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Safety Data Sheet EN

HiTEC® 6411EN Fuel Additive

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
HiTEC® 6411EN Fuel Additive
Product Form
Liquid

Regulatory Identifiers

CAS Number
N/A
UFI Code
TU36-M1T9-R24V-4T26

Identified Uses

Industrial. Formulation and blending of fuel additives and fuels.

Manufacturers & Suppliers

A

Afton Chemical Limited

manufacturer

Euro-Tech Centre, London Road, Bracknell, RG12 2UW, England

+44 1344 304141

A

Afton Chemical S.R.L. (Woluwe)

manufacturer

Alma Court, Lenneke Marelaan, 8, B-1932, St-Stevens-Woluwe, Belgium

+32 2 715 2211

A

Afton Chemical S.R.L. (Feluy Plant)

manufacturer

Rue de Scouffény, 50, B-7191 Ecaussinnes Lalaing, Belgium

+32 67 286211

A

Afton Chemical India PVT Ltd

manufacturer

Lotus Corporate Park, 7th Floor, A Wing, Ram Mandir Lane, Western Express Highway, Goregaon East, Mumbai 400063 India

+91 22 6728 0200

Emergency Contacts

Emergency Contact

+43 1 364 92 37

Emergency Contact

+32 2 808 32 37

Emergency Contact

+359 32 570 104

Emergency Contact

+385 1 7776 920

Emergency Contact

+420 228 880 039

Emergency Contact

+45 69 91 85 73

Emergency Contact

+358 9 42725036

Emergency Contact

+33 9 75 18 14 07

Emergency Contact

0800 1817059

Emergency Contact

+30 21 1176 8478

Emergency Contact

+36 1 808 8425

Emergency Contact

+91 8071 279 207

Emergency Contact

+353 1 901 4670

Emergency Contact

+39 02 4555 7031

Emergency Contact

+352 20 20 24 16

Emergency Contact

+31 85 888 0596

Emergency Contact

+234 2012 278 883

Emergency Contact

+48 22 398 80 29

Emergency Contact

+351 308 801 773

Emergency Contact

+421 2330 579 72

Emergency Contact

+386 1 888 80 16

Emergency Contact

080 001 4676

Emergency Contact

+34 931 768 545

Emergency Contact

+46 8 525 034 03

Emergency Contact

+41 435 082 011

Emergency Contact

+44 20 3807 3798

Emergency Contact

+1 703 527 3887

Emergency Contact

+44 20 3885 0382

Emergency Contact

+65 3163 8374

Emergency Contact

+55 55 8526 4930

Emergency Contact

+55-11 4349 1359

Emergency Contact

+1 800 424 9300

Emergency Contact

+43 1 406 43 43

Emergency Contact

+32 (0)70 245 245

Emergency Contact

+359 2 9154 233

Emergency Contact

+3851 2348 342

Emergency Contact

+357 1401

Emergency Contact

+420 224 91 92 93

Emergency Contact

+45 8212 1212

Emergency Contact

+372 16662

Emergency Contact

+33 (0)1 45 42 59 59

Emergency Contact

+30 210 779 3777

Emergency Contact

+36 80 201 199

Emergency Contact

+354 112

Emergency Contact

+39 800 883 300

Emergency Contact

+39 055 794 7819

Emergency Contact

+39 800 183 459

Emergency Contact

+39 02 6610 1029

Emergency Contact

+39 081 545 3333

Emergency Contact

+39 0382 24444

Emergency Contact

+39 06 305 4343

Emergency Contact

+39 06 4997 8000

Emergency Contact

+39 06 6859 3726

Emergency Contact

+39 800 011 858

Emergency Contact

+371 67042473

Emergency Contact

+370 (85) 236 2052

Emergency Contact

+352 8002 5500

Emergency Contact

+31 (0)88 755 8000

Emergency Contact

+47 22 59 13 00

Emergency Contact

+351 800 250 250

Emergency Contact

+40 (0)21 318 36 06

8am – 3pm

Emergency Contact

+421 2 5477 4166

Emergency Contact

+386 112

Emergency Contact

+34 91 562 04 20

Emergency Contact

+46 112

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Skin Irrit. Cat. 2 H315
Carc. Cat. 1B H350
STOT SE Cat. 3 H335
STOT SE Cat. 3 H336
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapor.
H315 Causes skin irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H350 May cause cancer.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P235 Keep cool.
P243 Take action to prevent static discharges.
P261 Avoid breathing vapor.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing and eye or face protection.
P308 + P313 IF exposed or concerned: Get medical advice or attention.
P352 IF ON SKIN: Wash with plenty of water.
P403 Store in a well-ventilated place.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Polyolefin alkyl phenol alkyl amine --- 65 - 75% Yes
Hydrocarbons, C9, aromatics EC: 918-668-5 64742-95-6 15 - 22% Yes
1,2,4-trimethylbenzene EC: 202-436-9 95-63-6 5 - 10% Yes
mesitylene EC: 203-604-4 108-67-8 1 - 2.7% Yes
cumene EC: 202-704-5 98-82-8 0.1 - 0.3% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Adverse symptoms may include the following: respiratory tract irritation, coughing, nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Continue to rinse for at least 15 minutes.

