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Safety Data Sheet EN

DL-Methionine

CAS 59-51-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
DL-Methionine
Product Code
M9500

Regulatory Identifiers

CAS Number
59-51-8 Check regulations →
REACH No.
A registration number is not available for this substance as the substance or its uses are exempted from registration or the annual tonnage does not require a registration.

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

M

Merck Life Science BV

manufacturer

Ildefonse Vandammestraat 5/7B B-1560 HOEILAART

+32 (0)3 899-1301

Emergency Contacts

CHEMTREC

+(32) 28 083237

Anti-poison centre

070 245245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Not Classified

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Synonyms : DL-2-Amino-4-(methylthio)butanoic acid (±)-2-Amino-4-(methylmercapto)butyric acid Formula : C5H11NO2S Molecular weight : 149,21 g/mol CAS-No. : 59-51-8 EC-No. : 200-432-1

Chemical Name CAS Number Concentration Hazardous
DL-2-Amino-4-(methylthio)butanoic acid (±)-2-Amino-4-(methylmercapto)butyric acid EC: 200-432-1 59-51-8 --- No

No components need to be disclosed according to the applicable regulations.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.

Eye contact

After eye contact: rinse out with plenty of water. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most). Consult doctor if feeling unwell.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides, Nitrogen oxides (NOx), Sulfur oxides

Instructions

Suppress (knock down) gases/vapors/mists with a water spray jet.

Firefighter Protection

In the event of fire, wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert.

Cleanup methods

Take up dry. Clean up affected area.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

For precautions see section 2.2.

Storage

Tightly closed. Dry.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P1 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
powder
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
white
Colour Intensity
---
Form
---
Odor
No data available
Odor Threshold
---
Ph
No data available
Melting Point
280 °C
Boiling Point
186 °C
Flash Point
No data available
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
No data available
Vapor Density
---
Relative Density
No data available
Bulk Density
---
Density
No data available
Flammability
No data available
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
No data available
Solubility In Water
No data available
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature) .

Reactivity

No data available

Hazardous reactions

No data available

Avoid

no information available

Incompatible

Strong oxidizing agents

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.6 Endocrine disrupting properties

No data available

No data available

12.7 Other adverse effects

Discharge into the environment must be avoided.

12.1 Toxicity

12.1 Toxicity

Toxicity to fish semi-static test LC50 - Danio rerio (zebra fish) - > 3.200 mg/l - 96 h (OECD Test Guideline 203) Remarks: The value is given in analogy to the following substances: L-methionine Toxicity to daphnia static test EC50 - Daphnia magna (Water flea) - 324 mg/l - 48 h and other aquatic (OECD Test Guideline 202) invertebrates Remarks: The value is given in analogy to the following substances: L-methionine Toxicity to algae static test ErC50 - Desmodesmus subspicatus (green algae) - > 1.000 mg/l - 72 h (OECD Test Guideline 201) Remarks: The value is given in analogy to the following substances: L-methionine Toxicity to bacteria static test EC50 - Pseudomonas putida - 10.000 mg/l - 18 h (DIN 38 412 Part 8) Remarks: The value is given in analogy to the following substances: L-methionine

12.2 Persistence and degradability

Biodegradability aerobic - Exposure time 28 d Result: 97 % - Readily biodegradable. (OECD Test Guideline 301A) Remarks: The value is given in analogy to the following substances: L-methionine

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for DL-Methionine?

The signal word is no signal word.

What is the physical form of DL-Methionine?

DL-Methionine is a powder with white color. It has no data available odor.

What is DL-Methionine used for?

Laboratory chemicals, Manufacture of substances

What is the melting point of DL-Methionine?

The melting point is 280 °C and the boiling point is 186 °C.