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Safety Data Sheet EN

Arsenic

CAS 7440-38-2
EC 231-148-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Arsenic
Product Code
1688

Regulatory Identifiers

CAS Number
7440-38-2 Check regulations →
EC Number
231-148-6 Check regulations →

Identified Uses

Industrial uses : Use of substance as such in preparations at industrial sites; Manufacture of basic metals, including alloys; Manufacture of bulk, large scale chemicals. Manufacture of fine chemicals

Uses advised against

No specific uses advised against are identified

Manufacturers & Suppliers

5N Plus Belgium SA logo

5N Plus Belgium SA

manufacturer

7 Rue de la Station, Tilly B-1495, Belgium

+32 (0) 7187 8821

http://www.5nplus.com

Emergency Contacts

CHEMTREC

1-800-424-9300

CHEMTREC

+1 703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 3 H331
Acute Tox. Cat. 3 H301
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410
Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318
Carc. Cat. 1A H350

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H301 + H331 Toxic if swallowed or if inhaled
H315 Causes skin irritation
H318 Causes serious eye damage
H350 May cause cancer.
H410 Very toxic to aquatic life with long lasting effects

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust, fume, gas, mist, vapours and/or spray.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Arsenic EC: 231-148-6 7440-38-2 99.9% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position. Get medical attention if symptoms occur.

Skin contact

Wash skin with soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Symptoms: skin irritation

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Symptoms: eye irritation

Ingestion

Get medical attention if symptoms occur. If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the lungs.

Immediate Medical Attention

If in doubt, GET MEDICAL ATTENTION PROMPTLY!

Medical Treatment

No recommendation given.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.

Unsuitable media

DO NOT use water if avoidable.

Specific hazards

Corrosive substances in contact with metals may produce flammable hydrogen gas.

Instructions

Confining and smothering metal fires is preferable rather than applying water.

Firefighter Protection

Fire fighters should wear complete protective clothing including self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Warn everybody of potential hazards and evacuate if necessary. Avoid breathing vapors, dust, or spray mist. Avoid contact with skin and eyes. Wear protective clothing as described in Section 8 of this safety data sheet. Avoid generation and spreading dust.

Environmental

Avoid discharge into drains, water courses or onto the ground. Dike and collect extinguishing water.

Cleanup methods

Collect powder using special dust vacuum cleaner with particle filter or carefully sweep into closed container.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid inhalation of dust and contact with skin and eyes. Avoid excessive heat for prolonged period of time. Do not handle broken packages without protective equipment.

Storage

Store in a cool, dry, well-ventilated place.

Hygiene

Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Change work clothing daily before leaving the work place. Wash contaminated clothing before reuse.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If operating conditions cause high dust concentrations to be produced, use dust goggles. Recommended ; safety glasses with side-shields.

Respiratory

In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended : acid proof clothing according to EN 14605 and protective boots according to EN20346.

Environmental

Avoid release to the environment. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Solid
Physical State Data
solid
State Under Standard Conditions
---
Appearance
Metallic solid.
Colour
Grey
Colour Intensity
---
Form
---
Odor
Odorless
Odor Threshold
---
Ph
---
Melting Point
270 C(518 F)
Boiling Point
---
Flash Point
---
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
---
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
4.9 g/mL @ 25 C(77 F)
Flammability
Classification criteria not met.
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Insoluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal temperatures and pressures.

Reactivity

No dangerous reaction known under conditions of normal use.

Hazardous reactions

Not revelant.

Avoid

Excess heat.

Incompatible

strong acids. strong oxidising substances.

Decomposition

When heated, vapours/gases hazardous to health may be formed.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

- Contains substance(s) that is classified as hazardous to the environment and may have an adverse effect.

12.2 Persistence and degradability

- The products solely consists of inorganic compounds which are not biodegradable.

12.3 Bioaccumulative potential

- Bioaccumulation is unlikely to be significant because of the low water solubility of this product.

12.4 Mobility in Soil

Not considered mobile but soluble compounds may be produced by acidic conditions.

The substance is not considered mobile, although acidic conditions may result in the formation of soluble compounds.

12.5 Results of PBT and vPvB assessment

The PBT and vPvB criteria of Annex XIII to regulation (EC) 1907/2006 does not apply to inorganic substances.

The PBT and vPvB criteria of Annex XIII to regulation (EC) 1907/2006 does not apply to inorganic substances.

12.6 Other adverse effects

No studies have been found.

No studies have been found.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Recover, reclaim or recycle if practical.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1558
Shipping Name
Arsenic
Transport Class
6.1
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Arsenic?

The signal word is danger.

What is the physical form of Arsenic?

Arsenic is a solid appearing as metallic solid. with grey color. It has odorless odor.

What is Arsenic used for?

Industrial uses : Use of substance as such in preparations at industrial sites; Manufacture of basic metals, including alloys; Manufacture of bulk, large scale chemicals. Manufacture of fine chemicals

What are the hazard statements for Arsenic?

This substance has 5 hazard statements:

  • H301 + H331: Toxic if swallowed or if inhaled
  • H315: Causes skin irritation
  • H318: Causes serious eye damage
  • H350: May cause cancer.
  • H410: Very toxic to aquatic life with long lasting effects

What is the melting point of Arsenic?

The melting point is 270 C(518 F) .