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Safety Data Sheet EN

2,2',2''-nitrilotriethanol

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
2,2',2''-nitrilotriethanol
Chemical Name
2,2',2''-nitrilotriethanol
Synonyms
Triethanolamine , TEA

Regulatory Identifiers

CAS Number
N/A
REACH No.
01-2119486482-31

Identified Uses

Anti-corrosion agent , Solvent , Intermediate ( Organic chemistry . ) Emulsifier ( Metal industry , Oils , Fuel , Paints , Cement , Cosmetics , Synthetic material , Household products )

Uses advised against

Non identified .

Manufacturers & Suppliers

BRENNTAG N.V. logo

BRENNTAG N.V.

national supplier

Nijverheidslaan 38 - BE-8540 DEERLIJK

+32(0)56/77.69.44

http://www.brenntag.be

BRENNTAG Nederland B.V. logo

BRENNTAG Nederland B.V.

national supplier

Donker Duyvisweg 44 - NL-3316 BM DORDRECHT

+31(0)78/65.44.944

http://www.brenntag.nl

Emergency Contacts

Antipoison Center - Brussels

+32(0)70/245.245

National Poisoning Information Center - Bilthoven

+31(0)30/274.88.88

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
2,2',2''-nitrilotriethanol EC: 203-049-8 102-71-6 99% No
2,2'-Iminodiethanol EC: 203-868-0 111-42-2 0.5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Allow the affected person to rest in semi-sitting position. Remove victim into fresh air. If symptoms, consult doctor.

Skin contact

Remove contaminated clothing and shoes. Rinse skin immediately with plenty of water. (shower if necessary). Obtain medical attention if irritation of skin develops.

Eye contact

Rinse immediately thoroughly and long (at least 15 min.) with plenty of water. Remove contact lenses. If symptoms, consult doctor.

Ingestion

DO NOT INDUCE VOMITING. Rinse mouth with water. Give 2 glasses of water to drink.

Medical Treatment

For specialist advice doctors should contact the NVCI or the Belgian Poison center.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Extinguishing powder, Carbon dioxide (CO2), Alcohol resistant foam, Water spray.

Unsuitable media

Heavy water stream.

Specific hazards

Fire may liberate Carbon oxides (CO), Nitrogen oxides (NOx) and dangerous Nitrogen compounds.

Instructions

Apply water spray or fog to cool nearby equipment.

Firefighter Protection

Use self-contained breathing apparatus and wear protective clothes when in close proximity to fire.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Eliminate every possible source of ignition (open fire, sparks, smoking, ...). Evacuate all personnel immediately and ventilate area. Avoid breathing vapour and contact with skin, eyes and clothing.

Environmental

Shut off leaks if without risks. Dike in the spilled product as much as possible with inert material. Prevent entry of product in public water, sewers or soil.

Cleanup methods

Collect the spillage in closable, suitable disposal containers. Clean up any spills as soon as possible, using an inert absorbent material. Flush residue with plenty of water.

Materials: inert absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid breathing vapour and contact with skin, eyes and clothing. Wear recommended personal protective equipment. (See section 8)

Storage

Keep only in the original container in a well-ventilated and dry place.

Hygiene

Wash hands before and after working with the product. When using, do not eat, drink or smoke.

Fire prevention

Remove all sources of ignition (open fire, sparks, smoking, ...).

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Viscous liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Colourless to amber
Colour Intensity
---
Form
Clear
Odor
Odour of ammonia
Odor Threshold
No data available.
Ph
10,5 (1,5 g/ 100ml)
Melting Point
app. 21 °C
Boiling Point
336 °C (Decomposes)
Flash Point
OC: 179 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
0.01 (Butyl acetate =1)
Vapor Pressure
< 0,001 kPa
Vapor Density
---
Relative Density
1,1
Bulk Density
---
Density
1,125 g/cm3
Flammability
---
Upper Explosive Limit
8,5 vol.%
Lower Explosive Limit
1,3 vol.%
Explosive Limits
---
Auto Ignition Temperature
app. 324 °C
Decomposition Temperature
> 335 °C
Solubility
---
Partition Coefficient
-2,3
Solubility In Water
100 g/ 100ml
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
934 mPa.s (Dynamic)
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable at normal circumstances.