Symptoms: Causes skin irritation. Adverse symptoms may include the following: irritation, redness

Eye contact

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Symptoms: No known significant effects or critical hazards. Adverse symptoms may include the following: pain or irritation, watering, redness

Ingestion

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Can cause central nervous system (CNS) depression. No specific data.

Immediate Medical Attention

Get medical attention.

Medical Treatment

No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

In case of fire, use water spray (fog), foam, dry chemical or CO₂.

Unsuitable media

Do not use water jet.

Specific hazards

Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Absorb with an inert material and place in an appropriate waste disposal container. Wash spillages into an effluent treatment plant or proceed as follows.

Materials: inert material, sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use.

Storage

Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

Hand Protection: Wear chemical resistant gloves. Nitrile gloves of minimum thickness 0.4 mm have an expected breakthrough time of 30 minutes or less when in frequent contact with the product. Due to variable exposure conditions the user must consider that the practical use of a chemical-protective glove in practice may be much shorter than the permeation time above. Manufacturer's directions for use, especially about the minimum thickness and the minimum breakthrough time, must be observed. This information does not replace suitability tests by the end user since glove protection varies depending on the conditions under which the product is used.

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Respiratory

Use appropriate respiratory protection if there is the potential to exceed the exposure limit(s). Seek professional advice prior to respirator selection and use. Select respirator based on suitability to provide adequate worker protection for given working conditions and level of airborne contaminant. Approved/certified respirator with organic vapor cartridge.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Hazy liquid.
Colour
Amber.
Colour Intensity
---
Form
---
Odor
Petroleum-like
Odor Threshold
Not available.
Ph
Not available.
Melting Point
Not available.
Boiling Point
Not available.
Flash Point
Closed cup: 40°C [Pensky-Martens Minimum]
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Not available.
Vapor Density
Not available.
Relative Density
0.9152
Bulk Density
---
Density
0.913 g/cm³
Flammability
Not applicable (liquid).
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
412°C
Decomposition Temperature
Not available.
Solubility
---
Partition Coefficient
---
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Kinematic (40°C): 470 mm²/s (470 cSt) Minimum
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible

oxidizing materials

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

| Product/ingredient name | Result | Species | Remarks | | --- | --- | --- | --- | | Polyolefin alkyl phenol alkyl amine | Acute - EC50 5.4 mg/l [96 hours] | Algae | Based on data for a similar substance. | | | Chronic - NOEC 3.65 mg/l [96 hours] | Algae | Based on data for a similar substance. | | | Chronic - NOEC 3.38 mg/l [21 days] | Daphnia | Based on data for a similar substance. |

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

| Product/ingredient name | Result | Species | Remarks | | --- | --- | --- | --- | | Hydrocarbons, C9, aromatics | Acute - LL50 8.2 mg/l [96 hours] | Fish - Pimephales promelas | Based on data for a similar substance. | | | Acute - EL50 4.5 mg/l [48 hours] | Crustaceans - Daphnia magna | Based on data for a similar substance. | | | Acute - EL50 3.1 mg/l [72 hours] | Algae - Raphidocelis subcapitata | |

12.1 Toxicity

| 1,2,4-trimethylbenzene | Chronic - NOEL 0.5 mg/l [72 hours] Chronic - NOEL 2.6 mg/l [14 days] | Algae - Raphidocelis subcapitata Fish - Pimephales promelas | Based on data for a similar substance. Based on data for a similar substance. | | --- | --- | --- | --- | | | Chronic - NOEC 0.4 mg/l [21 days] | Crustaceans - Daphnia magna | |

12.1 Toxicity

mesitylene | Acute - LC50 7.72 mg/l [96 hours] Acute - LC50 3.6 mg/l [48 hours] NOEC 24.2 mg/l [28 days] | Fish - Pimephales promelas Crustaceans - Daphnia magna Micro-organism | Based on data for a similar substance. Based on data for a similar substance. | | Chronic - NOEC 0.4 mg/l [21 days] | Crustaceans - Daphnia magna | |

