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Safety Data Sheet EN

LUBRIZOL® 6499

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LUBRIZOL® 6499

Regulatory Identifiers

CAS Number
N/A
UFI Code
EHWR-U056-8007-A0CW

Identified Uses

Marine Diesel Engine

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX, 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Repr. Cat. 1B H360F
Aquatic Chronic Cat. 4 H413

GHS Pictograms

GHS08 - Serious health hazard

GHS08

Hazard Statements

H360F May damage fertility.
H413 May cause long lasting harmful effects to aquatic life.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Calcium branched alkyl phenate sulphide (overbased) --- 50 - 100% Yes
Mineral oil --- 20 - 50% Yes
Phenol, dodecyl-, branched EC: 310-154-3 --- 1 - 2.5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Wash with soap and water. Launder contaminated clothing before reuse.

Eye contact

Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses.

Ingestion

Treat symptomatically.

Immediate Medical Attention

Get medical attention if symptoms occur (Skin Contact). Get medical attention (Ingestion).

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Not determined.

Specific hazards

No unusual fire or explosion hazards noted.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Personal Protective Equipment must be worn, see Personal Protection Section for PPE recommendations.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use personal protective equipment as required. In case of spills, beware of slippery floors and surfaces.

Storage

Store away from incompatible materials. See section 10 for incompatible materials.

Hygiene

Observe good industrial hygiene practices. Launder contaminated clothing before reuse.

Fire prevention

Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Chemical resistant gloves. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For applications involving mechanical risks with potential for abrasion or puncture, the standards set out in EN 388 should be considered. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm.

Eyes

If contact is likely, safety glasses with side shields are recommended. Eye protection should meet the standards set out in EN 166.

Respiratory

Use self-contained breathing apparatus (SCBA) for entry into a confined space as the natural decomposition of this material will lower the available oxygen in the air. In case of insufficient ventilation, wear suitable respiratory equipment. The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment.

Skin/Body

Gloves, coveralls, apron, boots as necessary to minimize contact.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Dark
Colour
Dark
Colour Intensity
---
Form
liquid
Odor
Strong
Odor Threshold
No data available.
Ph
No data available.
Melting Point
---
Boiling Point
No data available.
Flash Point
> 165 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
No data available.
Vapor Density
---
Relative Density
1.09 (15.6 °C)
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
No data available.
Lower Explosive Limit
No data available.
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
11.08 (Measured)
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
No data available.
Metal Corrosion
---
Dynamic Viscosity
63,972.6 cP (20 °C); 50 cP (134.3 °C)
Kinematic Viscosity
7500 mm2/s (40 °C); 32623 mm2/s (25 °C) 170 mm2/s (100 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Do not expose to excessive heat, ignition sources

Incompatible

oxidizing materials

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, sulfur oxides, mercaptans, sulfides, including hydrogen sulfide and other products of incomplete combustion.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity

Product: LC 50 (Fathead Minnow, 4 d): > 1,000 mg/l

12.1 Ecotoxicity

Calcium branched alkyl phenate sulphide (overbased) LC 50 (Fathead Minnow, 4 d): > 1,000 mg/l

12.1 Ecotoxicity

Mineral oil LC 50 (Fathead Minnow, 4 d): > 100 mg/l

12.1 Ecotoxicity

Fish Phenol, dodecyl-, branched LC 50 (Fathead Minnow, 4 d): 40 mg/l

12.1 Toxicity

EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Calcium branched alkyl phenate sulphide (overbased) EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Mineral oil EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Phenol, dodecyl-, branched EC 50 (Water flea (Daphnia magna), 2 d): 0.037 mg/l EC 50 (Shrimp (Mysidopsis Bahia), 4 d): > 0.58 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0.0079 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.0037 mg/l

