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Safety Data Sheet EN

ACRYSOL™ RM-5000 Rheology Modifier

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ACRYSOL™ RM-5000 Rheology Modifier

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Coating additives, Rheology Modifiers.

Manufacturers & Suppliers

D

DOW BENELUX B.V.

manufacturer

HERBERT H.DOWWEG 5, HOEK, 4542 NM TERNEUZEN, NETHERLANDS

(31) 115 67 2626

Emergency Contacts

Emergency Contact

31-(0)115 694982

Emergency Contact

00 32 3575 0330

Belgium Poison Center

070/245.245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) EC: 611-341-5 55965-84-9 0.0001 - 0.0015% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move person to fresh air and keep comfortable for breathing; consult a physician.

Skin contact

Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation or rash occurs. Wash clothing before reuse. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands.

Eye contact

Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist.

Ingestion

Rinse mouth with water. No emergency medical treatment necessary.

Medical Treatment

Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical. Water spray.

Unsuitable media

None known.

Specific hazards

Exposure to combustion products may be a hazard to health.. Dried product can burn.. Material can splatter above 100C/212F..

Instructions

Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so.

Firefighter Protection

Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Material can create slippery conditions. Follow safe handling advice and personal protective equipment recommendations.

Large spill

For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container.

Environmental

Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water.

Cleanup methods

Soak up with inert absorbent material. Clean up remaining materials from spill with suitable absorbant.

Materials: inert absorbent material, suitable absorbant

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Take care to prevent spills, waste and minimize release to the environment. Handle in accordance with good industrial hygiene and safety practice. Monomer vapors can be evolved when material is heated during processing operations. Use only with adequate ventilation.

Storage

Keep in properly labelled containers. Store in accordance with the particular national regulations. STIR WELL BEFORE USE – product quality may be affected.

Hygiene

Handle in accordance with good industrial hygiene and safety practice.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations.

Hands

Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Neoprene. Avoid gloves made of: Polyvinyl alcohol ("PVA"). When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374) is recommended. Glove thickness alone is not a good indicator of the level of protection a glove provides against a chemical substance as this level of protection is also highly dependent on the specific composition of the material that the glove is fabricated from. The thickness of the glove must, depending on model and type of material, generally be more than 0.35 mm to offer sufficient protection for prolonged and frequent contact with the substance. As an exception to this general rule it is known that multilayer laminate gloves may offer prolonged protection at thicknesses less than 0.35 mm. Other glove materials with a thickness of less than 0.35 mm may offer sufficient protection when only brief contact is expected. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Eyes

Use safety glasses (with side shields). Safety glasses (with side shields) should be consistent with EN 166 or equivalent.

Respiratory

Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions no respiratory protection should be needed; however, if discomfort is experienced, use an approved air-purifying respirator. Use the following CE approved air-purifying respirator: Organic vapor cartridge with a particulate pre-filter, type AP2 (meeting standard EN 14387).

Skin/Body

Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.

Environmental

See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear to hazy colorless to pale yellow
Colour
Clear to hazy colorless to pale yellow
Colour Intensity
---
Form
---
Odor
mild
Odor Threshold
---
Ph
4 - 8
Melting Point
0 °C Water
Boiling Point
100 °C Water
Flash Point
Noncombustible
Freezing Point
not determined
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
(Butyl Acetate = 1) <1 Water
Vapor Pressure
17 mmHg at 20 °C Water
Vapor Density
---
Relative Density
1,0 - 1,2
Bulk Density
---
Density
---
Flammability
Not applicable, liquid
Upper Explosive Limit
Not applicable
Lower Explosive Limit
Not applicable
Explosive Limits
---
Auto Ignition Temperature
Not applicable
Decomposition Temperature
not determined
Solubility
---
Partition Coefficient
not determined
Solubility In Water
partly miscible
Solubility In Fat
---
Molecular Weight
not determined
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
2 000 - 4 000 mPa.s
Kinematic Viscosity
not determined
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

Not classified as a reactivity hazard.

Hazardous reactions

None known. Product will not undergo polymerization.

