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Safety Data Sheet EN

Epichlorohydrin

CAS 106-89-8
EC 203-439-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Epichlorohydrin
Chemical Name
Epichlorohydrin
Synonyms
1-chloro-2, 3-epoxypropane, 3-Chloro-1, 2-Epoxypropane

Regulatory Identifiers

CAS Number
106-89-8 Check regulations →
EC Number
203-439-8 Check regulations →
REACH No.
01-2119457436-33-0108

Identified Uses

Chemical production, industrial applications.

Uses advised against

Not applicable

Manufacturers & Suppliers

Epigral Limited logo

Epigral Limited

manufacturer

CH/1 and CH/2, GIDC Industrial Estate, Dahej, Tal. Vagra, Dist. Bharuch - 392130, Gujarat (India).

+91 635 9953661/62/63/64/65

https://www.epigral.com

Emergency Contacts

Emergency Contact

+91 635 9953661/62/63/64/65

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 3 H301
Acute Tox. Cat. 3 H311
Acute Tox. Cat. 3 H331
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317
Carc. Cat. 1B H350
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapors.
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H350 May cause cancer.
H412 Harmful to aquatic life.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling the treated area.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P301 + P310 If swallowed: Immediately call a poison center or doctor/physician.
P301 + P330 + P331 If swallowed: Rinse mouth. Do not induce vomiting.
P302 + P352 If on skin: Wash with plenty of soap and water.
P304 + P340 If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308 + P313 If exposed or concerned: Get medical advice/ attention.
P312 Call a poison center or doctor/physician if you feel unwell.
P321 Specific treatment (see information on this label).
P322 Specific measures (see information on this label).
P330 Rinse mouth.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P361 Remove/Take off immediately all contaminated clothing.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use the fire extinguishing agent for extinction.
P405 Store locked up.
If on skin (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store in a cool & well-ventilated place. Keep container tightly closed.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
1-chloro-2,3-epoxypropane EC: 203-439-8 106-89-8 99.9% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Get immediate medical advice/attention. If exposed to excessive levels of dusts or fumes remove to fresh air and get medical attention if cough or other symptoms develop.

Symptoms: Cough or other symptoms.

Skin contact

Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Get immediate medical advice/attention. Remove and isolate contaminated clothing and shoes. For minor skin contact, avoid spreading material on unaffected skin. In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. Wash skin with soap and water.

Symptoms: Skin irritation or rash.

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention.

Symptoms: May cause severe eye damage.

Ingestion

If swallowed: Immediately call a poison center or doctor/physician. If swallowed: Rinse mouth. Do not induce vomiting. Do not use mouth-to-mouth methods if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.

Immediate Medical Attention

Get immediate medical advice/attention.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, dry chemical, water spray, alcohol-resistant foam.

Unsuitable media

Water. Do not use water jet as extinguisher, as this will spread the fire.

Specific hazards

Flammable liquid and vapor. May violently polymerize and result in fire and explosion. Vapors may travel to a source of ignition and ignite. Material may produce irritating and highly toxic gases from decomposition by heat and combustion during burning. May form explosive mixtures at temperatures at or above the flashpoint. Containers may explode when heated. Highly flammable: Will be easily ignited by heat, sparks or flames. Spilled material may create fire or explosion hazard.

Instructions

Move containers from fire area if you can do it without risk. Fire involving Tanks; Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Fire involving Tanks; cool containers with flooding quantities of water until well after fire is out. Fire involving Tanks; Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. Fire involving Tanks; always stay away from tanks engulfed in fire. Fire involving Tanks; for massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire bur

Firefighter Protection

Rescuers should put on appropriate protective gear. Evacuate area and fight fire from a safe distance.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid breathing dust/fume/gas/mist/vapors/spray. Clean up spills immediately, observing precautions in Protective Equipment section. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Stop leak if you can do it without risk. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

Small spill

Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Large spill

Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain.

Environmental

Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Obtain special instruction before use. Do not handle until all safety precautions have been read and understood. Wear appropriate personnel protective equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling the treated area. Do not breathe, eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. Follow all SDS/label precautions even after container is emptied because they may retain product residues. Loosen closure cautiously before opening. Avoid prolonged or repeated contact with skin. Do not get in eyes, do not taste or swallow. Be careful to heat. Pregnant or breastfeeding woman must not handle this product.

Storage

Protect material from direct sunlight exposure.

Hygiene

Wash thoroughly after handling the treated area. Do not breathe, eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace.

Fire prevention

Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. All equipment used when handling the product must be grounded. Do not expose such containers to heat, flame, sparks, static electricity, or other sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. If user operations generate dust, fume, or mist, use ventilation to keep exposure to airborne contaminants below the recommended exposure limit. Facilities for storing or utilizing this material should be equipped with an eyewash facility and a safety shower.

Hands

Wear appropriate chemical resistant protective gloves by considering physical and chemical properties of Chemicals.

