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Safety Data Sheet EN

MOLYKOTE® G-Rapid Plus Paste Spray

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
MOLYKOTE® G-Rapid Plus Paste Spray

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Lubricants and lubricant additives

Manufacturers & Suppliers

S

SPECIALTY ELECTRONIC MATERIALS UK LIMITED

manufacturer

KINGS COURT, LONDON ROAD STEVENAGE England SG1 2NG UNITED KINGDOM

00800-3876-6838

D

DuPont Specialty Products GmbH & Co. KG

manufacturer

Emergency Contacts

Emergency Contact

+(44)-2038850382

Emergency Contact

+(44)-2038850382

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Aerosol Cat. 1 H222
Eye Dam. Cat. 1 H318
STOT SE Cat. 3 H336
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
H318 Causes serious eye damage.
H336 May cause drowsiness or dizziness.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P261 Avoid breathing spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear eye protection/ face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/ doctor.
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
propane EC: 200-827-9 74-98-6 1 - 10% Yes
butane EC: 203-448-7 106-97-8 30 - 40% Yes
Molybdenum disulfide EC: 215-263-9 1317-33-5 1 - 10% No
Graphite EC: 231-955-3 7782-42-5 1 - 10% No
Calcium hydroxide EC: 215-137-3 1305-62-0 3 - 10% Yes
Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% aromatics --- 25 - 30% Yes
White mineral oil (petroleum) (viscosity < 20.5 cSt @ 40C) EC: 232-455-8 8042-47-5 10 - 20% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move person to fresh air; if effects occur, consult a physician.

Skin contact

Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. In the case of skin irritation or allergic reactions see a physician.

Eye contact

Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist.

Ingestion

Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Seek medical attention immediately. Consult a physician if necessary.

Immediate Medical Attention

Seek medical attention if irritation persists. Obtain medical attention without delay, preferably from an ophthalmologist. Seek medical attention immediately.

Medical Treatment

Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, Alcohol-resistant foam, Carbon dioxide (CO2), Dry chemical

Unsuitable media

Do not use direct water stream.

Specific hazards

Flash back possible over considerable distance. May form explosive mixtures in air. Exposure to combustion products may be a hazard to health. If the temperature rises there is danger of the vessels bursting due to the high vapor pressure. Vapours may form explosive mixtures with air.

Instructions

Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Fight advanced fires from a protected location. Fight fire remotely due to the risk of explosion. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so.

Firefighter Protection

In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Follow safe handling advice and personal protective equipment recommendations.

Large spill

For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.

Environmental

Do not release the product to the aquatic environment above defined regulatory levels. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water.

Cleanup methods

Soak up with inert absorbent material. Clean up remaining materials from spill with suitable absorbant.

Materials: inert absorbent material, suitable absorbant

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not get on skin or clothing. Do not breathe vapours or spray mist. Do not swallow. Do not get in eyes. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Close valve after each use and when empty. Do NOT change or force fit connections. Open the valves slowly to prevent pressure surges. Handle in accordance with good industrial hygiene and safety practice. Do not spray on an open flame or other ignition source.

Storage

Store locked up. Keep tightly closed. Keep in a cool, well-ventilated place. Keep away from direct sunlight. Store in accordance with the particular national regulations. Do not pierce or burn, even after use. Keep cool. Protect from sunlight.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Use good personal hygiene. Do not consume or store food in the work area. Wash hands before smoking or eating. Ensure that eye flushing systems and safety showers are located close to the working place.

Fire prevention

Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Do not spray on an open flame or other ignition source.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use engineering controls to maintain airborne level below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use only in enclosed systems or with local exhaust ventilation. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. Lethal concentrations may exist in areas with poor ventilation.

Hands

Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Chlorinated polyethylene. Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Polyvinyl alcohol ("PVA"). Viton. Examples of acceptable glove barrier materials include: Butyl rubber. Natural rubber ("latex"). Polyvinyl chloride ("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Eyes

Use chemical goggles.

Respiratory

Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use an approved respirator. When respiratory protection is required, use an approved positive-pressure self-contained breathing apparatus or positive-pressure airline with auxiliary selfcontained air supply. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. In confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive pressure air line with auxiliary self-contained air supply.

Skin/Body

Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.

Environmental

See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
aerosol
Physical State Data
aerosol
State Under Standard Conditions
---
Appearance
---
Colour
black
Colour Intensity
---
Form
Aerosol containing a dissolved gas
Odor
solvent-like
Odor Threshold
No data available
Ph
Substance/mixture is non-soluble (in water).
Melting Point
Melting point/ range: No data available
Boiling Point
Boiling point/boiling range: Not applicable
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable
Vapor Pressure
No data available
Vapor Density
---
Relative Density
0.74
Bulk Density
---
Density
---
Flammability
Extremely flammable aerosol.
Upper Explosive Limit
No data available
Lower Explosive Limit
No data available
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
---
Partition Coefficient
No data available
Solubility In Water
No data available
Solubility In Fat
---
Molecular Weight
No data available
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not applicable
Kinematic Viscosity
Not applicable
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

Not classified as a reactivity hazard.

