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Safety Data Sheet EN

2,2',2''-nitrilotriethanol , Triethanolamine , TEA, solution (>85%) with 2,2'Iminodiethanol , Diethanolamine , DEA (10<15%)

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
2,2',2''-nitrilotriethanol , Triethanolamine , TEA, solution (>85%) with 2,2'Iminodiethanol , Diethanolamine , DEA (10<15%)

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Anti-corrosion agent Additif Intermediate

Uses advised against

Non identified . Not for use in ornamental articles, in tricks and jokes and in games (in accordance with Annex XVII to Regulation (EC) No 1907/2006) (3. Liquid substances or mixtures, which are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: (a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F, (b) hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10, (c) hazard class 4.1, (d) hazard class 5.1).

Manufacturers & Suppliers

BRENNTAG N.V. logo

BRENNTAG N.V.

national supplier

Nijverheidslaan 38 - BE-8540 DEERLIJK

+32(0)56/77.69.44

http://www.brenntag.be

BRENNTAG Nederland B.V. logo

BRENNTAG Nederland B.V.

national supplier

Donker Duyvisweg 44 - NL-3316 BM DORDRECHT

+31(0)78/65.44.944

http://www.brenntag.nl

Emergency Contacts

Antipoison Center - Brussels

+32(0)70/245.245

National Poisoning Information Center - Bilthoven

+31(0)30/274.88.88

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318
STOT RE Cat. 2 H373

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 Causes skin irritation.
H318 Causes serious eye damage.
H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338 IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/
P314 Get medical advice if you feel unwell.
P501 Dispose of this material and its container to hazardous or special waste collection point.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
2,2',2''-nitrilotriethanol EC: 203-049-8 102-71-6 85% No
2,2'-Iminodiethanol EC: 203-868-0 111-42-2 10 - 15% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim into fresh air. If not breathing, give artificial respiration. Allow the affected person to rest in semi-sitting position. Consult a doctor.

Skin contact

Remove contaminated clothing. Rinse skin immediately with plenty of water. (shower if necessary). Consult doctor if irritation develops.

Eye contact

Rinse immediately thoroughly and long (at least 15 min.) with plenty of water. Remove contact lenses. Immediately call a POISON CENTER or doctor/physician. Keep rinsing or dripping the eye during transport.

Ingestion

DO NOT INDUCE VOMITING. Rinse mouth with water. Give 2 glasses of water to drink. Seek medical advice.

Immediate Medical Attention

For specialist advice doctors should contact the NVCI or the Belgian Poison center.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Extinguishing powder, Foam, Carbon dioxide (CO2), Water spray.

Unsuitable media

Heavy water stream.

Specific hazards

Fire may liberate Carbon oxides (CO) and Nitrogen oxides (NOx).

Instructions

Apply water spray or fog to cool nearby equipment.

Firefighter Protection

Use self-contained breathing apparatus and wear protective clothes when in close proximity to fire.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Shut off leaks if without risks.

Environmental

Shut off leaks if without risks. Dike in the spilled product as much as possible with inert material. Prevent entry of product in public water, sewers or soil. Notify authorities if product enters sewers or public waters.

Cleanup methods

Collect the spillage in closable, suitable disposal containers.

Materials: inert absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Attention : SKIN ABSORPTION ! Avoid breathing vapour and contact with skin, eyes and clothing. Wear recommended personal protective equipment. (See section 8) Wash hands before and after working with the product. When using, do not eat, drink or smoke. Emergency eye wash fountains and showers should be available in the immediate vicinity of any potential exposure.

Storage

Keep only in the original container in a cool, well-ventilated and dry place. All dangerous products should be placed on a drip tray or should be barreled.

Hygiene

Wash hands before and after working with the product. When using, do not eat, drink or smoke.

Fire prevention

Remove all sources of ignition (open fire, sparks, smoking, ...). Vapours are heavier than air and spread along the ground.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colourless to light yellow
Colour
Colourless to light yellow
Colour Intensity
---
Form
---
Odor
Slight odour of ammonia
Odor Threshold
Not applicable
Ph
app. 11 (20 g/l, 20°C)
Melting Point
14 - 18 °C
Boiling Point
Not applicable
Flash Point
app. 197 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
0,01 ( Butyl acetate =1)
Vapor Pressure
< 0,01 kPa
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
app. 1,12 g/cm³
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
1,2 - vol.%
Explosive Limits
---
Auto Ignition Temperature
app. 330 °C
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
-1,75
Solubility In Water
Completely soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0,6 Pa.s
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable at normal circumstances .

Reactivity

Reacts with : Strong acids , Oxidizing agents .

Hazardous reactions

Exothermic reaction with: Strong acids . Reacts with Oxidizing agents => May cause fire and explosion! Reacts with aluminium above 60°C forming hydrogen gas.

