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Safety Data Sheet EN

RADIA 4670

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
RADIA 4670
Product Form
Mixture

Regulatory Identifiers

CAS Number
N/A
UFI Code
7EJ6-4F8V-RE03-QKUU

Identified Uses

Industrial use Wide dispersive use

Manufacturers & Suppliers

OLEON N.V. logo

OLEON N.V.

manufacturer

Assenedestraat 2 BE 9940 Ertvelde Belgium

+32 9 341 10 11

http://www.oleon.com

Emergency Contacts

SGS ERS

+32 3 575 55 55

SGS ERS

+1 888 765 6554

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed.

Precautionary Statements

P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P330 Rinse mouth.
P501 Dispose of contents/container to comply with local/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
ethylene glycol EC: 203-473-3 107-21-1 40 - 80% Yes
glycerol EC: 200-289-5 56-81-5 50% No
1,2-propanediol EC: 200-338-0 57-55-6 50% No
dipropylene glycol EC: 246-770-3 25265-71-8 20% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air. Respiratory problems: consult a doctor/medical service.

Skin contact

Wash off immediately with soap and plenty of water. If irritation persists, consult a doctor.

Symptoms: Tingling/irritation of the skin.

Eye contact

Rinse immediately with plenty of water. Consult an ophthalmologist if irritation persists.

Symptoms: Irritation of the eye tissue.

Ingestion

Rinse mouth out with water. Get medical advice/attention if you feel unwell. Call a poison center (www.who.int/ipcs/poisons/centre/directory/en).

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

AFFF foam. BC-powder. Carbon dioxide. Dry sand. Dry chemical powder. Use the extinguishing media recommended for the burning materials and fire situation.

Unsuitable media

Do not use water jet.

Specific hazards

DIRECT FIRE HAZARD: Combustible. INDIRECT FIRE HAZARD: Heating may cause a fire or explosion. Temperature above flashpoint: higher fire/explosion hazard.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Mark the danger area. Exposure to fire/heat: have neighbourhood close doors and windows. Exposure to fire/heat: consider evacuation. Wash contaminated clothing before reuse.

Environmental

Prevent soil and water pollution.

Cleanup methods

Clean contaminated surfaces with a soap solution. Flush/dilute with water. Take up liquid spill into absorbent material.

Materials: sand, earth, vermiculite or powdered limestone

—

Related Products

Similar products with comparable safety profiles

R

RADIA 4670

---

R

RADIA 7860

---

R

RADIA 7730

CAS: 110-27-0

R

RADIA 7170

CAS: 68604-44-4

R

RADIA 7780

CAS: 29806-73-3

R

RADIA 7950

---

R

RADIA 7880

---

R

RADIA 7770

CAS: 91031-48-0

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handling temperature : ≥ 10 °C above melting point

Storage

Store at ambient temperature. Keep out of direct sunlight. Meet the legal requirements.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Gloves

Eyes

Safety glasses

Skin/Body

Protective clothing. Materials for protective clothing: Good resistance: Nitrile rubber

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid.
Colour
Yellow.
Colour Intensity
---
Form
---
Odor
Characteristic. Sweet odour.
Odor Threshold
Not available
Ph
ca. 6 (5 – 8)
Melting Point
< 0 °C
Boiling Point
> 150 °C (1 atm)
Flash Point
131 °C (ASTM D92; Intertek; 05.2013; ref. 6/108081/00)
Freezing Point
Not available
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
No supplementary information available
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1.085 – 1.12 g/cm³ (20°C; Oleon; 01.2017)
Flammability
---
Upper Explosive Limit
Not available
Lower Explosive Limit
Not available
Explosive Limits
---
Auto Ignition Temperature
> 80 °C
Decomposition Temperature
Not available
Solubility
Soluble in water. soluble in most organic solvents.
Partition Coefficient
Not available
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
not determined (1999/13/EC; 2004/42/EC; 2010/75/EU)
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Not available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

On burning: release of carbon monoxide/carbon dioxide.

Hazardous reactions

No additional information available

Avoid

No supplementary information available.

Incompatible

No supplementary information available.

Decomposition

No supplementary information available.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.5 Results of PBT and vPvB assessment

No data available

12.6 Endocrine disrupting properties

No data available

12.7 Other adverse effects

No data available

12.1 Toxicity

LC50 - Fish [1]: 54000 mg/l (96 h, Oncorhynchus mykiss, Static system, Fresh water, Experimental value, Nominal concentration) EC50 - Crustacea [1]: > 10000 mg/l (24 h, Daphnia magna, Static system, Fresh water, Experimental value, Locomotor effect)

12.1 Toxicity

LC50 - Fish [1] > 72860 mg/l (EPA 600/4-90/027, 96 h, Pimephales promelas, Static system, Fresh water, Experimental value, Nominal concentration) EC50 - Crustacea [1] > 100 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, Daphnia magna, Static system, Fresh water, Experimental value)

12.1 Toxicity

LC50 - Fish [1] 40613 mg/l (96 h, Oncorhynchus mykiss, Static system, Fresh water, Experimental value, Measured concentration) ErC50 algae 24200 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh water, Experimental value, GLP)

12.1 Toxicity

LC50 - Fish [1] > 1000 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oryzias latipes, Semi-static system, Fresh water, Experimental value, Nominal concentration) EC50 - Crustacea [1] > 100 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static system, Fresh water, Experimental value, Measured concentration) ErC50 algae > 100 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Desmodesmus subspicatus, Fresh water, Experimental value, Nominal concentration)

12.2. Persistence and degradability

RADIA 4670: Rapidly degradable

12.2. Persistence and degradability

Readily biodegradable in water.

