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Safety Data Sheet EN

AMMONIUM BISULPHITE SOLUTION

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
AMMONIUM BISULPHITE SOLUTION

Regulatory Identifiers

CAS Number
N/A
UFI Code
GCUE-409D-V00K-S94X

Identified Uses

FOR INDUSTRIAL USE FOOD ADDITIVE REDUCING AGENT FOR PROFESSIONAL USE See attached exposure scenario.

Uses advised against

N.A.

Manufacturers & Suppliers

E

ESSECO S.r.l.

manufacturer

Via San Cassiano 99 28069 - Trecate (NO) Italy

+39-0321-7901

Emergency Contacts

Esseco

+39-0321-7901

Emergency Contact

112

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Eye Irrit. Cat. 2

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H319 Causes serious eye irritation.

Precautionary Statements

P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear eye/face protection: wear eye glasses with side protection.
P312 Call a doctor if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
AMMONIUM BISULPHITE EC: 233-469-7 10192-30-0 60 - 70% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove casualty to fresh air and keep warm and at rest.

Skin contact

Immediately take off all contaminated clothing. After contact with skin, wash immediately with soap and plenty of water.

Symptoms: persistent skin irritation

Eye contact

Irrigate eyes with copious amounts of water for at least 10-15 min, holding eyelids apart to ensure thorough rinsing. Protect uninjured eye.

Symptoms: irritation, blurred vision or swelling

Ingestion

Do not induce vomiting, get medical attention showing the SDS and label hazardous.

Immediate Medical Attention

In case of persistent skin irritation consult a doctor. Ask for medical advice. If irritation, blurred vision or swelling occurs and persists, obtain medical advice from a specialist. Get medical attention showing the SDS and label hazardous.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water. CO2 or Dry chemical fire extinguisher. Foaming. According to the materials involved in the fire.

Unsuitable media

None in particular.

Specific hazards

Produces oxides of sulphur and nitrogen on combustion

Instructions

Move undamaged containers from immediate hazard area if it can be done safely.

Firefighter Protection

Wear suitable protective clothing (helmet, protective clothings, goggles, fire resistant gloves, boots) and protect respiratory organs (self contained breathing apparatus).

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear personal protection equipment. Remove persons to safety. See protective measures under point 7 and 8.

Environmental

Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with skin and eyes, inhalation of vapours and mists. Don't use empty container before they have been cleaned. Before making transfer operations, assure that there aren't any incompatible material residuals in the containers.

Storage

Keep this product in a dry place. Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to sunlight. Adequately ventilated premises.

Hygiene

Contaminated clothing should be changed before entering eating areas. Do not eat or drink while working.

Fire prevention

Keep away from unguarded flame, sparks, and heat sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Wear suitable gloves tested to EN374. Suitable material: NBR (nitrile rubber) (Recommended thickness of the material: 0.4 mm; Permeation time: > 480 min). Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions.

Eyes

Safety goggles with side protection and protective shield. Technical reference standard: UNI EN 166

Respiratory

Depending on the potential for exposure, select respiratory protective equipment suitable for the specific conditions of use and in compliance with current legislation. Half-face mask with combined filter. Technical reference standard for filters to be used in the presence of gases and vapours: UNI EN 14387. Combined filter: B/K-P2 (grey-green-white colour). Filter mask FFP2/FFP3 for solid particles. Technical reference standard: UNI EN 149

Skin/Body

Wear chemical resistant clothing. Technical reference standard: UNI EN 13034. Wear chemical resistant safety shoes. Technical reference standard: UNI EN 20345

Environmental

Comply with the applicable environmental regulations limiting discharge to air, water and soil.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Yellow
Colour Intensity
---
Form
---
Odor
Pungent
Odor Threshold
(Data not available.)
Ph
4.5-5.5 (100%)
Melting Point
N.A.
Boiling Point
±105°C
Flash Point
N.A.
Freezing Point
N.A.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
N.A.
Vapor Pressure
Not Relevant
Vapor Density
Not Relevant
Relative Density
1.30-1.41 Kg/dm3
Bulk Density
---
Density
---
Flammability
N.A.
Upper Explosive Limit
N.A.
Lower Explosive Limit
N.A.
Explosive Limits
---
Auto Ignition Temperature
N.A.
Decomposition Temperature
N.A.
Solubility
---
Partition Coefficient
Not Relevant
Solubility In Water
0-100%
Solubility In Fat
N.A.
Molecular Weight
---
Voc Content
N.A.
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
N.A.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

Stable under normal conditions

Hazardous reactions

Stable under normal conditions.

Avoid

Keep away from heat and direct sunlight.

Incompatible

Acids, Oxidants.

Decomposition

Toxic gases, Sulphur dioxide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Adopt good working practices, so that the product is not released into the environment. Eco-Toxicological Information: **List of Eco-Toxicological properties of the product** CODE SHEET BAS2(1022)22

12.1. Toxicity

a) Aquatic acute toxicity : LC50 Fish O. mykiss = 149.5 mg/l 96h a) Aquatic acute toxicity : EC50 Daphnia cladoceran Daphnia magna = 74.9 mg/l 48h a) Aquatic acute toxicity : EC50 Algae Scenedesmus subspicatus = 36.8 mg/l 72h b) Aquatic chronic toxicity : NOEC Daphnia cladoceran Daphnia magna = 8.41 mg/l b) Aquatic chronic toxicity : NOEC Fish = 50 mg/l b) Aquatic chronic toxicity : NOEC Bacteria Pseudomonas putida = 634.4 mg/l

12.2. Persistence and degradability

| Component | Persistence/Degradability: | | --- | --- | | AMMONIUM BISULPHITE SOLUTION | Not persistent and Biodegradable |

12.3. Bioaccumulative potential

| Component | Bioaccumulation | | --- | --- |

12.3. Bioaccumulative potential

| Component | Bioaccumulation | | --- | --- | | AMMONIUM BISULPHITE SOLUTION | Not bioaccumulative |

12.4. Mobility in soil

| Component | Mobility in soil | | --- | --- | | AMMONIUM BISULPHITE SOLUTION | Not mobile |

12.5. Results of PBT and vPvB assessment

No PBT, vPvB or endocrine disruptor substances present in concentration >= 0.1%

No PBT, vPvB or endocrine disruptor substances present in concentration >= 0.1%

12.6. Endocrine disrupting properties

No endocrine disruptor substances present in concentration >= 0.1%

No endocrine disruptor substances present in concentration >= 0.1%

12.7. Other adverse effects

N.A.

N.A.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Recover if possible. In so doing, comply with the local and national regulations currently in force.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Regulation (EU) n. 2020/878, Regulation (EC) n. 1907/2006 (REACH), Regulation (EC) n. 1272/2008 (CLP), Dir. 98/24/EC

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for AMMONIUM BISULPHITE SOLUTION?

The signal word is warning.

What is the physical form of AMMONIUM BISULPHITE SOLUTION?

AMMONIUM BISULPHITE SOLUTION is a liquid with yellow color. It has pungent odor.

What is AMMONIUM BISULPHITE SOLUTION used for?

FOR INDUSTRIAL USE FOOD ADDITIVE REDUCING AGENT FOR PROFESSIONAL USE See attached exposure scenario.

What are the hazard statements for AMMONIUM BISULPHITE SOLUTION?

This substance has 1 hazard statement:

  • H319: Causes serious eye irritation.

What is the melting point of AMMONIUM BISULPHITE SOLUTION?

The melting point is N.A. and the boiling point is ±105°C.