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Safety Data Sheet EN

GLYCERINE 4827

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
GLYCERINE 4827
Product Form
Mixture

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Industrial use, Professional use wide dispersive use

Manufacturers & Suppliers

OLEON N.V. logo

OLEON N.V.

manufacturer

Assenedestraat 2, 9940 Ertvelde - Belgium

+32 9 341 10 11

http://www.oleon.com

Emergency Contacts

Emergency Contact

+32 3 575 55 55

24/7

Emergency Contact

+1 888 765 6554

24/7

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Glycerol EC: 200-289-5 56-81-5 86 - 88% No
Aqua EC: 231-791-2 7732-18-5 12 - 14% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.

Symptoms: Coughing. ON HEATING: Irritation of the respiratory tract. Irritation of the nasal mucous membranes.

Skin contact

Rinse with water. Soap may be used. Take victim to a doctor if irritation persists.

Eye contact

Rinse with water. Remove contact lenses, if present and easy to do. Continue rinsing. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists.

Symptoms: Slight irritation.

Ingestion

Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Call Poison Information Centre (www.who.int/ipcs/poisons/centre/directory/en). Consult a doctor/medical service if you feel unwell. Ingestion of large quantities: immediately to hospital.

Symptoms: Nausea. Vomiting. Diarrhoea. AFTER INGESTION OF HIGH QUANTITIES: Headache. Dehydration. Disturbances of heart rate. Change in the haemogramme/blood composition. Decreased renal function.

Immediate Medical Attention

Depending on the victim's condition: doctor/hospital. Ingestion of large quantities: immediately to hospital.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

AFFF foam. BC powder. Carbon dioxide. Dry sand. Dry chemical powder. Adapt extinguishing media to the environment.

Unsuitable media

Solid water jet ineffective as extinguishing medium.

Specific hazards

DIRECT FIRE HAZARD: Combustible. INDIRECT FIRE HAZARD: Temperature above flashpoint: higher fire/explosion hazard. No direct explosion hazard. Decomposes on exposure to temperature rise: release of toxic/corrosive/combustible gases/vapours (acrolein). May polymerize on exposure to temperature rise. Reacts violently with (strong) oxidizers: (increased) risk of fire/explosion. Reacts with (some) acids: (increased) risk of fire/explosion.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Mark the danger area. Exposure to heat: have neighbourhood close doors and windows. Exposure to fire/heat: consider evacuation. Wash contaminated clothes.

Environmental

Prevent soil and water pollution.

Cleanup methods

Clean contaminated surfaces with an excess of water. Take up liquid spill into inert absorbent material

Materials: dry sand/earth/vermiculite or powdered limestone

—

Related Products

Similar products with comparable safety profiles

G

GLYCERINE 4823

---

G

GLYCERINE 4843

---

G

GLYCERINE 4819

CAS: 56-81-5

G

GLYCERINE 4827K

---

G

GLYCERINE 4812

CAS: 56-81-5

G

GLYCERINE 4807

CAS: 56-81-5

G

GLYCERINE 4818

CAS: 56-81-5

G

GLYCERINE 4816

CAS: 56-81-5

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handling temperature: ≥ 10 °C above melting point

Storage

Store at ambient temperature. Keep out of direct sunlight. Meet the legal requirements.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Gloves. Materials for protective clothing: GIVE GOOD RESISTANCE: natural rubber. neoprene. PVC. viton. GIVE LESS RESISTANCE: styrene-butadiene rubber. GIVE POOR RESISTANCE: polyurethane

Eyes

Safety glasses

Respiratory

Mist formation: aerosol mask with filter type P1. On heating: gas mask with filter type A.

Skin/Body

Protective clothing

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid.
Colour
Colourless to light yellow.
Colour Intensity
---
Form
---
Odor
---
Odor Threshold
---
Ph
5 - 8
Melting Point
< 0 °C
Boiling Point
> 120 °C
Flash Point
> 120 °C
Freezing Point
No data available
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
< 0,1 hPa (20°C)
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
ca. 1,23 g/cm³ (20°C)
Flammability
No data available
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
> 150 °C
Decomposition Temperature
290 °C (glycerol)
Solubility
Water: 100 g/100ml (25 °C, complete)
Partition Coefficient
Log Pow : -1,75 (Experimental value, Equivalent or similar to OECD 107, 25 °C)
Solubility In Water
Soluble in water
Solubility In Fat
Insoluble in oils/fats
Molecular Weight
---
Voc Content
< 1 % (1999/13/EC; 2004/42/EC; 2010/75/EU; SR 814.018)
Metal Corrosion
---
Dynamic Viscosity
ca. 150 mPa·s (20°C)
Kinematic Viscosity
ca. 121,951 mm²/s
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Hygroscopic.

Reactivity

Reacts violently with (strong) oxidizers: (increased) risk of fire/explosion. Reacts with (some) acids: (increased) risk of fire/explosion.

Hazardous reactions

May polymerize on exposure to temperature rise.

