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Safety Data Sheet EN

2-(Dimethylamino)-ethanol for synthesis

CAS 108-01-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
2-(Dimethylamino)-ethanol for synthesis
Product Code
8.03237
Chemical Name
2-(Dimethylamino)-ethanol

Regulatory Identifiers

CAS Number
108-01-0 Check regulations →

Identified Uses

Chemical for synthesis

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

Frankfurter Str. 250 D-64271 DARMSTADT

+49 (0)6151 72-0

Emergency Contacts

CHEMTREC (GB)

+(44)-870-8200418

CHEMTREC Ireland

+(353)-19014670

CHEMTREC India

001-803-017-9114

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 3 H331
Acute Tox. Cat. 4 H312
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H335

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H226 Flammable liquid and vapor.
H302 + H312 Harmful if swallowed or in contact with skin.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
2-dimethylaminoethanol EC: 203-542-8 108-01-0 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Call a physician immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2) Foam Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Carbon oxides, Nitrogen oxides (NOx). Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.

Instructions

Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains. Risk of explosion.

Cleanup methods

Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Clean up affected area.

Materials: liquid-absorbent material (e.g. Chemizorb®)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Butoject® (KCL 898). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,4 mm Break through time: 30 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M)

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds. The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
clear, colorless
Colour Intensity
---
Form
---
Odor
amine-like
Odor Threshold
---
Ph
10,5 - 11 at 100 g/l at 20 °C
Melting Point
-59 °C
Boiling Point
134,1 °C at ca.1.013 hPa
Flash Point
40 °C - Seta closed cup - DIN 51755 Part 1
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
6,12 hPa at 20 °C
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
0,89 g/cm3 at 20 °C
Flammability
---
Upper Explosive Limit
12,2 %(V)
Lower Explosive Limit
1,4 %(V)
Explosive Limits
---
Auto Ignition Temperature
230 °C at 1.013 hPa - DIN 51794
Decomposition Temperature
---
Solubility
---
Partition Coefficient
log Pow: -0,55 at 23 °C - Bioaccumulation is not expected., n-octanol/water (External MSDS)
Solubility In Water
soluble at 20 °C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
3,85 mPa.s at 20 °C
Kinematic Viscosity
ca.3,58 mm2/s at ca.21,6 °C
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature) .

Reactivity

Vapor/air-mixtures are explosive at intense warming.

Hazardous reactions

Violent reactions possible with: Strong oxidizing agents Isocyanates acid halides acids. Caution! In contact with nitrites, nitrates, nitrous acid possible liberation of nitrosamines!

Avoid

Heating.

Incompatible

No data available

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Toxicity to fish LC50 - Leuciscus idus (Golden orfe) - > 100 - 220 mg/l - 96 h static test LC50 - Leuciscus idus (Golden orfe) - 146,6 mg/l - 96 h (DIN 38412 T15) Toxicity to daphnia static test EC50 - Daphnia magna (Water flea) - 98,37 mg/l - 48 h and other aquatic (OECD Test Guideline 202) invertebrates Toxicity to algae static test ErC50 - Desmodesmus subspicatus (green algae) - 35 mg/l - 72 h Remarks: (External MSDS) static test EC50 - Desmodesmus subspicatus (green algae) - 66,08 mg/l - 72 h Toxicity to bacteria static test EC20 - activated sludge - > 1.000 mg/l - 0,5 h (OECD Test Guideline 209)

12.2 Persistence and degradability

Biodegradability aerobic - Exposure time 28 d Result: > 60 % - Readily biodegradable. (OECD Test Guideline 301C)

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Endocrine disrupting properties

Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

12.7 Other adverse effects

No data available
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

No data available

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2051
Shipping Name
2-DIMETHYLAMINOETHANOL
Transport Class
8 (3)
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed

Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 2-(Dimethylamino)-ethanol for synthesis?

The signal word is danger.

What is the physical form of 2-(Dimethylamino)-ethanol for synthesis?

2-(Dimethylamino)-ethanol for synthesis is a liquid with clear, colorless color. It has amine-like odor.

What is 2-(Dimethylamino)-ethanol for synthesis used for?

Chemical for synthesis

What are the hazard statements for 2-(Dimethylamino)-ethanol for synthesis?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapor.
  • H302 + H312: Harmful if swallowed or in contact with skin.
  • H314: Causes severe skin burns and eye damage.
  • H331: Toxic if inhaled.
  • H335: May cause respiratory irritation.

What is the melting point of 2-(Dimethylamino)-ethanol for synthesis?

The melting point is -59 °C and the boiling point is 134,1 °C at ca.1.013 hPa.