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Safety Data Sheet EN

Intergard 821 Part B

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Intergard 821 Part B
Product Code
EAA821

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Professional application of coatings and inks

Uses advised against

All Other Uses

Manufacturers & Suppliers

I

International Paint Ltd.

manufacturer

Stoneygate Lane, Felling, Gateshead, Tyne and Wear, NE10 0JY UK

+44 (0)191 469 6111

Emergency Contacts

Emergency Contact

+44 (0)191 469 6111

24H

National advisory body/ Poison Centre

+966 55 388 0087

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4
Skin Corr. Cat. 1B
Skin Sens. Cat. 1
Repr. Cat. 1B
Repr. Cat. 2
Aquatic Acute Cat. 1
Aquatic Chronic Cat. 1

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H360F May damage fertility.
H361d Suspected of damaging the unborn child.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves.
P281 Wear protective clothing.
P282 Wear eye or face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or physician.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention.
P310 Immediately call a POISON CENTER or physician.
P310 Immediately call a POISON CENTER or physician.
P310 Immediately call a POISON CENTER or physician.
P330 Rinse mouth.
P331 Do NOT induce vomiting.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
benzyl alcohol 100-51-6 10 - 25% Yes
2-piperazin-1-ylethylamine 140-31-8 10% Yes
m-phenylenebis(methylamine) 1477-55-0 5% Yes
bisphenol A 80-05-7 3% Yes
4-nonylphenol, branched 84852-15-3 3% Yes
3,6,9-triazaundecamethylenediamine 112-57-2 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: May give off gas, vapour or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Adverse symptoms may include the following: reduced foetal weight, increase in foetal deaths, skeletal malformations.

Skin contact

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: Causes severe burns. May cause an allergic skin reaction. Adverse symptoms may include the following: pain or irritation, redness, blistering may occur, reduced foetal weight, increase in foetal deaths, skeletal malformations.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician.

Symptoms: Causes serious eye damage. Adverse symptoms may include the following: pain, watering, redness.

Ingestion

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Harmful if swallowed. May cause burns to mouth, throat and stomach. Adverse symptoms may include the following: stomach pains, reduced foetal weight, increase in foetal deaths, skeletal malformations.

Immediate Medical Attention

Get medical attention immediately. Call a poison center or physician.

Medical Treatment

Chemical burns must be treated promptly by a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use an extinguishing agent suitable for the surrounding fire.

Unsuitable media

None known.

Specific hazards

This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Provide adequate ventilation.

Small spill

Move containers from spill area. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.

Large spill

Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid release to the environment. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Solid
Colour
Grey
Colour Intensity
---
Form
---
Odor
Amine-like
Odor Threshold
Not available
Ph
Not applicable
Melting Point
Not available
Boiling Point
Not available
Flash Point
Closed cup: 65°C (149°F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available
Vapor Pressure
Not available
Vapor Density
Not available
Relative Density
0.8
Bulk Density
---
Density
---
Flammability
Not available
Upper Explosive Limit
Not available
Lower Explosive Limit
Not available
Explosive Limits
---
Auto Ignition Temperature
Not available
Decomposition Temperature
Not available
Solubility
Not available
Partition Coefficient
Not available
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Kinematic (room temperature): 10000 mm²/s (10000 cSt)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

No specific data.

Incompatible

No specific data.

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

96 hours Fish - Pimephales promelas Acute LC50 2190000 to 2460000 μg/l Fresh water

12.2 Persistence and degradability

Not available.

12.3 Bioaccumulative potential

Not available.

12.4 Mobility in soil

Not available.

12.5 Results of PBT and vPvB assessment

Not available.

12.6 Endocrine disrupting properties

Not available.

12.7 Other adverse effects

Not available.

12.1 Toxicity

|Exposure|Species|Result|Product/ingredient name| |---|---|---|---| |72 hours|Algae - Prorocentrum minimum - Exponential growth phase|Acute EC50 1.506 mg/l|bisphenol A| |48 hours|Daphnia - Daphnia magna - Young|Acute EC50 9940 μg/l Fresh water|| |48 hours|Crustaceans - Tigriopus japonicus - Adult|Acute LC50 4.32 mg/l Marine water|| |96 hours|Fish - Rivulus marmoratus - Embryo|Acute LC50 3.5 mg/l Marine water|| |4 days|Algae - Chlorolobion braunii - Exponential growth phase|Chronic NOEC 2 mg/l Fresh water|| |21 days|Crustaceans - Tigriopus japonicus - Nauplii|Chronic NOEC 10 μg/l Marine water|| |21 days|Daphnia - Daphnia magna - Neonate|Chronic NOEC 0.86 mg/l Fresh water|| |90 days|Fish - Carassius auratus - Adult|Chronic NOEC 0.2 μg/l Fresh water||

12.1 Toxicity

Exposure: 72 hours, 96 hours; Species: Algae - Skeletonema costatum, Algae - Skeletonema costatum; Result: Acute EC50 0.03 mg/l Marine water, Acute EC50 0.027 mg/l Marine water; Product/ingredient name: 4-nonylphenol, branched. Exposure: 48 hours; Species: Crustaceans - Americamysis bahia - Juvenile (Fledgling, Hatchling, Weanling); Result: Acute LC50 0.047 mg/l Marine water. Exposure: 96 hours; Species: Fish - Pleuronectes americanus - Larvae; Result: Acute LC50 17 μg/l Marine water. Exposure: 96 hours; Species: Algae - Skeletonema costatum; Result: Chronic EC10 0.012 mg/l Marine water. Exposure: 33 days; Species: Fish - Pimephales promelas - Embryo; Result: Chronic NOEC 7.4 μg/l Fresh water.

12.3 Bioaccumulative potential

Potential: low, BCF: -, LogPow: 0.87, Product/ingredient name: benzyl alcohol

12.3 Bioaccumulative potential

Potential: low, BCF: -, LogPow: -1.48, 0.18

12.3 Bioaccumulative potential

Potential: low, BCF: 2.691534803, LogPow: 0.18

12.1 Toxicity

Not available

12.2 Persistence and degradability

Not available

12.3 Bioaccumulative potential

Product/ingredient name: bisphenol A, BCF: 43.651583224, LogPow: 3.4, Potential: low

12.4 Mobility in soil

Not available

12.5 Results of PBT and vPvB assessment

Not available

12.6 Endocrine disrupting properties

Not available

12.7 Other adverse effects

Not available

12.3 Bioaccumulative potential

Potential: low, BCF: 251.18864315, LogPow: 5.4

Mobility in soil

Not available. - : Soil/water partition coefficient (KOC)

Other adverse effects

No known significant effects or critical hazards.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1759
Shipping Name
CORROSIVE SOLID, N.O.S. (2-piperazin-1-ylethylamine, m-phenylenebis(methylamine))
Transport Class
8
Packing Group
III
IMDG

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

No known specific national and/or regional regulations applicable to this product (including its ingredients).

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Intergard 821 Part B?

The signal word is danger.

What is the physical form of Intergard 821 Part B?

Intergard 821 Part B is a solid appearing as solid with grey color. It has amine-like odor.

What is the solubility of Intergard 821 Part B?

Not available

What is Intergard 821 Part B used for?

Professional application of coatings and inks

What are the hazard statements for Intergard 821 Part B?

This substance has 6 hazard statements:

  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H360F: May damage fertility.
  • H361d: Suspected of damaging the unborn child.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of Intergard 821 Part B?

The melting point is Not available and the boiling point is Not available.