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Safety Data Sheet EN

Frigutec® OAT+

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Frigutec® OAT+

Regulatory Identifiers

CAS Number
N/A
UFI Code
1QD4-GRJ1-M30W-4S6A

Identified Uses

Anti-freezing agent Cooling agent

Uses advised against

No further relevant information available.

Manufacturers & Suppliers

H

HVL GmbH

manufacturer

79410 Badenweiler, Germany

+49-7632-823480

Emergency Contacts

Vergiftungs-Informations-Zentrale Freiburg

+49 (0) 761 19240

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
STOT RE Cat. 2 H373

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H373 May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves / eye protection / face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P330 Rinse mouth.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Ethanediol EC: 203-473-3 107-21-1 85% Yes
Potassium isononanoate EC: 282-991-1 84501-71-3 3% Yes
methyl-1H-benzotriazole EC: 249-596-6 29385-43-1 0.3% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air.

Skin contact

Immediately rinse with water.

Eye contact

Remove contact lenses, if present and easy to do. Continue rinsing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Ingestion

Rinse out mouth and then drink plenty of water. Do NOT induce vomiting.

Immediate Medical Attention

Seek medical treatment. If skin irritation continues, consult a doctor. If symptoms persist consult doctor.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO₂, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Use fire extinguishing methods suitable to surrounding conditions.

Unsuitable media

Water with full jet

Specific hazards

Formation of toxic gases is possible during heating or in case of fire.

Instructions

Cool endangered receptacles with water spray.

Firefighter Protection

Wear self-contained respiratory protective device.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Dilute with plenty of water.

Cleanup methods

Absorb with liquid-binding material

Materials: sand, diatomite, acid binders, universal binders, sawdust

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols.

Storage

Store in cool, dry conditions in well sealed receptacles.

Fire prevention

No special measures required.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No further data; see section 7.

Hands

Protective gloves. Only use chemical-protective gloves with CE-labelling of category III. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eyes

Tightly sealed goggles

Respiratory

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

Skin/Body

Protective work clothing

Environmental

No further relevant information available.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
According to product specification
Colour Intensity
---
Form
Fluid
Odor
Not determined.
Odor Threshold
Not determined.
Ph
7.5 - 9 (50%)
Melting Point
Not determined.
Boiling Point
170 - 185 °C
Flash Point
111 °C (CAS: 107-21-1 Ethanediol)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not determined.
Vapor Pressure
Not determined.
Vapor Density
Not determined.
Relative Density
Not determined.
Bulk Density
---
Density
Not determined.
Flammability
Not applicable.
Upper Explosive Limit
Not applicable.
Lower Explosive Limit
Not applicable.
Explosive Limits
---
Auto Ignition Temperature
398 °C (CAS: 107-21-1 Ethanediol)
Decomposition Temperature
Not determined.
Solubility
Fully miscible.
Partition Coefficient
107-21-1 Ethanediol: -1,36 log Pow; 29385-43-1 methyl-1H-benzotriazole: 1,079 - ≤ 1,083 logPow (25°C, OECD Guideline 117)
Solubility In Water
Fully miscible.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not determined.
Kinematic Viscosity
Not determined.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

No decomposition if used and stored according to specifications.

Reactivity

No further relevant information available.

Hazardous reactions

No dangerous reactions known.

Avoid

No decomposition if used according to specifications.

Incompatible

No further relevant information available.

Decomposition

No dangerous decomposition products known.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Aquatic toxicity: CAS: 107-21-1 Ethanediol

12.1 Toxicity

Aquatic toxicity: CAS: 107-21-1 Ethanediol LC50 (96h) (static) 72860 mg/L (fish) (EPA 600/4-90/027, Pimephales promelas) EC20 (0,5h) (static) > 1995 mg/L (Bacteria) (ISO 8192, activated sludge) Read-across to CAS 111-46-6 EC50 (96h) 6500 - 13000 mg/L (algae) (EPA 600/9-78-018) EC50 (48h) (static) > 100 mg/L (Daphnia) (OECD Guideline 202, Daphnia magna) NOEC 8590 mg/L (Daphnia) (EPA 600/4-89/001, Ceriodaphnia dubia) semi-static 15380 mg/L (fish) (EPA EPA 600/4-89/001 (7d), Pimephales promelas) semi-static

12.1 Toxicity

Aquatic toxicity: CAS: 93918-10-6 Potassium3,5,5-trimethylhexanoate | NOEC (48h) (static) | ≥ 100 mg/L (Daphnia) (OECD Guideline 202, Daphnia magna) freshwater |

12.1 Toxicity

Aquatic toxicity: CAS: 29385-43-1 methyl-1H-benzotriazole | LC50 (48h) (static) | 55 mg/L (Invertebrates) (ISO/CD 14669, Acartia tonsa) nominal | | --- | --- | | LC50 (96h) | 180 mg/L (fish) (OECD Guideline 203, Danio rerio) read-across | | ErC50 (72h) (static) | 75 mg/L (algae) (OECD Guideline 201, Pseudokirchneriella subcapitata) read-across nominal | | EC50 (48h) (static) | 8.58 mg/L (Daphnia) (OECD Guideline 202) read-across to 5-Methyl-benzotriazole | | EC50 (24h) (static) | 1060 mg/L (Bacteria) (ISO 8192, activated sludge) Read-across to CAS 95-16-9 nominal |

12.2 Persistence and degradability

12.2 Persistence and degradability

29385-43-1 methyl-1H-benzotriazole 4 % (28d, EU Method C.4-D)

12.3 Bioaccumulative potential

No further relevant information available.

12.4 Mobility in soil

No further relevant information available.

12.5 Results of PBT and vPvB assessment

Not determined.

12.6 Endocrine disrupting properties

The product does not contain substances with endocrine disrupting properties.

12.7 Other adverse effects

No further relevant information available.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Must be specially treated adhering to official regulations.

Disposal

Must be specially treated adhering to official regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Frigutec® OAT+?

The signal word is warning.

What is the physical form of Frigutec® OAT+?

Frigutec® OAT+ is a liquid with according to product specification color. It has not determined. odor.

What is the solubility of Frigutec® OAT+?

Fully miscible.

What is Frigutec® OAT+ used for?

Anti-freezing agent Cooling agent

What are the hazard statements for Frigutec® OAT+?

This substance has 4 hazard statements:

  • H302: Harmful if swallowed.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H373: May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral.

What is the melting point of Frigutec® OAT+?

The melting point is Not determined. and the boiling point is 170 - 185 °C.