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Safety Data Sheet EN

1,3-Dioxolane, stabilized

CAS 646-06-0
EC 211-463-5

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
1,3-Dioxolane, stabilized
Product Form
Substance
Chemical Name
1,3-Dioxolane, stabilized; 1,3-Dioxolane, Filtered
Synonyms
1,3-Dioxolane, Filtered

Regulatory Identifiers

CAS Number
646-06-0 Check regulations →
EC Number
211-463-5 Check regulations →
UFI Code
R3R0-G0C9-800X-0V7Y

Identified Uses

Intermediate

Uses advised against

None known

Manufacturers & Suppliers

B

Brewer Science, Inc.

manufacturer

2401 Brewer Drive, Rolla, MO 65401

(573) 364-0300

B

Brewer Science, Limited

distributor

North Mill, 2nd Floor, Darley Abbey Mills, Derby, England DE22 1DZ

+44 1332 545888

B

Brewer Science GmbH

distributor

Maximilianstraße 54, 80538 Munchen, Germany

+44 1332 545888

Emergency Contacts

CHEMTREC

1-800-424-9300

CHEMTREC

1-703-527-3887

Chemtrec UK

+(44)-870-8200418

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Eye Dam. Cat. 1 H318
Repr. Cat. 1B H360FD

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapour.
H318 Causes serious eye damage.
H360FD May damage fertility. May damage the unborn child.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P280 Wear eye protection, protective clothing.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P310 Immediately call a POISON CENTER or doctor.
P370 + P378 In case of fire: Use Dry chemical, CO2, alcohol-resistant foam or waterspray to extinguish.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
1,3-Dioxolane EC: 211-463-5 646-06-0 95% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove person to fresh air and keep comfortable for breathing. Get medical advice/attention.

Symptoms: May cause minor irritation to the respiratory tract and to other mucous membranes.

Skin contact

Gently wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse.

Symptoms: Repeated or prolonged skin contact may cause irritation.

Eye contact

Immediately flush thoroughly with water for at least 20 minutes, while holding the eye lids open to be sure the material is washed out. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention.

Symptoms: May cause severe eye irritation with possible eye damage.

Ingestion

Rinse mouth thoroughly with water. Get medical advice/attention if you feel unwell.

Symptoms: May cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Immediate Medical Attention

Immediate medical attention is required for eye contact.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO2, water spray or alcohol-resistant foam.

Unsuitable media

Do not use a heavy water stream.

Specific hazards

Highly flammable liquid and vapour. Vapours are heavier than air and may travel considerable distance to an ignition source and flash back to source of vapours. Prolonged exposure to fire may cause containers to rupture/explode.

Instructions

Cool down the containers exposed to heat with a water spray. Fight fire from safe distance and protected location. Do not enter fire area without proper protective equipment, including respiratory protection.

Firefighter Protection

Use self-contained breathing apparatus and chemically protective clothing. Do not attempt to take action without suitable protective equipment.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

General measures: Remove ignition sources. Stop leak if safe to do so. Keep unnecessary and unprotected personnel away from the spillage. Do not touch or walk on the spilled product. For non-emergency personnel: Avoid contact with eyes, skin and clothing. Avoid breathing mist, vapours. Ventilate spillage area. For emergency responders: Eliminate ignition sources. Evacuate unnecessary personnel.

Environmental

Avoid release to the environment.

Cleanup methods

Use non-sparking tools. Absorb and/or contain spill with inert material, then place in suitable container.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid contact with eyes, skin and clothing. Wear personal protective equipment. Avoid breathing mist, vapours. Use only outdoors or in a well-ventilated area. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Take precautionary measures against static discharge. Keep container closed when not in use.

Storage

Store in dry, cool, well-ventilated area. Keep away from ignition sources. Keep container tightly closed.

Hygiene

Do not eat, drink or smoke when using this product. Always wash hands after handling the product.

Fire prevention

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Take precautionary measures against static discharge.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use with adequate general or local exhaust ventilation to maintain exposure levels below the occupational exposure limits. Use explosion-proof equipment.

Hands

In case of repeated or prolonged contact wear gloves. Wear suitable gloves tested to EN374. Contact your glove supplier for selection assistance.