Avoid

temperature rise

Incompatible

(strong) oxidizers, (some) acids

Decomposition

toxic/corrosive/combustible gases/vapours (acrolein). Upon combustion CO and CO2 are formed.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

Ecology - general : No supplementary information available. Ecology - air : TA-Luft Klasse 5.2.5. Ecology - water : Mild water pollutant (surface water) Not harmful to fishes (LC50(96h) >1000 mg/l) Not harmful to aquatic organisms (EC50 >1000 mg/l) Not harmful to algae Not harmful to bacteria Bioaccumulation: not applicable Sludge digestion is inhibited at >1000 mg/l 50% Readily biodegradable in water (OECD 301D: 82%; 20 days) Acute aquatic toxicity : Not classified Chronic aquatic toxicity : Not classified

The substance is considered a mild water pollutant but is not classified as harmful to fish, aquatic organisms, algae, or bacteria.

12.2 Persistence and degradability

Readily biodegradable in water (OECD 301D: 82%; 20 days)

12.3 Bioaccumulative potential

Bioaccumulation: not applicable

12.1. Toxicity

LC50 fish 1: 54000 mg/l (96 h, SALMO GAIRDNERI/ ONCORHYNCHUS MYKISS) LC50 fish 2: > 1000 mg/l (96 h, PISCES) LC50 other aquatic organisms 1: > 1000 mg/l (96 h) EC50 Daphnia 2: > 10000 mg/l (24 h, DAPHNIA MAGNA, LOCOMOTOR EFFECT) EC50 other aquatic organisms 1: > 1000 mg/l (BACTERIA, ACTIVATED SLUDGE) TLM fish 1: > 1000 ppm (96 h, PISCES) TLM other aquatic organisms 1: > 1000 ppm (96 h) Threshold limit other aquatic organisms 1: 2900 mg/l (192 h, MICROCYSTIS AERUGINOSA, TOXICITY TEST) Threshold limit other aquatic organisms 2: > 10000 mg/l (16 h, PSEUDOMONAS PUTIDA, TOXICITY TEST) Threshold limit algae 1: > 10000 mg/l (168 h, SCENEDESMUS QUADRICAUDA, TOXICITY TEST)

12.1. Toxicity

| LC50 fish 1 | 54000 mg/l (96 h, SALMO GAIRDNERI/ ONCORHYNCHUS MYKISS) | | LC50 fish 2 | > 1000 mg/l (96 h, PISCES) | | LC50 other aquatic organisms 1 | > 1000 mg/l (96 h) | | EC50 Daphnia 2 | > 10000 mg/l (24 h, DAPHNIA MAGNA, LOCOMOTOR EFFECT) | | EC50 other aquatic organisms 1 | > 1000 mg/l (BACTERIA, ACTIVATED SLUDGE) | | TLM fish 1 | > 1000 ppm (96 h, PISCES) | | TLM other aquatic organisms 1 | > 1000 ppm (96 h) | | Threshold limit other aquatic organisms 1 | 2900 mg/l (192 h, MICROCYSTIS AERUGINOSA, TOXICITY TEST) | | Threshold limit other aquatic organisms 2 | > 10000 mg/l (16 h, PSEUDOMONAS PUTIDA, TOXICITY TEST) | | Threshold limit algae 1 | > 10000 mg/l (168 h, SCENEDESMUS QUADRICAUDA, TOXICITY TEST) |

12.2. Persistence and degradability

| Biochemical oxygen demand (BOD) | 0,87 g O2/g substance | | --- | --- | | Chemical oxygen demand (COD) | 1,16 g O2/g substance (ISO 15705) | | ThOD | 1,217 g O2/g substance | | BOD (% of ThOD) | 71 % ThOD |

12.2. Persistence and degradability

| Biochemical oxygen demand (BOD) | 0,87 g O2/g substance | | --- | --- | | Chemical oxygen demand (COD) | 1,16 g O2/g substance (ISO 15705) | | ThOD | 1,217 g O2/g substance | | BOD (% of ThOD) | 71 % ThOD |

12.3. Bioaccumulative potential

| Log Pow | -1,75 (Experimental value, Equivalent or similar to OECD 107, 25 °C) |

12.3. Bioaccumulative potential

| Log Pow | -1,75 (Experimental value, Equivalent or similar to OECD 107, 25 °C) |

12.4. Mobility in soil

GLYCERINE 4827 | Surface tension | 0,063 N/m (20°C) | | --- | --- | | Ecology - soil | Biodegradability in soil: no data available. | Glycerol (56-81-5) | Surface tension | 0,063 N/m (20°C) | | --- | --- | | Ecology - soil | Biodegradability in soil: no data available. | Aqua (7732-18-5) | Mobility in soil | Not applicable | | --- | --- |

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Recycle by distillation. Remove to an authorized incinerator equipped with an afterburner and a flue gas scrubber.

Disposal

Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite, or kieselguhr, powdered limestone. Scoop absorbed substance into closing containers. Wash down leftovers with plenty of water.

Waste Codes

KGA category 03 LWCA (the Netherlands) national code
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for GLYCERINE 4827?

The signal word is no signal word.

What is the physical form of GLYCERINE 4827?

GLYCERINE 4827 is a liquid appearing as liquid. with colourless to light yellow. color.

What is the solubility of GLYCERINE 4827?

Water: 100 g/100ml (25 °C, complete)

What is GLYCERINE 4827 used for?

Industrial use, Professional use wide dispersive use

What is the melting point of GLYCERINE 4827?

The melting point is < 0 °C and the boiling point is > 120 °C.