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Safety Data Sheet EN

Non-Spillable Lead Acid Battery

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Non-Spillable Lead Acid Battery
Synonyms
Industrial Battery, Traction Battery, Stationary Battery, Deep Cycle Battery

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

E

EnerSys

manufacturer

P.O. Box 14145, 2366 Bernville Road, Reading, PA 19612-4145

E

EnerSys Canada Corporate Office

manufacturer

3-61 Parr Boulevard, Bolton, Ontario, L7E 4E3

Emergency Contacts

EnerSys' Environmental, Health & Safety Dept.

610-208-1996

CHEMTREC DOMESTIC

800-424-9300

CHEMTREC INTL

703-527-3877

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4
Skin Corr. Cat. 1A
Eye Dam. Cat. 1
Repr. Cat. 1A
Carc. Cat. 1B
Carc. Cat. 1A
Carc. Cat. 1A
STOT RE Cat. 2
Aquatic Chronic Cat. 1
Aquatic Acute Cat. 1
Expl. Cat. 1.3

GHS Pictograms

GHS01 - Explosive

GHS01

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H203 Explosive, fire, blast, or projection hazard.
H242 May form explosive air/gas mixture during charging.
H302 + H312 + H332 Harmful if swallowed, inhaled, or contact with skin
H314 Causes severe skin burns and serious eye damage.
H318 Causes skin irritation, serious eye damage.
H350 May cause cancer if ingested or inhaled.
H360 May damage fertility or the unborn child if ingested or inhaled.
H362 May cause harm to breast-fed children
H372 Causes damage to central nervous system, blood and kidneys through prolonged or repeated exposure.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood
P210 Keep away from heat./sparks/open flames/hot surfaces. No smoking
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P261 Irritating to eyes, respiratory system, and skin.
P263 Avoid contact during pregnancy/while nursing
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing, eye protection/face protection.
P280 Contact with internal components may cause irritation or severe burns. Avoid contact with internal acid.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Inorganic lead and electrolyte (sulfuric acid) are the primary components of every battery manufactured by EnerSys. Other ingredients may be present dependent upon battery type.

Chemical Name CAS Number Concentration Hazardous
Lead 7439-92-1 45 - 60% No
Lead Dioxide 1309-60-0 15 - 25% No
Antimony 7440-36-0 2% No
Arsenic 7440-38-2 0.2% No
Calcium 7440-70-2 0.04% No
Tin 7440-31-5 0.2% No
Sulfuric Acid (H2SO4/H2O) 7664-93-9 10 - 30% No
Polypropylene 9003-07-0 5 - 10% No
Polystyrene 9003-53-6 --- No
Styrene Acrylonitrile 9003-54-7 --- No
Acrylonitrile Butadiene Styrene 9003-56-9 --- No
Styrene Butadiene 9003-55-8 --- No
Polyvinylchloride 9002-86-2 --- No
Polycarbonate, Hard Rubber, Polyethylene 9002-88-4 --- No
Silicon Dioxide 7631-86-9 1 - 5% No
Sheet Molding Compound (Glass reinforced polyester) --- --- No

Inorganic lead and electrolyte (sulfuric acid) are the primary components of every battery manufactured by EnerSys. Other ingredients may be present dependent upon battery type. Contact your EnerSys representative for additional information.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Sulfuric Acid: Remove to fresh air immediately. If breathing is difficult, give oxygen. Consult a physician. Lead: Remove from exposure, gargle, wash nose and lips; consult physician.

Skin contact

Sulfuric Acid: Flush with large amounts of water for at least 15 minutes; remove contaminated clothing completely, including shoes. If symptoms persist, seek medical attention. Wash contaminated clothing before reuse. Discard contaminated shoes. Lead: Wash immediately with soap and water.

Eye contact

Sulfuric Acid and Lead: Flush immediately with large amounts of water for at least 15 minutes while lifting lids. Seek immediate medical attention if eyes have been exposed directly to acid.

Ingestion

Sulfuric Acid: Give large quantities of water; do not induce vomiting or aspiration into the lungs may occur and can cause permanent injury or death; consult a physician. Lead: Consult physician immediately.

Immediate Medical Attention

Sulfuric Acid: Consult a physician (inhalation, ingestion). Lead: Consult physician (inhalation, ingestion). Seek immediate medical attention if eyes have been exposed directly to acid.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2; foam; dry chemical. Use appropriate media for surrounding fire.

Unsuitable media

Do not use carbon dioxide directly on cells.

Specific hazards

Highly flammable hydrogen gas is generated during charging and operation of batteries. Strings of series connected batteries may still pose risk of electric shock even when charging equipment is shut down.

Instructions

If batteries are on charge, shut off power. Water applied to electrolyte generates heat and causes it to spatter.

Firefighter Protection

Use positive pressure, self-contained breathing apparatus. Wear acid-resistant clothing, gloves, face and eye protection.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Stop flow of material, contain/absorb small spills with dry sand, earth, and vermiculite. Do not use combustible materials. If possible, carefully neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc.

Small spill

contain/absorb small spills with dry sand, earth, and vermiculite

Environmental

Acid must be managed in accordance with local, state, and federal requirements. Consult state environmental agency and/or federal EPA.

