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Safety Data Sheet EN

RADIA 4670

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
RADIA 4670
Product Form
Mixture

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Industrial use wide dispersive use

Uses advised against

No additional information available

Manufacturers & Suppliers

OLEON N.V. logo

OLEON N.V.

manufacturer

Assenedestraat 2, 9940 Ertvelde - Belgium

+32 9 341 10 11

http://www.oleon.com

Emergency Contacts

SGS ERS

+32 3 575 55 55

SGS ERS

+1 888 765 6554

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed.

Precautionary Statements

P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P330 Rinse mouth.
P501 Dispose of contents/container to comply with local/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
ethylene glycol EC: 203-473-3 107-21-1 40 - 80% Yes
glycerol EC: 200-289-5 56-81-5 50% No
1,2-propanediol EC: 200-338-0 57-55-6 50% No
dipropylene glycol EC: 246-770-3 25265-71-8 20% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.

Skin contact

Wash immediately with lots of water. Soap may be used. Take victim to a doctor if irritation persists.

Symptoms: Tingling/irritation of the skin.

Eye contact

Rinse immediately with plenty of water. Take victim to an ophthalmologist if irritation persists.

Symptoms: Irritation of the eye tissue.

Ingestion

Rinse mouth with water. Call Poison Information Centre (www.who.int/ipcs/poisons/centre/directory/en). Consult a doctor/medical service if you feel unwell.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

AFFF foam. BC powder. Carbon dioxide. Dry sand. Dry chemical powder. Adapt extinguishing media to the environment.

Unsuitable media

Solid water jet ineffective as extinguishing medium.

Specific hazards

DIRECT FIRE HAZARD: Combustible. INDIRECT FIRE HAZARD: Heating increases the fire hazard. Temperature above flashpoint: higher fire/explosion hazard. Explosion hazard: No direct explosion hazard.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Mark the danger area. Exposure to heat: have neighbourhood close doors and windows. Exposure to fire/heat: consider evacuation. Wash contaminated clothes.

Environmental

Prevent soil and water pollution.

Cleanup methods

Clean contaminated surfaces with an excess of water and soap solution. Take up liquid spill into inert absorbent material.

Materials: dry sand/earth/vermiculite or powdered limestone

—

Related Products

Similar products with comparable safety profiles

R

RADIA 4670

UFI: 7EJ6-4F8V-RE03-QKUU

R

RADIA 7860

---

R

RADIA 7730

CAS: 110-27-0

R

RADIA 7170

CAS: 68604-44-4

R

RADIA 7780

CAS: 29806-73-3

R

RADIA 7950

---

R

RADIA 7880

---

R

RADIA 7770

CAS: 91031-48-0

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handling temperature: ≥ 10 °C above melting point

Storage

Keep container in a well-ventilated place. Store at ambient temperature. Keep out of direct sunlight. Meet the legal requirements.

Fire prevention

KEEP SUBSTANCE AWAY FROM: ignition sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Gloves. GIVE GOOD RESISTANCE: nitrile rubber

Eyes

Safety glasses.

Skin/Body

Protective clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid.
Colour
Yellow to dark brown.
Colour Intensity
---
Form
---
Odor
Characteristic odour. Sweet odour.
Odor Threshold
---
Ph
ca. 6 (5 - 8)
Melting Point
< 0 °C
Boiling Point
> 150 °C (1 atm)
Flash Point
131 °C (ASTM D92; Intertek; 05.2013; ref. 6/108081/00)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
---
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1,085 - 1,120 g/cm³ (20°C; Oleon; 01.2017)
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
> 80 °C
Decomposition Temperature
---
Solubility
Soluble in water. soluble in most organic solvents.
Partition Coefficient
---
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
not determined (1999/13/EC; 2004/42/EC; 2010/75/EU)
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

On burning: release of (carbon monoxide - carbon dioxide).

Hazardous reactions

No additional information available

Avoid

No supplementary information available.

Incompatible

No supplementary information available.

Decomposition

No supplementary information available.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Ecology - general : According to literature: no environmental hazard. No data available on ecotoxicity. Ecology - air : No supplementary information available. Ecology - water : No bioaccumulation data available Acute aquatic toxicity : Not classified Chronic aquatic toxicity : Not classified

According to literature: no environmental hazard. No data available on ecotoxicity.

12.1. Toxicity

LC50 fish 1: 54000 mg/l (96 h, Salmo gairdneri, Static system, Fresh water, Experimental value, Lethal) EC50 Daphnia 1: > 10000 mg/l (24 h, Daphnia magna, Static system, Fresh water, Experimental value, Locomotor effect)

12.1. Toxicity

LC50 fish 1: 40761 mg/l (96 h, Salmo gairdneri, Static system) EC50 Daphnia 1: > 10000 mg/l (24 h, Daphnia magna) EC50 96h algae (1): 6,5 - 13 g/l (Selenastrum capricornutum, Growth)

12.1. Toxicity

| LC50 fish 1 | 51600 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oncorhynchus mykiss, Experimental value) | | --- | --- | | LC50 fish 2 | 40613 mg/l (Other, 96 h, Oncorhynchus mykiss, Static system, Fresh water, Experimental value) | | ErC50 (algae) | 24200 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh water, Experimental value, GLP) |

12.1. Toxicity

| LC50 fish 1 | > 1000 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oryzias latipes, Semi-static system, Fresh water, Experimental value) | | LC50 other aquatic organisms 1 | 3181 mg/l (Other, 48 h, Xenopus laevis, Fresh water, Experimental value) | | EC50 Daphnia 1 | > 100 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static system, Fresh water, Experimental value) | | EC50 72h algae (1) | > 100 mg/l (OECD 201: Alga, Growth Inhibition Test, Desmodesmus subspicatus, Fresh water, Experimental value) |

12.2. Persistence and degradability

12.2. Persistence and degradability

12.2. Persistence and degradability

Readily biodegradable in water. Biochemical oxygen demand (BOD) | 0,87 g O2/g substance Chemical oxygen demand (COD) | 1,16 g O2/g substance ThOD | 1,217 g O2/g substance BOD (% of ThOD) | 0,71

The substance is readily biodegradable in water.