Hazardous reactions

Can react with strong oxidizing agents. If the temperature rises there is danger of the vessels bursting due to the high vapor pressure. Vapours may form explosive mixture with air. Extremely flammable aerosol. When heated to temperatures above 150 °C (300 °F) in the presence of air, product can form formaldehyde vapours.

Avoid

If the temperature rises there is danger of the vessels bursting due to the high vapor pressure. When heated to temperatures above 150 °C (300 °F) in the presence of air.

Incompatible

strong oxidizing agents

Decomposition

formaldehyde vapours

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% aromatics Acute toxicity to fish LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, > 10 - < 30 mg/l, OECD Test Guideline 203 Acute toxicity to aquatic invertebrates LC50, Daphnia magna (Water flea), 48 Hour, > 22 - < 46 mg/l, OECD Test Guideline 202 Acute toxicity to algae/aquatic plants EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, > 1,000 mg/l, OECD Test Guideline 201 NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, 1 mg/l, OECD Test Guideline 201

12.1 Toxicity

Acute toxicity to fish Information given is based on data obtained from similar substances. LC50, Leuciscus idus (Golden orfe), 96 Hour, > 10,000 mg/l, OECD Test Guideline 203 Acute toxicity to aquatic invertebrates Information given is based on data obtained from similar substances. EC50, Daphnia magna (Water flea), 48 Hour, > 100 mg/l, OECD Test Guideline 202 Acute toxicity to algae/aquatic plants NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, 100 mg/l, OECD Test Guideline 201 Chronic toxicity to aquatic invertebrates Based on data from similar materials NOEC, Daphnia magna (Water flea), 21 d, 10 mg/l

Acute toxicity to fish

No data available

No data available

Acute toxicity to aquatic invertebrates

No data available

No data available

Acute toxicity to algae/aquatic plants

No data available

No data available

12.1 Toxicity

Calcium hydroxide Acute toxicity to fish LC50, Gasterosteus aculeatus (threespine stickleback), 96 Hour, 457 mg/l, OECD Test Guideline 203 Acute toxicity to aquatic invertebrates EC50, 48 Hour, 158 mg/l, OECD Test Guideline 202 Acute toxicity to algae/aquatic plants EC50, Raphidocelis subcapitata (freshwater green alga), 72 Hour, 184.47 mg/l, OECD Test Guideline 201 NOEC, Raphidocelis subcapitata (freshwater green alga), 72 Hour, 48 mg/l, OECD Test Guideline 201 Toxicity to bacteria EC50, 3 Hour, 300.4 mg/l, OECD Test Guideline 209 Chronic toxicity to aquatic invertebrates NOEC, 14 d, 32 mg/l

12.1 Toxicity

### **12.1 Toxicity** ### **Molybdenum disulfide** ### **Acute toxicity to fish** Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). For similar material(s): LC50, Fish, 96 Hour, > 100 mg/l **Acute toxicity to aquatic invertebrates** Based on data from similar materials EC50, Daphnia magna (Water flea), 48 Hour, > 100 mg/l ### **Acute toxicity to algae/aquatic plants** Based on data from similar materials ErC50, algae, 72 Hour, Growth rate, > 100 mg/l ### **Toxicity to bacteria** EC50, 30 Hour, Respiration rates., > 100 mg/l **Chronic toxicity to fish** Based on data from similar materials NOEC, Fish, 34 d, > 10 mg/l **Chronic toxicity to aquatic invertebrates** Based on data from similar materials NOEC, Daphnia magna, 21 d, > 10 mg/l

12.1 Toxicity

Graphite Acute toxicity to fish No toxicity at the limit of solubility LC50, Danio rerio (zebra fish), 96 Hour, > 100 mg/l, OECD Test Guideline 203 Acute toxicity to aquatic invertebrates No toxicity at the limit of solubility EC50, Daphnia magna (Water flea), 48 Hour, > 100 mg/l, OECD Test Guideline 202 Acute toxicity to algae/aquatic plants EC50, Raphidocelis subcapitata (freshwater green alga), 72 Hour, > 100 mg/l, OECD Test Guideline 201 NOEC, Raphidocelis subcapitata (freshwater green alga), 72 Hour, >= 100 mg/l, OECD Test Guideline 201 Toxicity to bacteria EC50, 3 Hour, > 1,012.5 mg/l, OECD Test Guideline 209

12.2 Persistence and degradability

12.2 Persistence and degradability

Biodegradability: Readily biodegradable. Method: OECD Test Guideline 301

12.2 Persistence and degradability

Biodegradability: Not readily biodegradable. Information given is based on data obtained from similar substances. Biodegradation: 31 % Exposure time: 28 d Method: OECD Test Guideline 301F Theoretical Oxygen Demand: 3.50 mg/mg Photodegradation Test Type: Half-life (indirect photolysis) Sensitization: OH radicals Atmospheric half-life: 1.291 d Method: Estimated.

12.2 Persistence and degradability

propane Biodegradability: No data available Theoretical Oxygen Demand: 3.64 mg/mg Photodegradation Test Type: Half-life (indirect photolysis) Sensitization: OH radicals Atmospheric half-life: 8.4 d Method: Estimated.

