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Safety Data Sheet EN

Glycolic acid

CAS 79-14-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Glycolic acid
Product Code
124737
Chemical Name
Glycolic acid

Regulatory Identifiers

CAS Number
79-14-1 Check regulations →

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

S

Sigma-Aldrich Chemie GmbH

manufacturer

Eschenstrasse 5, D-82024 TAUFKIRCHEN

+49 (0)89 6513-1130

Emergency Contacts

CHEMTREC Deutschland

0800 181 7059

CHEMTREC weltweit

+49 (0)696 43508409

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H332
Skin Corr. Cat. 1B H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.

Precautionary Statements

P260 Do not breathe dusts or mists.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Glycolic acid EC: 201-180-5 79-14-1 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

Rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

Make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Immediate Medical Attention

Immediately call in physician or ophthalmologist.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water, Foam, Carbon dioxide (CO2), Dry powder

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating.

Instructions

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up dry. Clean up affected area.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Work under hood. Do not inhale substance/mixture.

Storage

Tightly closed. Dry.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Material: Nitrile rubber, Minimum layer thickness: 0,11 mm, Break through time: 480 min, Material tested: KCL 741 Dermatril® L

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P2. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Acid-resistant protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
crystalline
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
colorless
Colour Intensity
---
Form
---
Odor
No data available
Odor Threshold
---
Ph
2 at 50 g/l at 20 °C
Melting Point
75 - 80 °C
Boiling Point
169 °C at 998 hPa - OECD Test Guideline 103
Flash Point
> 300 °C - (decomposition)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
0,0041 hPa at 25 °C - OECD Test Guideline 104
Vapor Density
---
Relative Density
No data available
Bulk Density
---
Density
1,26 g/cm³ at 20 °C - OECD Test Guideline 109
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
No data available
Decomposition Temperature
No data available
Solubility
Methanol > 1,402 g/l at 22 °C - OECD Test Guideline 105
Partition Coefficient
log Pow: < 0,3 at 25 °C - OECD Test Guideline 117 - n-octanol/water Bioaccumulation is not expected.
Solubility In Water
300 g/l at 22 °C - OECD Test Guideline 105
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available
Kinematic Viscosity
6,149 mm²/s at 23 °C - OECD Test Guideline 114
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.

Hazardous reactions

Violent reactions possible with: Oxidizing agents, Reducing agents, Bases, Cyanides, Sulfides

Avoid

Strong heating.

Incompatible

Gives off hydrogen by reaction with metals.

Decomposition

In the event of fire: see section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Toxicity to fish: semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - > 100 mg/l - 96 h (OECD Test Guideline 203) Toxicity to daphnia and other aquatic invertebrates: semi-static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h (OECD Test Guideline 202) Toxicity to algae: static test ErC50 - Pseudokirchneriella subcapitata - > 100 mg/l - 72 h (OECD Test Guideline 201) Toxicity to bacteria: static test NOEC - activated sludge - 100 mg/l - 3 h (OECD Test Guideline 209) Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity): semi-static test NOEC - Daphnia magna (Water flea) - >= 89,6 mg/l - 21 d (OECD Test Guideline 211)

12.2 Persistence and degradability

Biodegradability: aerobic - Exposure time 28 d Result: 83,9 % - Readily biodegradable. (OECD Test Guideline 310)

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Endocrine disrupting properties

Assessment: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.7 Other adverse effects

May be harmful to aquatic organisms due to the shift of the pH. Avoid release to the environment.

May be harmful to aquatic organisms due to the shift of the pH.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

Disposal

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3261
Shipping Name
CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (Glycolic acid)
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Glycolic acid?

The signal word is danger.

What is the physical form of Glycolic acid?

Glycolic acid is a crystalline with colorless color. It has no data available odor.

What is the solubility of Glycolic acid?

Methanol > 1,402 g/l at 22 °C - OECD Test Guideline 105

What is Glycolic acid used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for Glycolic acid?

This substance has 2 hazard statements:

  • H314: Causes severe skin burns and eye damage.
  • H332: Harmful if inhaled.

What is the melting point of Glycolic acid?

The melting point is 75 - 80 °C and the boiling point is 169 °C at 998 hPa - OECD Test Guideline 103.