Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- Maleic anhydride
- Product Code
- P0008a, E0004219, E0120058, 8260810410
- Chemical Name
- Maleic anhydride
- Synonyms
- 2,5-Furandione, MSA, MAN
Regulatory Identifiers
- CAS Number
- 108-31-6 Check regulations →
- EC Number
- 203-571-6 Check regulations →
- REACH No.
- 01-2119472428-31-0001
Identified Uses
Intermediate, Raw material for chemical synthesis, Monomer for the preparation of copolymers.
Uses advised against
Until now no uses have been defined that are advised against.
Manufacturers & Suppliers
ESIM Chemicals GmbH
manufacturer
St.Peterstraße 25, A-4020 LINZ, AUSTRIA
+43(0)732/6982-0
Emergency Contacts
London Guy's & St Thomas' Poisons Unit Medical Toxicology Unit Guy's & St Thomas' Hospital Trust
0870 243 2241
ESIM-Chemicals
+43(0)732 6982-2249
00:00 - 24:00 Uhr
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS05
GHS07
GHS08
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| 2,5-Furandione EC: 203-571-6 | 108-31-6 | --- | No |
First Aid Measures
Emergency procedures for chemical exposure incidents
In case of unconsciousness place patient stably in side position for transportation. Provide fresh air.
Symptoms: Lachrymation, burning sensation of nose and throat, bleeding from the nose, weakness, coughing, rhinitis, irritation of respiratory tract and weakness of breathing. Coughing, headache, indisposition, shortness of breath.
Immediately wash with water and soap and rinse thoroughly.
Symptoms: Sensitization possible through skin contact. After prolonged action severe corrosion of skin with poorly healing wounds, burning of skin, strong irritating/corrosive action, extremely corrosive action on skin.
Call a doctor immediately. Remove contact lenses immediately! Rinse opened eye for several minutes under running water.
Symptoms: Lachrymation, burning sensation of eyes, severe damage of the eyes, strong irritation with danger of serious damage to eyes, sensitizing action, visual defects, danger of conjunctivitis.
Call for a doctor immediately. Drink plenty of water.
Symptoms: After swallowing headache, vomiting, abdominal pain.
Immediate Medical Attention
Call a doctor immediately. A 24-hour medical surveillance period is recommended in all cases of exposure to this substance, even in the absence of immediate signs of symptoms.
Medical Treatment
Symptomatic treatment.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Alcohol resistant foam, Carbon dioxide, Water, Foam, Extinguishing powder.
Do not use water jet with hot melt: Steam explosion with propagation of material. Do not use extinguishing powder, hot maleic anhydride may thermally decompose or explode because of impurities.
Formation of explosive dust/air-mixtures is possible. Strong heating may cause formation of potentially explosive vapours.
Firefighter Protection
Wear self-contained respiratory protective device. Chemical resistant protective suit. Under the protective suit a fire protective suit according to EN 469 should be applied. Use chemical protective suit and self contained breathing apparatus while undressing contaminated co-workers or handling contaminated equipment.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Keep people at a distance and stay on the windward side. Let spilled melt cool and solidify, then take up mechanically.
Do not allow to enter sewers/ surface or ground water. Keep contaminated washing water and dispose of appropriately.
Absorb with liquid-binding material, Let spilled melt cool and solidify, then take up mechanically.
Materials: sand, diatomite, acid binders, universal binders, sawdust
Related Products
Similar products with comparable safety profiles
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Empty containers must not be used for other products. Contaminated protective equipment should be cleaned before taking it off. Any unavoidable deposit of dust must be completely removed. Prevent formation of aerosols. Protect from humidity. Use additional container if material is transported in glass bottles. Fill only in dedicated and assigned containers. Keep containers tightly sealed.
Store in a dry location, keep away from humidity. Store in a cool location. Use only receptacles specifically permitted for this substance/product.
Contaminated protective equipment should be cleaned before taking it off.
Protect against electrostatic charges. Use explosion-proof apparatus / fittings and spark-proof tools.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Handling of material under inert gas and protected from humidity. Sufficient ventilation is recommended. Check seals on flanges and valves for suitability and corrosion resistance. If necessary inspection intervals should be defined! Handle this material under exclusion of humidity. If possible use this material only in closed systems and devices. In case of open plant systems (sampling devices, filling and discharging, cleansing works etc.) use local exhaust and collecting trays.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. Information given in the Exposure Scenarios in the annex have to be observed. For the permanent contact gloves made of the following materials are suitable: Do not wear gloves made from the following materials longer than 8 hours: Baypren-Viton. Check for tightness before use. Replace damaged gloves.
Tightly sealed goggles.
Short term filter device: Particle filter. The filter grade (P1 - P3) has to be established depending on work-place related limit values and the actual exposition. Information given in the Exposure Scenarios in the annex have to be observed.
Use only liquid proof and chemical resistant protective suit. Use protective suit with self-contained breathing apparatus.
Waste gases should be led into the atmosphere only via appropriate separators, scrubbers or incinerators. Avoid spillage of product into the environment. If possible use this material only in closed systems and devices. In case of open plant systems (sampling devices, filling and discharging, cleansing works etc.) use local exhaust and collecting trays. Follow emission limit values. Measures in case of unwanted emissions should be established. Measures for prevention of hazards in case of unwanted leakage (LOPC) shall be implemented.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
No decomposition if used according to specifications.
see 10.3.
Maleic anhydride reacts with sodium, potassium, ammonia salt solutions and hydroxides with formation of carbon dioxide. Above 150°C MAN decomposes and polymerizes under the influence of small amounts of alkali compounds or amines. Vigorous reaction with strong oxidising agents. Hydrolyses with water forming maleic acid. Reacts violently with water Possible formation of explosive mixtures with air upon strong heating.
Avoid electrostatic charge.
Exposure to humidity. Strong oxidizing agents. Alkali/erthalkali hydroxides, alkali metals, sodium ions, cations. Acids Humidity Bases
Carbon monoxide Carbon monoxide and carbon dioxide In the event of fire: See chapter 5.
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
The data for this section has not been processed yet.
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
Must not be disposed together with household garbage. Do not allow product to reach sewage system. Must be specially treated adhering to official regulations. If possible recovery or recycling.
Empty container completely. Storage in a safe place after emptying.
Waste Codes
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- UN2215
- Shipping Name
- MALEIC ANHYDRIDE, MOLTEN
- Transport Class
- 8
- Packing Group
- III
Warning: Corrosive substances.
Warning: Corrosive substances.
Warning: Corrosive substances.
Regulatory Information
Chemical regulations, safety assessments, and compliance status
Frequently Asked Questions
Common questions about safety, handling, and properties
What other names is Maleic anhydride known by?
Maleic anhydride is also known as: 2,5-Furandione, MSA, MAN
What is the hazard signal word for Maleic anhydride?
The signal word is danger.
What is the physical form of Maleic anhydride?
Maleic anhydride is a melt appearing as melt with colourless color. It has pungent odor.
What is the solubility of Maleic anhydride?
Hydrolysis
What is Maleic anhydride used for?
Intermediate, Raw material for chemical synthesis, Monomer for the preparation of copolymers.
What are the hazard statements for Maleic anhydride?
This substance has 5 hazard statements:
- H302: Harmful if swallowed.
- H314: Causes severe skin burns and eye damage.
- H317: May cause an allergic skin reaction.
- H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
- H372: Causes damage to the lung and the respiratory system through prolonged or repeated exposure.. Route of exposure: Inhalation.
What is the melting point of Maleic anhydride?
The melting point is 53-58 °C and the boiling point is 200 °C.