12.2 Persistence and degradability

butane Biodegradability: Readily biodegradable. Biodegradation: 100 % Exposure time: 17 d Theoretical Oxygen Demand: 3.58 mg/mg Photodegradation Test Type: Half-life (indirect photolysis) Sensitization: OH radicals Atmospheric half-life: 49 Hour Method: Estimated.

12.2 Persistence and degradability

Molybdenum disulfide Biodegradability: Biodegradability is not applicable to inorganic substances. Graphite Biodegradability: Not applicable

12.3 Bioaccumulative potential

12.3 Bioaccumulative potential

12.3 Bioaccumulative potential

Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% aromatics Partition coefficient: n-octanol/water(log Pow): 1.99 - 5.25

12.3 Bioaccumulative potential

White mineral oil (petroleum) (viscosity < 20.5 cSt @ 40C) Bioaccumulation: Bioconcentration potential is high (BCF > 3000 or Log Pow between 5 and 7). Partition coefficient: n-octanol/water(log Pow): 5.18 Measured

12.3 Bioaccumulative potential

propane Bioaccumulation: Bioaccumulation is unlikely. Partition coefficient: n-octanol/water(log Pow): 1.815

12.3 Bioaccumulative potential

Bioaccumulation: Bioaccumulation is unlikely. Partition coefficient: n-octanol/water(log Pow): 2.31 at 20 °C

12.3 Bioaccumulative potential

Molybdenum disulfide: Partitioning from water to n-octanol is not applicable. Graphite: Not applicable Not applicable

12.4 Mobility in soil

Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% aromatics: No data available. White mineral oil (petroleum) (viscosity < 20.5 cSt @ 40C): Potential for mobility in soil is low (Koc between 500 and 2000). Koc : 510 Method : Estimated. propane: No data available. Calcium hydroxide: No data available. butane: No data available. Molybdenum disulfide: No relevant data found. Graphite: No relevant data found.

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% aromatics: This substance is not considered to be persistent, bioaccumulating and toxic (PBT). White mineral oil (petroleum) (viscosity < 20.5 cSt @ 40C): No data available propane: Not persistent, bioaccumulative, and toxic (PBT). Not very persistent and very bioaccumulative (vPvB). Calcium hydroxide: Not persistent, bioaccumulative, and toxic (PBT). Not very persistent and very bioaccumulative (vPvB). Not applicable to inorganic substances. butane: Not persistent, bioaccumulative, and toxic (PBT). Not very persistent and very bioaccumulative (vPvB). Molybdenum disulfide: Not persistent, bioaccumulative, and toxic (PBT). Not very persistent and very bioaccumulative (vPvB). Graphite: Not persistent, bioaccumulative, and toxic (PBT). Not very persistent and very bioaccumulative (vPvB). Not applicable to inorganic substances.

12.6 Other adverse effects

Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% aromatics: No relevant data found. White mineral oil (petroleum) (viscosity < 20.5 cSt @ 40C): This substance is not on the Montreal Protocol list of substances that deplete the ozone layer. propane: This substance is not on the Montreal Protocol list of substances that deplete the ozone layer. Calcium hydroxide: This substance is not on the Montreal Protocol list of substances that deplete the ozone layer. butane: This substance is not on the Montreal Protocol list of substances that deplete the ozone layer. Molybdenum disulfide: This substance is not on the Montreal Protocol list of substances that deplete the ozone layer. Graphite: This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

None of the listed substances are on the Montreal Protocol list of substances that deplete the ozone layer.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not dump into any sewers, on the ground, or into any body of water.

Disposal

Contact the authorized waste disposal services.

Waste Codes

The definitive assignment of this material to the appropriate EWC group and thus its proper EWC code will depend on the use that is made of this material. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1950
Shipping Name
AEROSOLS
Transport Class
2.1
Packing Group
Not applicable
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The following substance/s contained in this product is/are subject through Annex XVII of UK REACH regulation to restrictions on the manufacture, placing on the market and use when present in certain dangerous substances, mixtures and articles. Users of this product have to comply with the restrictions placed upon it by the aforementioned provision.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for MOLYKOTE® G-Rapid Plus Paste Spray?

The signal word is danger.

What is the physical form of MOLYKOTE® G-Rapid Plus Paste Spray?

MOLYKOTE® G-Rapid Plus Paste Spray is a aerosol with black color. It has solvent-like odor.

What is MOLYKOTE® G-Rapid Plus Paste Spray used for?

Lubricants and lubricant additives

What are the hazard statements for MOLYKOTE® G-Rapid Plus Paste Spray?

This substance has 5 hazard statements:

  • H222: Extremely flammable aerosol.
  • H229: Pressurised container: May burst if heated.
  • H318: Causes serious eye damage.
  • H336: May cause drowsiness or dizziness.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of MOLYKOTE® G-Rapid Plus Paste Spray?

The melting point is Melting point/ range: No data available and the boiling point is Boiling point/boiling range: Not applicable.