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Safety Data Sheet EN

SODIUM HYDROXIDE 33% RE ISCC+

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
SODIUM HYDROXIDE 33% RE ISCC+

Regulatory Identifiers

CAS Number
N/A
UFI Code
AJ1J-T131-X002-VS4P

Identified Uses

Identified use: See table in front of appendix for a complete overview of identified uses.

Uses advised against

At this moment we have not identified any uses advised against

Manufacturers & Suppliers

B

Brenntag N.V.

manufacturer

Nijverheidslaan 38 BE 8540 Deerlijk

+32 (0)56 77 6944

B

Brenntag Nederland B.V.

manufacturer

Donker Duyvisweg 44 NL 3316 BM Dordrecht

+31 (0)78 65 44 944

Emergency Contacts

Antipoison Center - Brussels

+32(0)70 245 245

National Poisoning Information Center - Bilthoven

+31(0) 88 755 8000

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.

Precautionary Statements

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P390 Absorb spillage to prevent material damage.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
sodium hydroxide EC: 215-185-5 1310-73-2 30 - 35% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

In case of accident by inhalation: remove casualty to fresh air and keep at rest. If breathing is irregular or stopped, administer artificial respiration. Call a physician immediately.

Skin contact

Call a physician immediately. Wash off immediately with soap and plenty of water.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult an eye specialist immediately. Go to an ophthalmic hospital if possible.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Call a physician immediately.

Symptoms: Severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus and the stomach.

Immediate Medical Attention

Call a physician immediately.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

High volume water jet

Specific hazards

Incomplete combustion may form toxic pyrolysis products.

Instructions

Control smoke with water spray.

Firefighter Protection

In the event of fire, wear self-contained breathing apparatus. Wear appropriate body protection (full protective suit)

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep away unprotected persons. Use personal protective equipment. Ensure adequate ventilation. Avoid contact with the skin and the eyes. Do not breathe vapours or spray mist.

Environmental

Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.

Cleanup methods

Absorb with liquid-binding material. Use mechanical handling equipment.

Materials: sand, diatomite, acid binders, universal binders

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep container tightly closed. Ensure adequate ventilation. Use personal protective equipment. Avoid contact with skin, eyes and clothing. Do not breathe vapours or spray mist. Use respirator with appropriate filter if vapours or aerosol are released. Emergency eye wash fountains and emergency showers should be available in the immediate vicinity.

Storage

Keep tightly closed in a dry and cool place. Keep in a well-ventilated place.

Hygiene

Keep away from food, drink and animal feedingstuffs. Smoking, eating and drinking should be prohibited in the application area. Wash hands before breaks and at the end of workday. Take off all contaminated clothing immediately.

Fire prevention

Normal measures for preventive fire protection.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Refer to protective measures listed in sections 7 and 8.

Hands

Wear suitable gloves. The glove material has to be impermeable and resistant to the product / the substance / the preparation. Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Protective gloves should be replaced at first signs of wear. Material : Natural Rubber Break through time : >= 8 h Glove thickness : 0,5 mm; Material : polychloroprene Break through time : >= 8 h Glove thickness : 0,5 mm; Material : Nitrile rubber Break through time : >= 8 h Glove thickness : 0,35 mm; Material : butyl-rubber Break through time : >= 8 h Glove thickness : 0,5 mm; Material : Fluorinated rubber Break through time : >= 8 h Glove thickness : 0,4 mm; Material : Polyvinylchloride Break through time : >= 8 h Glove thickness : 0,5 mm

Eyes

Safety goggles; Face-shield

Respiratory

In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use self-contained breathing apparatus. Equipment should conform to EN 14387 Filter Type : P2 filter

Skin/Body

Impervious clothing; Chemical resistant apron

Environmental

Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. If the product contaminates rivers and lakes or drains inform respective authorities. If material reaches soil inform authorities responsible for such cases.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless
Colour Intensity
---
Form
liquid
Odor
odourless
Odor Threshold
Not applicable
Ph
14 - 15 Concentration: 100 % Method: (calculated)
Melting Point
< 12 °C
Boiling Point
105 °C 10% solution
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable
Vapor Pressure
negligible
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
ca. 1,38 g/cm3 (20 °C) 35% solution
Flammability
non-combustible
Upper Explosive Limit
Not applicable
Lower Explosive Limit
Not applicable
Explosive Limits
---
Auto Ignition Temperature
Not applicable
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
This product is inorganic substance.
Solubility In Water
1090 g/l (20 °C)
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
Corrosive to metals
Dynamic Viscosity
No data available
Kinematic Viscosity
Not applicable
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

No decomposition if stored and applied as directed.

