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Safety Data Sheet EN

Maleic acid

CAS 110-16-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Maleic acid
Product Code
M0375

Regulatory Identifiers

CAS Number
110-16-7 Check regulations →
REACH No.
01-2119488705-25-XXXX

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV

manufacturer

Ildefonse Vandammestraat 5/7B B-1560 HOEILAART

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H302 + H312 Harmful if swallowed or in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.

Precautionary Statements

P260 Do not breathe dust.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
maleic acid EC: 203-742-5 110-16-7 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. Call in physician.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

Rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

Make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Call a physician immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Foam, Carbon dioxide (CO2), Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

Tightly closed. Dry.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Material: Nitrile rubber; Break through time: 480 min; Glove thickness: 0,11 mm; Protective index: Full contact; Manufacturer: KCL 741 Dermatril® L; Material: Nitrile rubber; Break through time: 480 min; Glove thickness: 0,11 mm; Protective index: Splash contact; Manufacturer: KCL 741 Dermatril® L; Remarks: This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection. Recommended Filter : Filter type P2 type: The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Acid-resistant protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Bulk Density
---
Relative Evaporation Rate
---
State Under Standard Conditions
---
Odor
slightly sourish
Colour Intensity
---
Vapor Density
---
Decomposition Temperature
> 135 °C
Cloud Point
---
Solidification Point
---
Density
1,59 g/cm3 (25 °C) Method: lit.
Solubility In Fat
---
Form
powder
Relative Density
---
Evaporation Rate
No data available
Upper Explosive Limit
No data available
Metal Corrosion
---
Odor Threshold
---
Colour
white
Physical State Data
solid
Kinematic Viscosity
No data available
Partition Coefficient
log Pow: -1,3 (20 °C) pH: 2,5 Method: OECD Test Guideline 107 GLP: yes Bioaccumulation is not expected.
Molecular Weight
116,07 g/mol
Flammability
---
Auto Ignition Temperature
No data available
Melting Point
130 °C
Solubility In Water
478,8 g/l (20 °C) pH: 0,2 - 0,3 Method: OECD Test Guideline 105 GLP: yes completely soluble
Vapor Pressure
< 0,1 hPa (20 °C) Method: OECD Test Guideline 104 GLP: yes
Voc Content
---
Softening Point
---
Lower Explosive Limit
No data available
Appearance
---
Freezing Point
---
Solubility
---
Properties Status
---
Explosive Limits
---
Flash Point
No data available
Physical State
solid
Ph
1,3 (20 °C)
Dynamic Viscosity
No data available
Crystallisation Point
---
Boiling Point
157,8 °C (997 hPa)
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature) .

Reactivity

The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Hazardous reactions

Violent reactions possible with: Oxidizing agents Bases Reducing agents

Avoid

no information available

Incompatible

No data available

Decomposition

For Hazardous combustion products in the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3261
Shipping Name
CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (maleic acid)
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Maleic acid?

The signal word is danger.

What is the physical form of Maleic acid?

Maleic acid is a solid with white color. It has slightly sourish odor.

What is Maleic acid used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Maleic acid?

This substance has 4 hazard statements:

  • H302 + H312: Harmful if swallowed or in contact with skin.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H335: May cause respiratory irritation.

What is the melting point of Maleic acid?

The melting point is 130 °C and the boiling point is 157,8 °C (997 hPa).