12.1 Toxicity

| cumene | Acute - LC50 12.52 mg/l [96 hours] Acute - LC50 6 mg/l [48 hours] Acute - EC50 53 mg/l [48 hours] Chronic - EC10 16 mg/l [48 hours] Chronic - NOEC 0.4 mg/l [21 days] Acute - LC50 4.8 mg/l [96 hours] Acute - EC50 2.14 mg/l [48 hours] Acute - EC50 2.01 mg/l [72 hours] Chronic - EC10 1.35 mg/l [72 hours] EC50 >2000 mg/l [3 hours] Chronic - NOEC 0.35 mg/l [21 days] Chronic - NOEC 0.38 mg/l [28 days] | Fish - Carassius auratus Crustaceans - Daphnia magna Algae - Desmodesmus subspicatus Algae - Desmodesmus subspicatus Crustaceans - Daphnia magna Fish - Oncorhynchus mykiss Crustaceans - Daphnia magna Algae - Desmodesmus subspicatus Algae - Desmodesmus subspicatus Micro-organism Crustaceans - Daphnia magna Fish - D. rerio and P. promelas |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | --- | --- | --- | --- |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | --- | --- | --- | --- | | Polyolefin alkyl phenol alkyl amine | OECD [Ready Biodegradability - Closed Bottle Test] | 4% [28 days] - Not readily | Based on data for a similar substance. |

12.2 Persistence and degradability

12.2 Persistence and degradability | Product/ingredient name | Test | Result | Remarks | | --- | --- | --- | --- | | mesitylene | | 42% [28 days] - Not readily | |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | Remarks | | --- | --- | --- | --- | | cumene | | 70% [20 days] - Readily | |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | Hydrocarbons, C9, aromatics | - | 10 to 2500 | High |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | 1,2,4-trimethylbenzene | 3.63 | 243 | Low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | mesitylene | 3.42 | 161 | Low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | cumene | 3.55 | 35.48 | Low |

12.4 Mobility in soil

Product/ingredient name | logKoc | Koc 1,2,4-trimethylbenzene | 2.93 | 846.864 mesitylene | 2.82 | 658.527 cumene | 2.72 | 521.484

12.5 Results of PBT and vPvB assessment

Regulation (EC) No. 1272/2008 [CLP] | Product/ingredient name | PBT | P | B | T | vPvB | vP | vB | | --- | --- | --- | --- | --- | --- | --- | --- | | Polyolefin alkyl phenol alkyl amine | No | No | No | No | No | No | No | | Hydrocarbons, C9, aromatics | No | No | No | No | No | No | No | | 1,2,4-trimethylbenzene | No | No | No | No | No | No | No | | mesitylene | No | No | No | No | No | No | No | | cumene | No | No | No | No | No | No | No | Conclusion/Summary : The product does not meet the criteria to be considered as a PBT or vPvB. Afton will update product classifications in line with the transitional period specified in CLP.

The product does not meet the criteria to be considered as a PBT or vPvB.

12.6 Endocrine disrupting properties

Conclusion/Summary : The product does not meet the criteria to be considered as having endocrine disrupting properties according to the criteria set out in either Regulation (EC) No. 1907/2006 or Regulation (EC) No 1272/2008. Afton will update product classifications in line with the transitional period specified in CLP.

The product does not meet the criteria to be considered as having endocrine disrupting properties according to the criteria set out in either Regulation (EC) No. 1907/2006 or Regulation (EC) No 1272/2008.

12.7 Other adverse effects

No known significant effects or critical hazards.

No known significant effects or critical hazards.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Waste Codes

13 07 03* other fuels (including mixtures) EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1993
Shipping Name
FLAMMABLE LIQUID, N.O.S. (Solvent naphtha; Trimethylbenzenes)
Transport Class
3
Packing Group
III
ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Restricted to professional users.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for HiTEC® 6411EN Fuel Additive?

The signal word is danger.

What is the physical form of HiTEC® 6411EN Fuel Additive?

HiTEC® 6411EN Fuel Additive is a liquid. appearing as hazy liquid. with amber. color. It has petroleum-like odor.

What is HiTEC® 6411EN Fuel Additive used for?

Industrial. Formulation and blending of fuel additives and fuels.

What are the hazard statements for HiTEC® 6411EN Fuel Additive?

This substance has 6 hazard statements:

  • H226: Flammable liquid and vapor.
  • H315: Causes skin irritation.
  • H335: May cause respiratory irritation.
  • H336: May cause drowsiness or dizziness.
  • H350: May cause cancer.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of HiTEC® 6411EN Fuel Additive?

The melting point is Not available. and the boiling point is Not available..