water.

Eye contact

Flush immediately with large amounts of water for at least 15 minutes while lifting lids.

Ingestion

Sulfuric Acid: Give large quantities of water; consult a physician. Lead: Consult physician immediately.

Immediate Medical Attention

Consult physician immediately for Lead ingestion. Seek immediate medical attention if eyes have been exposed directly to acid. If skin symptoms persist (Sulfuric Acid), seek medical attention.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2; foam; dry chemical. Use appropriate media for surrounding fire.

Unsuitable media

Do not use carbon dioxide directly on cells. Water applied to electrolyte generates heat and causes it to spatter.

Specific hazards

Highly flammable hydrogen gas is generated during charging and operation of batteries. To avoid risk of fire or explosion, keep sparks or other sources of ignition away from batteries. Do not allow metallic materials to simultaneously contact negative and positive terminals of cells and batteries.

Instructions

If batteries are on charge, shut off power. But note that strings of series connected batteries may still pose risk of electric shock even when charging equipment is shut down. Follow manufacturer's instructions for installation and service.

Firefighter Protection

Use positive pressure, self-contained breathing apparatus. Wear acid-resistant clothing, gloves, face and eye protection.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Stop flow of material, contain/absorb small spills with dry sand, earth, and vermiculite. Do not use combustible materials. If possible, carefully neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc.

Small spill

contain/absorb small spills with dry sand, earth, and vermiculite.

Environmental

Acid must be managed in accordance with local, state, and federal requirements.

Cleanup methods

Stop flow of material, contain/absorb small spills with dry sand, earth, and vermiculite. If possible, carefully neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc.

Materials: dry sand, earth, and vermiculite; soda ash, sodium bicarbonate, lime, etc.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Unless involved in recycling operations, do not breach the casing or empty the contents of the battery. Handle carefully and avoid tipping, which may allow electrolyte leakage. There may be increasing risk of electric shock from strings of connected batteries. Keep containers tightly closed when not in use. If battery case is broken, avoid contact with internal components. Keep vent caps on and cover terminals to prevent short circuits. Place cardboard between layers of stacked automotive batteries to avoid damage and short circuits. Shut-off power to chargers whenever not in use and before detachment of any circuit connections. Keep battery vent caps in position. Wear face and eye protection when near batteries being charged.

Storage

Store batteries in cool, dry, well-ventilated areas with impervious surfaces and adequate containment in the event of spills. Batteries should also be stored under roof for protection against adverse weather conditions.

Fire prevention

Keep away from fire, sparks and heat. Prohibit smoking and avoid creation of flames and sparks nearby.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Store and handle in well-ventilated area. If mechanical ventilation is used, components must be acid-resistant. Handle batteries cautiously to avoid spills. Make certain vent caps are on securely. Avoid contact with internal components. Do not allow metallic materials to simultaneously contact both the positive and negative terminals of the batteries. Charge the batteries in areas with adequate ventilation. General dilution ventilation is acceptable.

Hands

If battery case is damaged, use rubber or plastic acid-resistant gloves with elbow-length gauntlet.

Eyes

If battery case is damaged, use chemical goggles or face shield. Face shield recommended when adding water or electrolyte to batteries.

Respiratory

None required under normal conditions. When concentrations of sulfuric acid mist are known to exceed the PEL, use NIOSH or MSHA-approved respiratory protection.

Skin/Body

If battery case is damaged, use acid-resistant apron, clothing and boots. Under severe exposure emergency conditions, wear acid-resistant clothing and boots.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Manufactured article; Electrolyte is a clear liquid
Colour
clear
Colour Intensity
---
Form
liquid
Odor
sharp, penetrating, pungent odor
Odor Threshold
---
Ph
~1 to 2
Melting Point
---
Boiling Point
203 - 240° F
Flash Point
Below room temperature (as hydrogen gas)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
Less than 1
Evaporation Rate
Less than 1 (Butyl Acetate = 1)
Vapor Pressure
10 mm Hg
Vapor Density
Greater than 1 (AIR = 1)
Relative Density
1.215 to 1.350
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
74.2% (Hydrogen)
Lower Explosive Limit
4.1% (Hydrogen)
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
100%
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable. This product is stable under normal conditions at ambient temperature.

Reactivity

Sulfuric Acid: Reacts violently with strong reducing agents, metals, sulfur trioxide gas, strong oxidizers and water. Contact with metals may produce toxic sulfur dioxide fumes and may release flammable hydrogen gas. Lead Compounds: Hydrogen gas can react with inorganic arsenic to form the highly toxic gas-arsine.

Hazardous reactions

Will not occur. Contact with combustibles and organic materials may cause fire and explosion.

Avoid

Prolonged overcharge; sources of ignition

Incompatible

Sulfuric Acid: Combustibles and organic materials, strong reducing agents, metals, sulfur trioxide gas, strong oxidizers and water. Lead Compounds: Strong acids, bases, halides, halogenates, potassium nitrate, permanganate, peroxides, nascent hydrogen and reducing agents. Arsenic compounds: Strong oxidizers; bromine azide.

Decomposition

Sulfuric Acid: Sulfur trioxide, carbon monoxide, sulfuric acid mist, sulfur dioxide, and hydrogen sulfide. Lead Compounds: High temperatures likely to produce toxic metal fume, vapor, or dust; contact with strong acid or base or presence of nascent hydrogen may generate highly toxic arsine gas.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

neutralized slurry; neutralization and testing

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2800
Shipping Name
BATTERIES, WET, NON-SPILLABLE
Transport Class
8
IMDG

Battery terminals must be protected against short circuits.

IATA

Battery Terminals must be protected against short circuits.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Non-Spillable Lead Acid Battery known by?

Non-Spillable Lead Acid Battery is also known as: Industrial Battery, Traction Battery, Stationary Battery, Deep Cycle Battery

What is the hazard signal word for Non-Spillable Lead Acid Battery?

The signal word is danger.

What is the physical form of Non-Spillable Lead Acid Battery?

Non-Spillable Lead Acid Battery is a liquid appearing as manufactured article; electrolyte is a clear liquid with clear color. It has sharp, penetrating, pungent odor odor.

What are the hazard statements for Non-Spillable Lead Acid Battery?

This substance has 9 hazard statements:

  • H362: May cause harm to breast-fed children
  • Causes severe skin burns and serious eye damage.
  • May damage fertility or the unborn child if ingested or inhaled.
  • May cause cancer if ingested or inhaled.
  • Causes damage to central nervous system, blood and kidneys through prolonged or repeated exposure.
  • May form explosive air/gas mixture during charging.
  • Explosive, fire, blast, or projection hazard.
  • Harmful if swallowed, inhaled, or contact with skin
  • Causes skin irritation, serious eye damage.

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