Eyes

Wear chemical splash goggle. An eye wash unit and safely shower station should be available nearby work place.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134. Use a NIOSH / MSHA approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Skin/Body

Wear appropriate chemical resistant protective clothing by considering physical and chemical properties of chemicals.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid
Colour
Colourless
Colour Intensity
---
Form
---
Odor
Pungent
Odor Threshold
Not available
Ph
Not Available
Melting Point
-57°C
Boiling Point
116-117°C(1atm)
Flash Point
28 °C closed cup, 40 °C Open cup
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not Available
Vapor Pressure
22.7hP at 25°C
Vapor Density
3.29
Relative Density
1.18 @ 25 °C
Bulk Density
---
Density
---
Flammability
Not Applicable
Upper Explosive Limit
21%
Lower Explosive Limit
3.8%
Explosive Limits
---
Auto Ignition Temperature
385°C
Decomposition Temperature
---
Solubility
---
Partition Coefficient
n-octanol/water:0.45
Solubility In Water
70 gm/ltr
Solubility In Fat
---
Molecular Weight
92.53 g/mol
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
1.03 mPa.s @ 25 °C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

May form explosive mixtures at temperatures at or above the flashpoint. May cause vapor explosion hazard indoors, outdoors or in sewers. Some of these materials may burn, but none ignite readily. Vapors may form explosive mixtures with air.

Avoid

Avoid contact with the temperature more than 325°C.

Incompatible

Acid, alcohol, phenol, organic acids, metal salts, amine, combustible materials, bases, oxidizing agents, halo carbons, aluminum, ammonia, magnesium, zinc, sodium.

Decomposition

May decompose at high temperatures into forming toxic gases.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Eco-toxicity:

LC50 Daphnia Magna: 15 mg/l, 72 hours

12.2 Persistence and degradability:

Photolysis Half-Life (Photolysis-Atmospheric) 36.5 days direct photolysis Hydrolysis Half-Life (Hydrolysis-Acidic) 7.3 d 20deg.C(68deg.F), pH4.0 Half-Life (Hydrolysis-Basic) 6.8 d 20deg.C(68deg.F), pH9.0 Half-Life (Hydrolysis-Neutral) 3.9 d 20deg.C(68deg.F), pH7.0

12.3 Bio-accumulative potential:

Aquatic toxicity Harmful to aquatic organisms.

12.4 Mobility in soil:

No data available

12.5 Results of PBT and vPvB assessment

Product does not contain any substance meeting the criteria for PBT or vPvB in accordance with the Annex XIII of Regulation (EC) No 1907/2006 (REACH) as amended.

12.5 Endocrine disrupting properties

This substance does not have endocrine disrupting properties with respect to non-target organisms as it does not meet the criteria set out in section B of Regulation (EU) No 2017/2100.

12.6 Other adverse effects

Not available

12.7 Toxicity to fish

LC50 - Pimephales promelas (fathead minnow) - 10.6 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates LC50 - Daphnia magna (Water flea) - 21 mg/l - 48 h

12.5 Results of PBT and vPvB assessment

Product does not contain any substance meeting the criteria for PBT or vPvB in accordance with the Annex XIII of Regulation (EC) No 1907/2006 (REACH) as amended.

The product does not contain any substances meeting the criteria for PBT or vPvB in accordance with Annex XIII of REACH.

12.5 Endocrine disrupting properties

This substance does not have endocrine disrupting properties with respect to non-target organisms as it does not meet the criteria set out in section B of Regulation (EU) No 2017/2100.

The substance does not have endocrine disrupting properties as it does not meet the criteria set out in section B of Regulation (EU) No 2017/2100.

12.7 Toxicity to fish

LC50 - Pimephales promelas (fathead minnow) - 10.6 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates LC50 - Daphnia magna (Water flea) - 21 mg/l - 48 h

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

12.6 Other adverse effects

Not available

Other adverse effects

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Harmful to aquatic life
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2023
Shipping Name
EPICHLOROHYDRIN
Transport Class
6.1 (3)
Packing Group
II
IMDG

in case of fire : F-E, in case of leakage: S-D

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Epichlorohydrin known by?

Epichlorohydrin is also known as: 1-chloro-2, 3-epoxypropane, 3-Chloro-1, 2-Epoxypropane

What is the hazard signal word for Epichlorohydrin?

The signal word is danger.

What is the physical form of Epichlorohydrin?

Epichlorohydrin is a liquid appearing as liquid with colourless color. It has pungent odor.

What is Epichlorohydrin used for?

Chemical production, industrial applications.

What are the hazard statements for Epichlorohydrin?

This substance has 7 hazard statements:

  • H226: Flammable liquid and vapors.
  • H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H318: Causes serious eye damage.
  • H350: May cause cancer.
  • H412: Harmful to aquatic life.

What is the melting point of Epichlorohydrin?

The melting point is -57°C and the boiling point is 116-117°C(1atm).