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Safety Data Sheet EN

BIOMATE SAN9494L

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
BIOMATE SAN9494L

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Biocide

Manufacturers & Suppliers

S

SUEZ-Tecnologias e Soluccoes para Tratamento de Aguas Ltda.

manufacturer

Av. Paraná, 4900 - Cajuru do Sul 18105-002 - Sorocaba - SP - Brasil

Emergency Contacts

Emergency Contact

08000143999

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4
Skin Irrit. Cat. 3
Eye Irrit. Cat. 2A
Skin Sens. Cat. 1A
Repr. Cat. 2
Aquatic Acute Cat. 1

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed.
H315 Causes mild skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H361 Suspected of damaging fertility or the unborn child.
H400 Very toxic to aquatic life.

Precautionary Statements

P201 Obtain special instructions before use.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Tetrakis(hydroxymethyl)phosphonium sulphate (2:1) 55566-30-8 60 - 80% Yes
phosphinylidynetrimethanol 1067-12-5 2.5 - 10% Yes

Notes

The listed ingredients refer to the hazardous ones which meet the cut-off levels prescribed by the standard ABNT NBR 14725.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. Call a physician if symptoms develop or persist.

Skin contact

Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions.

Symptoms: Mild skin irritation. May cause an allergic skin reaction. Dermatitis. Rash.

Eye contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.

Symptoms: Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Ingestion

Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical advice/attention if you feel unwell.

Immediate Medical Attention

Get medical advice/attention if you feel unwell. Get medical attention if irritation develops and persists. In case of eczema or other skin disorders: Seek medical attention.

Medical Treatment

Provide general supportive measures and treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Dry chemical, carbon dioxide, foam or water.

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

During fire, gases hazardous to health may be formed.

Firefighter Protection

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.

Small spill

Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Large spill

Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases.

Cleanup methods

Following product recovery, flush area with water. Wipe up with absorbent material. Clean surface thoroughly.

Materials: absorbent material (e.g. cloth, fleece), vermiculite, dry sand or earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices.

Storage

Store locked up. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).

Hygiene

When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Observe good industrial hygiene practices.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid
Colour
Colorless to light yellow
Colour Intensity
---
Form
Not available.
Odor
Mild
Odor Threshold
---
Ph
4 (0,1% Solution)
Melting Point
---
Boiling Point
100 °C
Flash Point
> 101 °C P-M(CC)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Slower than Ether
Vapor Pressure
18 mmHg
Vapor Density
< 1
Relative Density
1,39
Bulk Density
---
Density
---
Flammability
Not applicable.
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
100 %
Solubility In Fat
---
Molecular Weight
---
Voc Content
0 % ESTIMATED
Metal Corrosion
---
Dynamic Viscosity
47 mPa.s
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

The product is stable and non-reactive under normal conditions of use, storage and transport.

Hazardous reactions

Hazardous reactions may occur if this material gets inadvertently in contact with incompatible materials.

Avoid

Contact with incompatible materials.

Incompatible

Strong oxidizing agents.

Decomposition

Thermal decomposition (destructive fires) yields elemental oxides.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12. Ecological information

Very toxic to aquatic life. This product has been classified as environmentally hazardous short term (acute), category 1 based on the GHS classification of its components.

The product is classified as very toxic to aquatic life (acute category 1).

12.1 Toxicity

| Product | | Species | Test Results | | BIOMATE SAN9494L (CAS Mixture) | | | | | Other | EC50 | Pseudokirchnerella subcapitata | 0,2 mg/l, 96 hours | | Aquatic | | | | | Crustacea | LC50 | Daphnia magna | 19,4 mg/l, 96 hours | | Fish | LC50 | Rainbow Trout | 119 mg/l, 48 hours |

12.2 Persistence and degradability

Not provided

12.3 Bioaccumulative potential

Not provided

12.4 Mobility in soil

Not provided

12.5 Results of PBT and vPvB assessment

Not provided

12.6 Endocrine disrupting properties

Not provided

12.7 Other adverse effects

Not provided

Persistence and degradability

No data is available on the degradability of this product.

Bioaccumulative potential

No data available. Partition coefficient n-octanol / water (log Kow): Not available. Bioconcentration factor (BCF): Not available.

Mobility in soil

No data available for this product.

Other adverse effects

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN2810
Shipping Name
TOXIC LIQUID, ORGANIC, N.O.S. (Tetrakis(hydroxymethyl)phosphonium sulphate (2:1))
Transport Class
6.1
Packing Group
III
IMDG

Read safety instructions, SDS and emergency procedures before handling.

IATA

Read safety instructions, SDS and emergency procedures before handling.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This SDS was prepared in accordance with the latest version of Brazilian Standard ABNT NBR 14725 valid in the date of its revision.

Chemical Safety Assessment Not performed

The Chemicals Safety Information Card of the hazardous chemical can be obtained from a supplier.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for BIOMATE SAN9494L?

The signal word is warning.

What is the physical form of BIOMATE SAN9494L?

BIOMATE SAN9494L is a liquid. appearing as liquid with colorless to light yellow color. It has mild odor.

What is BIOMATE SAN9494L used for?

Biocide

What are the hazard statements for BIOMATE SAN9494L?

This substance has 6 hazard statements:

  • H302: Harmful if swallowed.
  • H315: Causes mild skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H361: Suspected of damaging fertility or the unborn child.
  • H400: Very toxic to aquatic life.