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Safety Data Sheet EN

TMGa SSG

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
TMGa SSG

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Specific use(s): Semiconductors Solar cells

Manufacturers & Suppliers

A

Akzo Nobel Functional Chemicals B.V.

manufacturer

Stationsstraat 77 NL 3811 MH Amersfoort Netherlands

+31334676767

Emergency Contacts

AkzoNobel

+31 57 06 79211

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Pyr. Liq. Cat. 1 H250
Water-react. Cat. 1 H260
Skin Corr. Cat. 1A H314

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

Hazard Statements

H250 Catches fire spontaneously if exposed to air.
H260 In contact with water releases flammable gases which may ignite spontaneously.
H314 Causes severe skin burns and eye damage.

Precautionary Statements

P231 + P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302 + P334 IF ON SKIN: Immerse in cool water/ wrap in wet bandages.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370 + P378 In case of fire: Use vermiculite, dry chemical powder or dry sand for extinction.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Trimethylgallium EC: 215-897-6 1445-79-0 99.9999 - 100% Yes

Notes

Trimethylgallium, neat

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. Consult a physician after significant exposure.

Skin contact

Take off contaminated clothing and shoes immediately. Rinse immediately with plenty of water. Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty.

Symptoms: untreated wounds from corrosion of the skin

Eye contact

Rinse with plenty of water. Get medical attention immediately. Continue to rinse during transport. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing.

Symptoms: Small amounts splashed into eyes can cause irreversible tissue damage and blindness.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Take victim immediately to hospital. Do not induce vomiting!

Symptoms: May cause chemical burns in mouth and throat.

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

In case of fire: Use vermiculite, dry chemical powder or dry sand for extinction.

Unsuitable media

Water, Foam, Carbon dioxide (CO2)

Specific hazards

CAUTION: reignition may occur. Waterspray may only be used by experienced fire fighters.

Firefighter Protection

Wear self-contained breathing apparatus and protective suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment. Ensure adequate ventilation. Ignition will occur. Allow controlled hydrolysis. Stop leak if safe to do so. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.

Environmental

Prevent product from entering drains.

Cleanup methods

collect with non-combustible absorbent material and place in container for disposal according to local / national regulations (see section 13). Ensure that the product is completely non-reactive before cleaning up.

Materials: non-combustible absorbent material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Handle and open container with care.

Storage

Keep container tightly closed in a dry and well-ventilated place. Keep under nitrogen.

Hygiene

Smoking, eating and drinking should be prohibited in the application area.

Fire prevention

Keep away from sources of ignition - No smoking. No sparking tools should be used. Do not cut or weld on or near this container even when empty.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Effective exhaust ventilation system. Ensure that eyewash stations and safety showers are close to the workstation location.

Hands

Heavy PVC or leather (cowhide); both with long gauntlets.

Eyes

Safety glasses and face-shield

Respiratory

In the case of vapour or aerosol formation use a respirator with an approved filter. Filter AX

Skin/Body

Aluminised suit and protective boots. For further advice contact manufacturer.

Environmental

Prevent product from entering drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
clear, colourless
Colour
clear, colourless
Colour Intensity
---
Form
liquid
Odor
not significant
Odor Threshold
No data available
Ph
No data available
Melting Point
-16 °C
Boiling Point
56 °C
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available
Vapor Pressure
85 hPa at 32 °C
Vapor Density
---
Relative Density
1.151 at 15 °C
Bulk Density
Not applicable
Density
---
Flammability
Not applicable
Upper Explosive Limit
Not applicable
Lower Explosive Limit
Not applicable
Explosive Limits
---
Auto Ignition Temperature
Catches fire spontaneously if exposed to air.
Decomposition Temperature
To avoid thermal decomposition, do not overheat.
Solubility
---
Partition Coefficient
Not applicable
Solubility In Water
Reacts violently with water.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
No data available
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

To avoid thermal decomposition, do not overheat.

Reactivity

Stable under normal conditions.

Hazardous reactions

Reacts violently with water.

Avoid

do not overheat

Incompatible

Avoid contact with moisture and water, alcohols, acids, organic halides and oxygen containing compounds.

Decomposition

thermal decomposition

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

12.2 Persistence and degradability

Product information : No information available. Components : No information available.

12.3 Bioaccumulative potential

Product information : No information available. Components : No information available.

12.4 Mobility in soil

Product information : No information available. Components : No information available.

12.5 Results of PBT and vPvB assessment

Product information: PBT and vPvB assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Other adverse effects

Product information : No information available. Components : No information available.

No information available.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container.

Disposal

Dispose of contents/container in accordance with local regulation.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3394
Shipping Name
ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE (Trimethylgallium)
Transport Class
4.2 (4.3)
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for TMGa SSG?

The signal word is danger.

What is the physical form of TMGa SSG?

TMGa SSG is a liquid appearing as clear, colourless with clear, colourless color. It has not significant odor.

What is TMGa SSG used for?

Specific use(s): Semiconductors Solar cells

What are the hazard statements for TMGa SSG?

This substance has 3 hazard statements:

  • H250: Catches fire spontaneously if exposed to air.
  • H260: In contact with water releases flammable gases which may ignite spontaneously.
  • H314: Causes severe skin burns and eye damage.

What is the melting point of TMGa SSG?

The melting point is -16 °C and the boiling point is 56 °C.