Cleanup methods

neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Unless involved in recycling operations, do not breach the casing or empty the contents of the battery. Handle carefully and avoid tipping, which may allow electrolyte leakage. There may be increasing risk of electric shock from strings of connected batteries. Keep containers tightly closed when not in use. If battery case is broken, avoid contact with internal components. Keep vent caps on and cover terminals to prevent short circuits. Place cardboard between layers of stacked automotive batteries to avoid damage and short circuits. Keep away from combustible materials, organic chemicals, reducing substances, metals, strong oxidizers and water. Use banding or stretch wrap to secure items for shipping.

Storage

Store batteries in cool, dry, well-ventilated areas with impervious surfaces and adequate containment in the event of spills. Batteries should also be stored under roof for protection against adverse weather conditions. Separate from incompatible materials. Store and handle only in areas with adequate water supply and spill control. Avoid damage to containers. Keep away from fire, sparks and heat. Keep away from metallic objects could bridge the terminals on a battery and create a dangerous short-circuit.

Hygiene

Wear face and eye protection when near batteries being charged.

Fire prevention

Keep away from fire, sparks and heat. Prohibit smoking and avoid creation of flames and sparks nearby.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Store and handle in well-ventilated area. If mechanical ventilation is used, components must be acid-resistant. Handle batteries cautiously to avoid spills. Make certain vent caps are on securely. Avoid contact with internal components. Charge the batteries in areas with adequate ventilation. General dilution ventilation is acceptable.

Hands

If battery case is damaged, use rubber or plastic acid-resistant gloves with elbow-length gauntlet.

Eyes

Wear protective clothing, eye and face protection when filling, charging or handling batteries. If battery case is damaged, use chemical goggles or face shield. Face shield recommended when adding water or electrolyte to batteries.

Respiratory

None required under normal conditions. When concentrations of sulfuric acid mist are known to exceed the PEL, use NIOSH or MSHA-approved respiratory protection.

Skin/Body

Wear protective clothing when filling, charging or handling batteries. If battery case is damaged, use acid-resistant apron, clothing and boots. Under severe exposure emergency conditions, wear acid-resistant clothing and boots. Acid-resistant apron.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
clear liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Manufactured article; no apparent odor. Electrolyte is a clear liquid with a sharp, penetrating, pungent odor.
Colour
clear
Colour Intensity
---
Form
liquid
Odor
sharp, penetrating, pungent odor
Odor Threshold
---
Ph
~1 to 2
Melting Point
---
Boiling Point
203 - 240° F
Flash Point
Below room temperature (as hydrogen gas)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
Less than 1
Evaporation Rate
Less than 1
Vapor Pressure
10 mm Hg
Vapor Density
Greater than 1
Relative Density
1.215 to 1.350
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
74.2% (Hydrogen)
Lower Explosive Limit
4.1% (Hydrogen)
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
100%
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions at ambient temperature

Hazardous reactions

Will not occur

Avoid

Prolonged overcharge; sources of ignition

Incompatible

Sulfuric Acid: Contact with combustibles and organic materials may cause fire and explosion. Also reacts violently with strong reducing agents, metals, sulfur trioxide gas, strong oxidizers and water. Contact with metals may produce toxic sulfur dioxide fumes and may release flammable hydrogen gas. Lead Compounds: Avoid contact with strong acids, bases, halides, halogenates, potassium nitrate, permanganate, peroxides, nascent hydrogen and reducing agents. Arsenic compounds: strong oxidizers; bromine azide. NOTE: hydrogen gas can react with inorganic arsenic to form the highly toxic gas-arsine.

Decomposition

Sulfuric Acid: Sulfur trioxide, carbon monoxide, sulfuric acid mist, sulfur dioxide, and hydrogen sulfide. Lead Compounds: High temperatures likely to produce toxic metal fume, vapor, or dust; contact with strong acid or base or presence of nascent hydrogen may generate highly toxic arsine gas.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Send spent batteries to secondary lead smelter for recycling. Place electrolyte neutralized slurry into sealed containers.

Disposal

Manage in accordance with approved local, state and federal requirements. Consult state environmental agency and/or federal EPA.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2800
Shipping Name
BATTERIES, WET, NON-SPILLABLE
Transport Class
8
IMDG

Battery terminals must be protected against short circuits.

IATA

Battery Terminals must be protected against short circuits.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Non-Spillable Lead Acid Battery known by?

Non-Spillable Lead Acid Battery is also known as: Industrial Battery, Traction Battery, Stationary Battery, Deep Cycle Battery

What is the hazard signal word for Non-Spillable Lead Acid Battery?

The signal word is danger.

What is the physical form of Non-Spillable Lead Acid Battery?

Non-Spillable Lead Acid Battery is a clear liquid appearing as manufactured article; no apparent odor. electrolyte is a clear liquid with a sharp, penetrating, pungent odor. with clear color. It has sharp, penetrating, pungent odor odor.

What are the hazard statements for Non-Spillable Lead Acid Battery?

This substance has 9 hazard statements:

  • H203: Explosive, fire, blast, or projection hazard.
  • H242: May form explosive air/gas mixture during charging.
  • H302 + H312 + H332: Harmful if swallowed, inhaled, or contact with skin
  • H314: Causes severe skin burns and serious eye damage.
  • H318: Causes skin irritation, serious eye damage.
  • H350: May cause cancer if ingested or inhaled.
  • H360: May damage fertility or the unborn child if ingested or inhaled.
  • H362: May cause harm to breast-fed children
  • H372: Causes damage to central nervous system, blood and kidneys through prolonged or repeated exposure.