Hazardous reactions

Corrosive in contact with metals Gives off hydrogen by reaction with base metals (zinc, aluminium). Reacts exothermically with water. Reacts exothermic with acids.

Avoid

Heat, flames and sparks.

Incompatible

Acids, Light metals, Alcohols, Halogenated hydrocarbon

Decomposition

hydrogen products

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1. Toxicity

Component: sodium hydroxide CAS-No. 1310-73-2 Acute toxicity Fish LC50 : 125 mg/l (Gambusia affinis; 96 h) (No guideline followed) LC50 145 mg/l (Poecilia reticulata; 24 h) (No guideline followed) Toxicity to daphnia and other aquatic invertebrates EC50 : 40,4 mg/l (Ceriodaphnia (water flea); 48 h) (No guideline followed) algae : No data available

12.2. Persistence and degradability

Component: sodium hydroxide CAS-No. 1310-73-2 Persistence and degradability Persistence Result: No data available Biodegradability Result: The methods for determining the biologic applicable to inorganic substances.

12.3. Bioaccumulative potential

12.3. Bioaccumulative potential

|**Component:**|**sodium hydroxide**|**CAS-No.** **1310-73-2**| |---|---|---| ||**Bioaccumulation**|| |Result|: Does not bioaccumulate.||

Does not bioaccumulate.

12.4. Mobility in soil

Component: sodium hydroxide CAS-No. 1310-73-2 Mobility Water: Good soluble in water. Air: not volatile Soil: Low potential for adsorption (based on substance properties).

12.5. Results of PBT and vPvB assessment

The PBT or vPvB criteria of Annex XIII to the REACH Regulation does not apply to inorganic substances.

The PBT or vPvB criteria of Annex XIII to the REACH Regulation does not apply to inorganic substances.

Results of PBT and vPvB assessment

The PBT or vPvB criteria of Annex XIII to the REACH Regulation does not apply to inorganic substances.

The PBT or vPvB criteria of Annex XIII to the REACH Regulation does not apply to inorganic substances.

12.6. Endocrine disrupting properties

Data for the product Endocrine disrupting potential: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Component: sodium hydroxide CAS-No. 1310-73-2 Endocrine disrupting potential: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

12.7. Other adverse effects

Harmful effects to aquatic organisms due to pH-shift. Neutralization is normally necessary before waste water is discharged into water treatment plants. Do not flush into surface water or sanitary sewer system.

Harmful effects to aquatic organisms due to pH-shift. Neutralization is required before discharge.

12.1. Toxicity

![img-27.png](img-27.png)
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Disposal together with normal waste is not allowed. Special disposal required according to local regulations. Do not let product enter drains. Contact waste disposal services. This product shall be disposed of or recovered in compliance with Directive 2008/98/EC on waste as lastly amended.

Disposal

Disposal together with normal waste is not allowed. Special disposal required according to local regulations.

Waste Codes

No waste code according to the European Waste Catalogue can be assigned for this product, as the intended use dictates the assignment. The waste code is established in consultation with the regional waste disposer. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1824
Shipping Name
SODIUM HYDROXIDE SOLUTION
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

SDS updated according to Regulation (EU) 2020/878

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for SODIUM HYDROXIDE 33% RE ISCC+?

The signal word is danger.

What is the physical form of SODIUM HYDROXIDE 33% RE ISCC+?

SODIUM HYDROXIDE 33% RE ISCC+ is a liquid with colourless color. It has odourless odor.

What is SODIUM HYDROXIDE 33% RE ISCC+ used for?

Identified use: See table in front of appendix for a complete overview of identified uses.

What are the hazard statements for SODIUM HYDROXIDE 33% RE ISCC+?

This substance has 2 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.

What is the melting point of SODIUM HYDROXIDE 33% RE ISCC+?

The melting point is < 12 °C and the boiling point is 105 °C 10% solution.