12.1 Toxicity

Toxicity to Aquatic Plants Product: EC 50 (Green algae (Selenastrum capricornutum), 96 h): > 1,000 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Calcium branched alkyl phenate sulphide (overbased) EC 50 (Green algae (Selenastrum capricornutum), 96 h): > 1,000 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Mineral oil EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Phenol, dodecyl-, branched EC 50 (Green algae (Scenedesmus quadricauda), 72 h): 0.36 mg/l

12.1 Toxicity

Toxicity to soil dwelling organisms No data available Sediment Toxicity No data available Toxicity to Terrestrial Plants No data available Toxicity to Above-Ground Organisms No data available Toxicity to microorganisms Product: EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.1 Ecotoxicity

Toxicity to microorganisms Calcium branched alkyl phenate sulphide (overbased) EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.1 Ecotoxicity

Toxicity to microorganisms Phenol, dodecyl-, branched EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.2 Persistence and Degradability

Biodegradation Product: OECD TG 301 B, 4.7 - 10.8 %, 28 d, Not readily degradable. Inherent Sludge, 38.8 %, 28 d

12.2 Persistence and Degradability

Biodegradation Calcium branched alkyl phenate sulphide (overbased) OECD TG 301 B, 4.7 - 10.8 %, 28 d, Not readily degradable. Inherent Sludge, 38.8 %, 28 d

12.2 Persistence and Degradability

Biodegradation Mineral oil OECD TG 301 B, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Phenol, dodecyl-, branched Miscellaneous, 10 %, 56 d, Not readily degradable. OECD TG 301 B, 25 %, 28 d, Not readily degradable.

Persistence and degradability

BOD/COD Ratio: No data available

12.3 Bioaccumulative potential Bioconcentration Factor (BCF)

Product: Bioconcentration Factor (BCF): 3.2 - 656

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF): 2.2

12.3 Bioaccumulative potential Bioconcentration Factor (BCF)

Phenol, dodecyl-, branched Bioconcentration Factor (BCF): 794.33 (Measured)

12.3 Bioaccumulative potential

Calcium branched alkyl phenate sulphide (overbased) Log Kow: 11.08 (Measured)

12.3 Bioaccumulative potential

Phenol, dodecyl-, branched Log Kow: 7.14 (Measured)

12.4 Mobility:

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Endocrine Disruption:

Product: No data available.

No data available.

12.7 Other adverse effects

Product: This material contains one or more components that have an impurity (alkylated phenol) that is highly toxic to aquatic organisms (Aquatic Acute 1 and Aquatic Chronic 1). The component containing the impurity (calcium phenate) was tested in fish, invertebrates and algae and the results showed that it may cause long lasting harmful effects to aquatic life (Aquatic Chronic 4). Therefore the classification shown in Section 3 for the alkylphenol impurity should not be used to classify the product for aquatic toxicity. Calcium branched alkyl phenate sulphide (overbased) This material contains one or more components that have an impurity (alkylated phenol) that is highly toxic to aquatic organisms (Aquatic Acute 1 and Aquatic Chronic 1). The component containing the impurity (calcium phenate) was tested in fish, invertebrates and algae and the results showed that it may cause long lasting harmful effects to aquatic life (Aquatic Chronic 4). Therefore the classification shown in Section 3 for the alkylphenol impurity should not be used to classify the product for aquatic toxicity.

The material contains an alkylated phenol impurity that is highly toxic to aquatic organisms, but the component (calcium phenate) itself is classified as Aquatic Chronic 4, so the impurity's classification should not be used for the product.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of packaging or containers in accordance with local, regional, national and international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LUBRIZOL® 6499?

The signal word is danger.

What is the physical form of LUBRIZOL® 6499?

LUBRIZOL® 6499 is a liquid appearing as dark with dark color. It has strong odor.

What is LUBRIZOL® 6499 used for?

Marine Diesel Engine

What are the hazard statements for LUBRIZOL® 6499?

This substance has 2 hazard statements:

  • H360F: May damage fertility.
  • H413: May cause long lasting harmful effects to aquatic life.