12.2. Persistence and degradability

Readily biodegradable in the soil, Readily biodegradable in water. Biochemical oxygen demand (BOD) 0.47 g O2/g substance Chemical oxygen demand (COD) 1.24 g O2/g substance ThOD 1.29 g O2/g substance

12.2. Persistence and degradability

Biodegradable in the soil, Readily biodegradable in water. Biochemical oxygen demand (BOD) 0.96 – 1.08 g O2/g substance. Chemical oxygen demand (COD) 1.63 g O2/g substance. ThOD 1.69 g O2/g substance.

12.2. Persistence and degradability

Readily biodegradable in water.

The substance is readily biodegradable in water.

12.3. Bioaccumulative potential

glycerol (56-81-5) Partition coefficient n-octanol/water (Log Pow) -1.8 (Experimental value, Equivalent or similar to OECD 107, 25 °C) Bioaccumulative potential Not bioaccumulative.

12.3. Bioaccumulative potential

ethylene glycol (107-21-1) Partition coefficient n-octanol/water (Log Pow) -1.36 (Experimental value) Bioaccumulative potential Not bioaccumulative.

12.3. Bioaccumulative potential

1,2-propanediol (57-55-6) Partition coefficient n-octanol/water (Log Pow) -1.1 (Experimental value, EU Method A.8: Partition Coefficient, 20.5 °C) Bioaccumulative potential Not bioaccumulative.

The substance is considered not bioaccumulative with a log Pow of -1.1.

12.3. Bioaccumulative potential

|**dipropylene glycol (25265-71-8)**|| |Partition coefficient n-octanol/water (Log Pow)|-0.46 (Test data, Equivalent or similar to OECD 107, 21.7 °C)| |Bioaccumulative potential|Not bioaccumulative.|

12.1. Toxicity

Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Ecology - air : No supplementary information available. Ecology - water : No data available concerning bioaccumulation Hazardous to the aquatic environment, short–term : Not classified (acute) Hazardous to the aquatic environment, long–term : Not classified (chronic)

The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment.

12.2 Persistence and degradability

No data available

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.4. Mobility in soil

RADIA 4670 Ecology - soil: Biodegradability in soil: no data available. glycerol (56-81-5) Surface tension: 63.4 mN/m (20 °C, 1000 g/l) Organic Carbon Normalized Adsorption Coefficient (Log Koc): 0 (log Koc, SRC PCKOCWIN v2.0, Calculated value) Ecology - soil: Highly mobile in soil. ethylene glycol (107-21-1) Surface tension: 48.4 mN/m (20 °C) Organic Carbon Normalized Adsorption Coefficient (Log Koc): 0 (log Koc, SRC PCKOCWIN v2.0, QSAR) Ecology - soil: Highly mobile in soil. 1,2-propanediol (57-55-6) Surface tension: 71.6 mN/m (22 °C, 1.01 g/l, EU Method A.5: Surface tension) Organic Carbon Normalized Adsorption Coefficient (Log Koc): 0.46 (log Koc, Calculated value) Ecology - soil: Highly mobile in soil. dipropylene glycol (25265-71-8) Surface tension: 71.4 mN/m (22 °C, 1.01 g/l, EU Method A.5: Surface tension) Organic Carbon Normalized Adsorption Coefficient (Log Koc): 0.78 (log Koc, Calculated value) Ecology - soil: Highly mobile in soil.

12.5. Results of PBT and vPvB assessment

Substance(s) not meeting the PBT criteria of REACH regulation, in accordance with Annex XIII: glycerol (56-81-5), ethylene glycol (107-21-1), 1,2-propanediol (57-55-6), dipropylene glycol (25265-71-8) Substance(s) not meeting the vPvB criteria of REACH regulation, in accordance with Annex XIII: glycerol (56-81-5), ethylene glycol (107-21-1), 1,2-propanediol (57-55-6), dipropylene glycol (25265-71-8)

12.6. Endocrine disrupting properties

No additional information available

12.7. Other adverse effects

RADIA 4670: No supplementary information available. glycerol (56-81-5): No supplementary information available. ethylene glycol (107-21-1): No supplementary information available. 1,2-propanediol (57-55-6): No supplementary information available. dipropylene glycol (25265-71-8): No supplementary information available.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Prevent dispersion by covering with dry absorbent, Scoop solid spill into closing containers, Scoop absorbed substance into closing containers, Clean contaminated surfaces with an excess of water and soap solution, Wash clothing and equipment after handling

Waste Codes

HP6 “Acute Toxicity:” waste which can cause acute toxic effects following oral or dermal administration, or inhalation exposure. HP Code
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The product is compliant with major international chemical inventories. It is not subject to the Major Accidents Ordinance (12. BImSchV) in Germany. Specific restrictions apply in Denmark regarding young workers and pregnant/breastfeeding women.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for RADIA 4670?

The signal word is warning.

What is the physical form of RADIA 4670?

RADIA 4670 is a liquid appearing as liquid. with yellow. color. It has characteristic. sweet odour. odor.

What is the solubility of RADIA 4670?

Soluble in water. soluble in most organic solvents.

What is RADIA 4670 used for?

Industrial use Wide dispersive use

What are the hazard statements for RADIA 4670?

This substance has 1 hazard statement:

  • H302: Harmful if swallowed.

What is the melting point of RADIA 4670?

The melting point is < 0 °C and the boiling point is > 150 °C (1 atm).