Eyes

Wear safety goggles or other eye protection to prevent eye contact. Use eye protection according to EN 166.

Respiratory

In operations where exposure limits are exceeded or exposure levels are excessive, an approved respirator should be used. Respirator selection and use should be based on contaminant type, form and concentration. Follow applicable regulations and good Industrial Hygiene practice.

Skin/Body

Wear suitable protective clothing. EN 13034

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Clear, colorless liquid.
Colour
Colourless.
Colour Intensity
---
Form
---
Odor
Odourless.
Odor Threshold
Not available
Ph
Not available
Melting Point
Not applicable
Boiling Point
75 – 76 °C (167-169°F) (1,3-Dioxolane)
Flash Point
-3 °C (27°F) (1,3-Dioxolane)
Freezing Point
-95 °C (-139°F) (1,3-Dioxolane)
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
Not available
Vapor Density
---
Relative Density
Not available
Bulk Density
---
Density
1.06 g/cm³ (25°C/77°F)
Flammability
Highly flammable liquid and vapour.
Upper Explosive Limit
Not available
Lower Explosive Limit
Not available
Explosive Limits
---
Auto Ignition Temperature
250 °C (482°F) (1,3-Dioxolane)
Decomposition Temperature
Not available
Solubility
Soluble in water.
Partition Coefficient
0.37
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Not available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

No dangerous reactions known under normal conditions of use. 1, 3- Dioxolane can have a potentially explosive reaction with lithium perchlorate.

Avoid

Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

lithium perchlorate

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.2. Persistence and degradability

12.2. Persistence and degradability

No additional information available.

No additional information available.

12.2. Persistence and degradability

No appreciable biodegradation is expected.

No appreciable biodegradation is expected.

12.3. Bioaccumulative potential

12.3. Bioaccumulative potential

Partition coefficient n-octanol/water (Log Pow) 0.37

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Endocrine disrupting properties

No additional information available

12.7. Other adverse effects

No additional information available

12.1. Toxicity

Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. Hazardous to the aquatic environment, short-term (acute) : Not classified (Based on available data, the classification criteria are not met) Hazardous to the aquatic environment, long-term (chronic) : Not classified (Based on available data, the classification criteria are not met)

The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment.

12.1. Toxicity

| 1,3-Dioxolane (646-06-0) | | | --- | --- | | LC50 - Fish [1] | > 95.4 mg/l Lepomis macrochirus (Bluegill) | | EC50 - Crustacea [1] | > 772 mg/l Daphnia magna (Water flea) | | EC50 72h - Algae [1] | > 877 mg/l Pseudokirchneriella subcapitata | | NOEC (chronic) | 197.4 mg/l Daphnids | | NOEC chronic fish | 546.3 mg/l (QSAR) |
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose in a safe manner in accordance with local/national regulations.

Disposal

Flammable vapours may accumulate in the container. Do not re-use empty containers. Disposal must be done according to official regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1166
Shipping Name
DIOXOLANE
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The substance is not listed on REACH Annex XVII, REACH Annex XIV, the REACH Candidate List (SVHC), the PIC list, the POP list, the Ozone Depletion list, or lists for explosive and drug precursors.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is 1,3-Dioxolane, stabilized known by?

1,3-Dioxolane, stabilized is also known as: 1,3-Dioxolane, Filtered

What is the hazard signal word for 1,3-Dioxolane, stabilized?

The signal word is danger.

What is the physical form of 1,3-Dioxolane, stabilized?

1,3-Dioxolane, stabilized is a liquid appearing as clear, colorless liquid. with colourless. color. It has odourless. odor.

What is the solubility of 1,3-Dioxolane, stabilized?

Soluble in water.

What is 1,3-Dioxolane, stabilized used for?

Intermediate

What are the hazard statements for 1,3-Dioxolane, stabilized?

This substance has 3 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H318: Causes serious eye damage.
  • H360FD: May damage fertility. May damage the unborn child.

What is the melting point of 1,3-Dioxolane, stabilized?

The melting point is Not applicable and the boiling point is 75 – 76 °C (167-169°F) (1,3-Dioxolane).