12.2. Persistence and degradability

Biodegradable in the soil. Readily biodegradable in water. Biochemical oxygen demand (BOD) 0,47 g O2/g substance. Chemical oxygen demand (COD) 1,24 g O2/g substance. ThOD 1,29 g O2/g substance. BOD (% of ThOD) 0,36.

12.2. Persistence and degradability

Biodegradable in the soil. Readily biodegradable in water. | Persistence and degradability | Biodegradable in the soil. Readily biodegradable in water. | | --- | --- | | Biochemical oxygen demand (BOD) | 0,96 - 1,08 g O2/g substance | | Chemical oxygen demand (COD) | 1,63 g O2/g substance | | ThOD | 1,69 g O2/g substance |

Biodegradable in the soil. Readily biodegradable in water.

12.2. Persistence and degradability

Readily biodegradable in water.

Readily biodegradable in water.

12.3. Bioaccumulative potential

glycerol (56-81-5)

12.3. Bioaccumulative potential

| Log Pow | -1,75 (Experimental value, Equivalent or similar to OECD 107, 25 °C) | | --- | --- | | Bioaccumulative potential | Not bioaccumulative. |

12.3. Bioaccumulative potential

| BCF fish 1 | 10 (72 h, Leuciscus idus) | | --- | --- | | BCF other aquatic organisms 1 | 0,21 - 0,6 (Procambarus sp., Chronic) | | BCF other aquatic organisms 2 | 190 (24 h, Algae) | | Log Pow | -1,34 (Experimental value) | | Bioaccumulative potential | Not bioaccumulative. |

Not bioaccumulative.

12.3. Bioaccumulative potential

| BCF other aquatic organisms 1 | 0,09 | | --- | --- | | Log Pow | -1,07 (Experimental value, EU Method A.8: Partition Coefficient, 20.5 °C) | | Bioaccumulative potential | Not bioaccumulative. |

Not bioaccumulative.

12.3. Bioaccumulative potential

| Log Pow | -0,462 (Test data, Equivalent or similar to OECD 107, 21.7 °C) | | --- | --- | | Bioaccumulative potential | Bioaccumulation: not applicable. |

12.4. Mobility in soil

12.4. Mobility in soil | RADIA 4670 | | | --- | --- | | Ecology - soil | Biodegradability in soil: no data available. | glycerol (56-81-5) | Surface tension | 0,0634 N/m (20 °C, 1000 g/l) | | --- | --- | | Ecology - soil | No (test)data on mobility of the substance available. | ethylene glycol (107-21-1) | Surface tension | 48 mN/m (20 °C) | | --- | --- | | Ecology - soil | No (test)data on mobility of the substance available. | 1,2-propanediol (57-55-6) | Surface tension | 71,6 mN/m (21.5 °C, 1.01 g/l, EU Method A.5: Surface tension) | | --- | --- | | Log Koc | 0,46 (log Koc, Calculated value) | | Ecology - soil | Highly mobile in soil. | dipropylene glycol (25265-71-8) | Surface tension | 71,4 mN/m (22 °C, 1.01 g/l) | | --- | --- | | Log Koc | 0,78 (log Koc, Calculated value) | | Ecology - soil | Low potential for adsorption in soil. |

12.5. Results of PBT and vPvB assessment

| Component | | | --- | --- | | glycerol (56-81-5) | This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII | | ethylene glycol (107-21-1) | This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII | | 1,2-propanediol (57-55-6) | This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII | | dipropylene glycol (25265-71-8) | This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII |

All listed components (glycerol, ethylene glycol, 1,2-propanediol, and dipropylene glycol) do not meet the PBT or vPvB criteria as defined in Annex XIII of the REACH regulation.

12.6. Other adverse effects

No additional information available
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Prevent dispersion by covering with dry absorbent, Scoop solid spill into closing containers, Scoop absorbed substance into closing containers, Clean contaminated surfaces with an excess of water and soap solution, Wash clothing and equipment after handling

Disposal

Remove to an authorized waste treatment plant.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for RADIA 4670?

The signal word is warning.

What is the physical form of RADIA 4670?

RADIA 4670 is a liquid appearing as liquid. with yellow to dark brown. color. It has characteristic odour. sweet odour. odor.

What is the solubility of RADIA 4670?

Soluble in water. soluble in most organic solvents.

What is RADIA 4670 used for?

Industrial use wide dispersive use

What are the hazard statements for RADIA 4670?

This substance has 1 hazard statement:

  • H302: Harmful if swallowed.

What is the melting point of RADIA 4670?

The melting point is < 0 °C and the boiling point is > 150 °C (1 atm).