Reactivity

Reacts violently with oxidizing agents and acids.

Hazardous reactions

Reacts with : Nitrites => Creation of: Nitrosamine. Reacts with aluminium above 60°C forming hydrogen gas.

Avoid

High temperatures.

Incompatible

Oxidizing agents, Acids, Nitrites, Copper, Light metals, Some synthetics.

Decomposition

Carbon oxides, Nitrogen oxides, Nitrogen compounds (Nitrosamine).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

• 2,2',2''-nitrilotriethanol : LC50 (Fish, 96 h) : 11800 mg/l (Pimephales promelas) (OECD Guideline 203) • 2,2',2''-nitrilotriethanol : EC50 (Algae, 72 h) : 512 mg/l (Scenedesmus subspicatus) (OECD Guideline 201) • 2,2',2''-nitrilotriethanol : EC50 (Daphnia magna, 48 h) : 609,9 mg/l (Ceriodaphnia dubia) (OECD Guideline 202) • 2,2',2''-nitrilotriethanol : NOEC (Daphnia magna, 21 d) : 16 mg/l (OECD Guideline 211)

12.1. Toxicity

• 2,2'-Iminodiethanol : LC50 (Fish, 96 h) : 1460 mg/l (Pimephales promelas) • 2,2'-Iminodiethanol : EC50 (Algae, 96 h) : 2,2 mg/l (Pseudokirchneriella subcapitata) • 2,2'-Iminodiethanol : EC50 (Daphnia magna, 48 h) : 55 mg/l • 2,2'-Iminodiethanol : NOEC (Daphnia magna, 21 d) : 0,78 mg/l

12.2. Persistence and degradability

• 2,2',2''-nitrilotriethanol : Persistence and degradability : Readily biodegradable.

Readily biodegradable.

12.2. Persistence and degradability

• 2,2'-Iminodiethanol : Persistence and degradability : Readily biodegradable.

12.3. Bioaccumulative potential

• 2,2',2''-nitrilotriethanol : Bioaccumulation : Low potential to bioaccumulate.

12.3. Bioaccumulative potential

• 2,2'-Iminodiethanol : Bioaccumulation : Low potential to bioaccumulate.

12.4. Mobility in soil

* Mobility : For components : • 2,2',2''-nitrilotriethanol : Mobility : Very high potential for mobility in soil. • 2,2'-Iminodiethanol : Mobility : Very high potential for mobility in soil.

12.5. Results of PBT and vPvB assessment

Evaluation : For components : • 2,2',2''-nitrilotriethanol : PBT/vPvB : No • 2,2'-Iminodiethanol : PBT/vPvB : No

The components 2,2',2''-nitrilotriethanol and 2,2'-Iminodiethanol are not classified as PBT or vPvB.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The product has to be destroyed according to national or local legislation, by a company specialised in handling hazardous waste products.

Disposal

The product has to be destroyed according to national or local legislation, by a company specialised in handling hazardous waste products.

Waste Codes

XXXXXX European waste product code. This code is assigned on the basis of the most current applications and can not be representative for pollutions which are arisen at the effective use of the product. The producer of the waste has to evaluate its process himself and has to grant the appropriate waste coding. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Decontamination exertion : No data available.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 2,2',2''-nitrilotriethanol known by?

2,2',2''-nitrilotriethanol is also known as: Triethanolamine , TEA

What is the hazard signal word for 2,2',2''-nitrilotriethanol?

The signal word is no signal word.

What is the physical form of 2,2',2''-nitrilotriethanol?

2,2',2''-nitrilotriethanol is a viscous liquid with colourless to amber color. It has odour of ammonia odor.

What is 2,2',2''-nitrilotriethanol used for?

Anti-corrosion agent , Solvent , Intermediate ( Organic chemistry . ) Emulsifier ( Metal industry , Oils , Fuel , Paints , Cement , Cosmetics , Synthetic material , Household products )

What is the melting point of 2,2',2''-nitrilotriethanol?

The melting point is app. 21 °C and the boiling point is 336 °C (Decomposes).