Avoid

None known.

Incompatible

strong oxidizing agents

Decomposition

There are no known hazardous decomposition products for this material.. Monomer vapors can be evolved when material is heated during processing operations. See SECTION 8, for types of ventilation required..

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

There is no data available for this product.

No data available.

12.2 Persistence and degradability

There is no data available for this product.

No data available.

12.3 Bioaccumulative potential

There is no data available for this product.

No data available.

12.4 Mobility in soil

There is no data available for this product.

No data available.

12.5 Results of PBT and vPvB assessment

There is no data available for this product.

No data available.

12.6 Endocrine disrupting properties

There is no data available for this product.

No data available.

12.7 Other adverse effects

There is no data available for this product.

No data available.

12.1 Toxicity

reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) Acute toxicity to fish Material is very toxic to aquatic organisms (LC50/EC50/IC50 below 1 mg/L in the most sensitive species). LC50, Oncorhynchus mykiss (rainbow trout), flow-through test, 96 Hour, 0,19 mg/l, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates LC50, Daphnia magna (Water flea), flow-through test, 48 Hour, 0,16 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants NOEC, Skeletonema costatum (marine diatom), Static, 48 Hour, 0,00049 mg/l, OECD Test Guideline 201 ErC50, Skeletonema costatum (marine diatom), Static, 48 Hour, 0,0052 mg/l, OECD Test Guideline 201 Chronic toxicity to fish NOEC, Rainbow trout (Oncorhynchus mykiss), flow-through, 14 d, 0,05 mg/l Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna, flow-through test, 21 d, 0,1 mg/l

12.2 Persistence and degradability

reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) Biodegradability: Considered to be rapidly degradable. Material is not readily biodegradable according to OECD/EEC guidelines. Biodegradation: < 50 % Exposure time: 10 d Photodegradation Atmospheric half-life: 0,38 - 1,3 d

12.3 Bioaccumulative potential

Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). 2-Methyl-4-isothiazolin-3-one(MIT): 5-Chloro-2-methyl-4-isothiazolin-3-one (CMIT): Partition coefficient: n-octanol/water(log Pow): -0,486 Measured Partition coefficient: n-octanol/water(log Pow): 0,401 Measured

Bioconcentration potential is low (BCF < 100 or Log Pow < 3).

12.4 Mobility in soil

Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Partition coefficient (Koc): 28 Estimated.

12.5 Results of PBT and vPvB assessment

This substance has not been assessed for persistence, bioaccumulation and toxicity (PBT).

The substance has not been assessed for persistence, bioaccumulation and toxicity (PBT).

12.6 Endocrine disrupting properties

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. **reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1)** The substance is not considered to have endocrine disrupting properties according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100.

The substance is not considered to have endocrine disrupting properties according to the specified regulations.

12.7 Other adverse effects

reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

The substance is not listed on the Montreal Protocol list of substances that deplete the ozone layer.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

For uncontaminated material the disposal options include mechanical and chemical recycling or energy recovery. In some countries landfill is also allowed.

Disposal

For contaminated material the options remain the same, although additional evaluation is required.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This product contains only components that have been either registered, are exempt from registration, are regarded as registered or are not subject to registration according to Regulation (EC) No. 1907/2006 (REACH). Polymers are exempted from registration under REACH. All relevant starting materials and additives have been either registered or are exempt from registration according to Regulation (EC) No. 1907/2006 (REACH).

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for ACRYSOL™ RM-5000 Rheology Modifier?

The signal word is no signal word.

What is the physical form of ACRYSOL™ RM-5000 Rheology Modifier?

ACRYSOL™ RM-5000 Rheology Modifier is a liquid appearing as clear to hazy colorless to pale yellow with clear to hazy colorless to pale yellow color. It has mild odor.

What is ACRYSOL™ RM-5000 Rheology Modifier used for?

Coating additives, Rheology Modifiers.

What is the melting point of ACRYSOL™ RM-5000 Rheology Modifier?

The melting point is 0 °C Water and the boiling point is 100 °C Water.