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Safety Data Sheet EN

Maleic anhydride

CAS 108-31-6
EC 203-571-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Maleic anhydride
Product Code
P0008a, E0004219, E0120058, 8260810410
Chemical Name
Maleic anhydride
Synonyms
2,5-Furandione, MSA, MAN

Regulatory Identifiers

CAS Number
108-31-6 Check regulations →
EC Number
203-571-6 Check regulations →
REACH No.
01-2119472428-31-0001

Identified Uses

Intermediate, Raw material for chemical synthesis, Monomer for the preparation of copolymers.

Uses advised against

Until now no uses have been defined that are advised against.

Manufacturers & Suppliers

E

ESIM Chemicals GmbH

manufacturer

St.Peterstraße 25, A-4020 LINZ, AUSTRIA

+43(0)732/6982-0

Emergency Contacts

London Guy's & St Thomas' Poisons Unit Medical Toxicology Unit Guy's & St Thomas' Hospital Trust

0870 243 2241

ESIM-Chemicals

+43(0)732 6982-2249

00:00 - 24:00 Uhr

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Resp. Sens. Cat. 1 H334
Skin Sens. Cat. 1A H317
STOT RE Cat. 1 H372

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H372 Causes damage to the lung and the respiratory system through prolonged or repeated exposure.. Route of exposure: Inhalation.

Precautionary Statements

P284 [In case of inadequate ventilation] wear respiratory protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P321 Specific treatment (see on this label).
P362 + P364 Take off contaminated clothing and wash it before reuse.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
2,5-Furandione EC: 203-571-6 108-31-6 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

In case of unconsciousness place patient stably in side position for transportation. Provide fresh air.

Symptoms: Lachrymation, burning sensation of nose and throat, bleeding from the nose, weakness, coughing, rhinitis, irritation of respiratory tract and weakness of breathing. Coughing, headache, indisposition, shortness of breath.

Skin contact

Immediately wash with water and soap and rinse thoroughly.

Symptoms: Sensitization possible through skin contact. After prolonged action severe corrosion of skin with poorly healing wounds, burning of skin, strong irritating/corrosive action, extremely corrosive action on skin.

Eye contact

Call a doctor immediately. Remove contact lenses immediately! Rinse opened eye for several minutes under running water.

Symptoms: Lachrymation, burning sensation of eyes, severe damage of the eyes, strong irritation with danger of serious damage to eyes, sensitizing action, visual defects, danger of conjunctivitis.

Ingestion

Call for a doctor immediately. Drink plenty of water.

Symptoms: After swallowing headache, vomiting, abdominal pain.

Immediate Medical Attention

Call a doctor immediately. A 24-hour medical surveillance period is recommended in all cases of exposure to this substance, even in the absence of immediate signs of symptoms.

Medical Treatment

Symptomatic treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Alcohol resistant foam, Carbon dioxide, Water, Foam, Extinguishing powder.

Unsuitable media

Do not use water jet with hot melt: Steam explosion with propagation of material. Do not use extinguishing powder, hot maleic anhydride may thermally decompose or explode because of impurities.

Specific hazards

Formation of explosive dust/air-mixtures is possible. Strong heating may cause formation of potentially explosive vapours.

Firefighter Protection

Wear self-contained respiratory protective device. Chemical resistant protective suit. Under the protective suit a fire protective suit according to EN 469 should be applied. Use chemical protective suit and self contained breathing apparatus while undressing contaminated co-workers or handling contaminated equipment.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep people at a distance and stay on the windward side. Let spilled melt cool and solidify, then take up mechanically.

Environmental

Do not allow to enter sewers/ surface or ground water. Keep contaminated washing water and dispose of appropriately.

Cleanup methods

Absorb with liquid-binding material, Let spilled melt cool and solidify, then take up mechanically.

Materials: sand, diatomite, acid binders, universal binders, sawdust

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Empty containers must not be used for other products. Contaminated protective equipment should be cleaned before taking it off. Any unavoidable deposit of dust must be completely removed. Prevent formation of aerosols. Protect from humidity. Use additional container if material is transported in glass bottles. Fill only in dedicated and assigned containers. Keep containers tightly sealed.

Storage

Store in a dry location, keep away from humidity. Store in a cool location. Use only receptacles specifically permitted for this substance/product.

Hygiene

Contaminated protective equipment should be cleaned before taking it off.

