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Safety Data Sheet EN

Glycerol

CAS 56-81-5
EC 200-289-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Glycerol
Product Code
332030000, 332030010, 332030025, 332031000
Chemical Name
Glycerol
Synonyms
Glycerine

Regulatory Identifiers

CAS Number
56-81-5 Check regulations →
EC Number
200-289-5 Check regulations →
REACH No.
01-2119471987-18

Identified Uses

Laboratory chemicals.

Uses advised against

No Information available

Manufacturers & Suppliers

T

Thermo Fisher Scientific

manufacturer

Janssen Pharmaceuticalaan 3a, 2440 Geel, Belgium

F

Fisher Scientific UK

manufacturer

Bishop Meadow Road, Loughborough, Leicestershire LE11 5RG, United Kingdom

F

Fisher Scientific AG

distributor

Neuhofstrasse 11, CH 4153 Reinach

+41 (0) 56 618 41 11

Emergency Contacts

Emergency Contact

001-800-227-6701

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

Tox Info Suisse

145

24hr

Tox Info Suisse

+41-44 251 51 51

Chemtrec

0800 564 402

24h

Chemtrec

+41-43 508 20 11

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
1,2,3-Propanetriol EC: 200-289-5 56-81-5 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Get medical attention immediately if symptoms occur.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists: Get medical advice/attention.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Unsuitable media

No information available.

Specific hazards

Keep product and empty container away from heat and sources of ignition.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required.

Environmental

Should not be released into the environment.

Cleanup methods

Sweep up and shovel into suitable containers for disposal.

Materials: suitable containers

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid contact with skin, eyes or clothing. Avoid ingestion and inhalation.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. To maintain product quality, do not store in heat or direct sunlight. Protect from moisture. Do not freeze.

Hygiene

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.

Hands

Protective gloves. Glove material: Natural rubber, Nitrile rubber, Neoprene, PVC. Breakthrough time: See manufacturers recommendations. EU standard: EN 374. (minimum requirement).

Eyes

Wear safety glasses with side shields (or goggles) (European standard - EN 166)

Respiratory

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Large scale/emergency use: Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended Filter type: Particle filter. Small scale/Laboratory use: Maintain adequate ventilation.

Skin/Body

Long sleeved clothing.

Environmental

No information available.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Very viscous Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear
Colour
---
Colour Intensity
---
Form
---
Odor
Slight
Odor Threshold
No data available
Ph
5
Melting Point
18 °C / 64.4 °F
Boiling Point
290 °C / 554 °F
Flash Point
160 °C / 320 °F
Freezing Point
---
Softening Point
No data available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No information available
Vapor Pressure
0.003 mbar @ 50 °C
Vapor Density
3.17 (Air = 1.0)
Relative Density
---
Bulk Density
Not applicable
Density
1.261
Flammability
No data available
Upper Explosive Limit
19 vol %
Lower Explosive Limit
2.7 vol %
Explosive Limits
---
Auto Ignition Temperature
400 °C / 752 °F
Decomposition Temperature
>290°C
Solubility
---
Partition Coefficient
log Pow -1.75 (1,2,3-Propanetriol)
Solubility In Water
>500 g/L (20°C)
Solubility In Fat
---
Molecular Weight
92.09
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
1069 mPa.s at 20 °C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Hygroscopic.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. Hazardous Reactions: None under normal processing.

Avoid

Incompatible products. Excess heat.

Incompatible

Strong oxidizing agents.

Decomposition

Thermal decomposition can lead to release of irritating gases and vapors.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

| Component | Freshwater Fish | Water Flea | Freshwater Algae | | 1,2,3-Propanetriol | LC50: 51 - 57 mL/L, 96h static (Oncorhynchus mykiss) | | |

12.2. Persistence and degradability

Resistence Readily biodegradable Persistence Persistence is unlikely.

The substance is readily biodegradable and persistence is unlikely.

12.3. Bioaccumulative potential

Bioaccumulation is unlikely | Component | log Pow | Bioconcentration factor (BCF) | | --- | --- | --- |

Bioaccumulation is unlikely.

12.3. Bioaccumulative potential

| Component | log Pow | Bioconcentration factor (BCF) | | 1,2,3-Propanetriol | -1.75 | No data available |

12.4. Mobility in soil

The product is water soluble, and may spread in water systems. Will likely be mobile in the environment due to its water solubility. Highly mobile in soils

The product is water soluble and highly mobile in soils, with potential to spread in water systems.

12.5. Results of PBT and vPvB assessment

Substance is not considered persistent, bioaccumulative and toxic (PBT) / very persistent and very bioaccumulative (vPvB).

The substance is not considered to be PBT or vPvB.

12.6. Endocrine disrupting properties

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors

12.7. Other adverse effects

Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

Disposal

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste.

Waste Codes

Waste Codes are not product specific, but application specific. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Glycerol known by?

Glycerol is also known as: Glycerine

What is the hazard signal word for Glycerol?

The signal word is no signal word.

What is the physical form of Glycerol?

Glycerol is a very viscous liquid appearing as clear . It has slight odor.

What is Glycerol used for?

Laboratory chemicals.

What is the melting point of Glycerol?

The melting point is 18 °C / 64.4 °F and the boiling point is 290 °C / 554 °F.