Avoid

High temperatures .

Incompatible

Strong acids , Oxidizing agents .

Decomposition

Carbon oxides , Nitrogen oxides .

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

• 2,2',2''-nitrilotriethanol : LC50 (Fish, 96 h) : 11800 mg/l (Pimephales promelas) ( OECD Guideline 203) • 2,2',2''-nitrilotriethanol : EC50 (Algae, 72 h) : 512 mg/l (Scenedesmus subspicatus) ( OECD Guideline 201) • 2,2',2''-nitrilotriethanol : EC50 (Daphnia magna, 48 h) : 609,9 mg/l (Ceriodaphnia dubia) ( OECD Guideline 202) • 2,2',2''-nitrilotriethanol : NOEC (Daphnia magna, 21 d) : 16 mg/l ( OECD Guideline 211)

12.1. Toxicity

• 2,2'-Iminodiethanol : LC50 (Fish, 96 h) : 1460 mg/l (Pimephales promelas) • 2,2'-Iminodiethanol : EC50 (Algae, 96 h) : 2,2 mg/l (Pseudokirchneriella subcapitata) • 2,2'-Iminodiethanol : EC50 (Daphnia magna, 48 h) : 55 mg/l • 2,2'-Iminodiethanol : NOEC (Daphnia magna, 21 d) : 0,78 mg/l

12.2. Persistence and degradability

Persistence and degradability: For components:

12.2. Persistence and degradability

• 2,2',2''-nitrilotriethanol : Persistence and degradability : Readily biodegradable .

The substance is readily biodegradable.

12.2. Persistence and degradability

2,2'-Iminodiethanol : Persistence and degradability : Readily biodegradable .

The substance is readily biodegradable.

12.3. Bioaccumulative potential

• 2,2',2''-nitrilotriethanol : Bioaccumulation : Low potential to bioaccumulate.

12.3. Bioaccumulative potential

• 2,2'-Iminodiethanol : Bioaccumulation : Low potential to bioaccumulate.

12.4. Mobility in soil

Mobility: For components: • 2,2',2''-nitrilotriethanol : Mobility : Very high potential for mobility in soil. • 2,2'-Iminodiethanol : Mobility : Very high potential for mobility in soil.

12.5. Results of PBT and vPvB assessment

Evaluation: For components: • 2,2',2''-nitrilotriethanol : PBT/vPvB : No • 2,2'-Iminodiethanol : PBT/vPvB : No

12.6. Other adverse effects

Photochemical ozone creation potential: No data available. Ozone depletion potential: This substance is not in Annex I of Regulation (EC) No 2037/2000 on substances that deplete the ozone layer. Endocrine disrupting potential: No data available. Global warming potential: No data available.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The product has to be destroyed according to national or local legislation, by a company specialised in handling hazardous waste products.

Disposal

The product has to be destroyed according to national or local legislation, by a company specialised in handling hazardous waste products.

Waste Codes

XXXXXX European waste product code. This code is assigned on the basis of the most current applications and can not be representative for pollutions which are arisen at the effective use of the product. The producer of the waste has to evaluate its process himself and has to grant the appropriate waste coding. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 2,2',2''-nitrilotriethanol , Triethanolamine , TEA, solution (>85%) with 2,2'Iminodiethanol , Diethanolamine , DEA (10<15%)?

The signal word is danger.

What is the physical form of 2,2',2''-nitrilotriethanol , Triethanolamine , TEA, solution (>85%) with 2,2'Iminodiethanol , Diethanolamine , DEA (10<15%)?

2,2',2''-nitrilotriethanol , Triethanolamine , TEA, solution (>85%) with 2,2'Iminodiethanol , Diethanolamine , DEA (10<15%) is a liquid appearing as colourless to light yellow with colourless to light yellow color. It has slight odour of ammonia odor.

What is 2,2',2''-nitrilotriethanol , Triethanolamine , TEA, solution (>85%) with 2,2'Iminodiethanol , Diethanolamine , DEA (10<15%) used for?

Anti-corrosion agent Additif Intermediate

What are the hazard statements for 2,2',2''-nitrilotriethanol , Triethanolamine , TEA, solution (>85%) with 2,2'Iminodiethanol , Diethanolamine , DEA (10<15%)?

This substance has 3 hazard statements:

  • H315: Causes skin irritation.
  • H318: Causes serious eye damage.
  • H373: May cause damage to organs through prolonged or repeated exposure.

What is the melting point of 2,2',2''-nitrilotriethanol , Triethanolamine , TEA, solution (>85%) with 2,2'Iminodiethanol , Diethanolamine , DEA (10<15%)?

The melting point is 14 - 18 °C and the boiling point is Not applicable.