Fire prevention

Protect against electrostatic charges. Use explosion-proof apparatus / fittings and spark-proof tools.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Handling of material under inert gas and protected from humidity. Sufficient ventilation is recommended. Check seals on flanges and valves for suitability and corrosion resistance. If necessary inspection intervals should be defined! Handle this material under exclusion of humidity. If possible use this material only in closed systems and devices. In case of open plant systems (sampling devices, filling and discharging, cleansing works etc.) use local exhaust and collecting trays.

Hands

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. Information given in the Exposure Scenarios in the annex have to be observed. For the permanent contact gloves made of the following materials are suitable: Do not wear gloves made from the following materials longer than 8 hours: Baypren-Viton. Check for tightness before use. Replace damaged gloves.

Eyes

Tightly sealed goggles.

Respiratory

Short term filter device: Particle filter. The filter grade (P1 - P3) has to be established depending on work-place related limit values and the actual exposition. Information given in the Exposure Scenarios in the annex have to be observed.

Skin/Body

Use only liquid proof and chemical resistant protective suit. Use protective suit with self-contained breathing apparatus.

Environmental

Waste gases should be led into the atmosphere only via appropriate separators, scrubbers or incinerators. Avoid spillage of product into the environment. If possible use this material only in closed systems and devices. In case of open plant systems (sampling devices, filling and discharging, cleansing works etc.) use local exhaust and collecting trays. Follow emission limit values. Measures in case of unwanted emissions should be established. Measures for prevention of hazards in case of unwanted leakage (LOPC) shall be implemented.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Melt
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Melt
Colour
Colourless
Colour Intensity
---
Form
Melt
Odor
Pungent
Odor Threshold
5-11 mg/m³
Ph
~1
Melting Point
53-58 °C
Boiling Point
200 °C
Flash Point
100-110 °C
Freezing Point
53-58 °C
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not determined.
Vapor Pressure
0.33 hPa
Vapor Density
Not determined.
Relative Density
Not determined.
Bulk Density
---
Density
1.48 g/cm³
Flammability
Not relevant.
Upper Explosive Limit
7.1 Vol %
Lower Explosive Limit
1.4 Vol %
Explosive Limits
---
Auto Ignition Temperature
380 °C
Decomposition Temperature
275 °C
Solubility
Hydrolysis
Partition Coefficient
-2.61
Solubility In Water
400 g/l
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
No corroding action on metals (expert statement).
Dynamic Viscosity
1.61 mPas
Kinematic Viscosity
Not determined.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

No decomposition if used according to specifications.

Reactivity

see 10.3.

Hazardous reactions

Maleic anhydride reacts with sodium, potassium, ammonia salt solutions and hydroxides with formation of carbon dioxide. Above 150°C MAN decomposes and polymerizes under the influence of small amounts of alkali compounds or amines. Vigorous reaction with strong oxidising agents. Hydrolyses with water forming maleic acid. Reacts violently with water Possible formation of explosive mixtures with air upon strong heating.

Avoid

Avoid electrostatic charge.

Incompatible

Exposure to humidity. Strong oxidizing agents. Alkali/erthalkali hydroxides, alkali metals, sodium ions, cations. Acids Humidity Bases

Decomposition

Carbon monoxide Carbon monoxide and carbon dioxide In the event of fire: See chapter 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Must not be disposed together with household garbage. Do not allow product to reach sewage system. Must be specially treated adhering to official regulations. If possible recovery or recycling.

Disposal

Empty container completely. Storage in a safe place after emptying.

Waste Codes

07 07 99 wastes not otherwise specified EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2215
Shipping Name
MALEIC ANHYDRIDE, MOLTEN
Transport Class
8
Packing Group
III
ADR

Warning: Corrosive substances.

IMDG

Warning: Corrosive substances.

IATA

Warning: Corrosive substances.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Maleic anhydride known by?

Maleic anhydride is also known as: 2,5-Furandione, MSA, MAN

What is the hazard signal word for Maleic anhydride?

The signal word is danger.

What is the physical form of Maleic anhydride?

Maleic anhydride is a melt appearing as melt with colourless color. It has pungent odor.

What is the solubility of Maleic anhydride?

Hydrolysis

What is Maleic anhydride used for?

Intermediate, Raw material for chemical synthesis, Monomer for the preparation of copolymers.

What are the hazard statements for Maleic anhydride?

This substance has 5 hazard statements:

  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H372: Causes damage to the lung and the respiratory system through prolonged or repeated exposure.. Route of exposure: Inhalation.

What is the melting point of Maleic anhydride?

The melting point is 53-58 °C and the boiling point is 200 °C.