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Safety Data Sheet EN

Hydrogen peroxide ROTIPURAN® 30 %, p.a., ISO, stabilized

CAS 7722-84-1
EC 231-765-0

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hydrogen peroxide ROTIPURAN® 30 %, p.a., ISO, stabilized
Product Code
8070
Chemical Name
Hydrogen peroxide

Regulatory Identifiers

CAS Number
7722-84-1 Check regulations →
EC Number
231-765-0 Check regulations →

Identified Uses

Laboratory chemical Laboratory and analytical use

Uses advised against

Do not use for products which come into contact with foodstuffs. Do not use for private purposes (household).

Manufacturers & Suppliers

Carl Roth GmbH + Co KG logo

Carl Roth GmbH + Co KG

manufacturer

Schoemperlenstr. 3-5, D-76185 Karlsruhe

+49 (0) 721 - 56 06 0

http://www.carlroth.de

Emergency Contacts

National Poisons Information Service City Hospital

844 892 0111

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H332
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H302 + H332 Harmful if swallowed or if inhaled
H318 Causes serious eye damage

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 IF ON SKIN: Wash with plenty of water
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER/doctor

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Hydrogen peroxide solution ... % EC: 231-765-0 7722-84-1 25 - 35% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.

Symptoms: Cough, Dyspnoea

Skin contact

Rinse skin with water/shower. In all cases of doubt, or when symptoms persist, seek medical advice.

Symptoms: Irritant effects

Eye contact

In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist.

Symptoms: Conjunctivitis (pink eye), Risk of serious damage to eyes, Risk of blindness

Ingestion

Rinse mouth with water (only if the person is conscious). Call a doctor.

Symptoms: Nausea, Vomiting, Diarrhoea, Vertigo, Spasms, Unconsciousness

Immediate Medical Attention

In all cases of doubt, or when symptoms persist, seek medical advice.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

co-ordinate firefighting measures to the fire surroundings, water spray, foam, dry extinguishing powder

Unsuitable media

water jet, carbon dioxide (CO₂)

Specific hazards

Oxidising property. The product itself does not burn.

Instructions

Fight fire with normal precautions from a reasonable distance.

Firefighter Protection

In case of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not breathe vapour/spray.

Environmental

Keep away from drains, surface and ground water.

Cleanup methods

Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).

Materials: sand, diatomaceous earth, acid- or universal binding agents

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

No special measures are necessary.

Storage

Keep only in original container. Protect from sunlight. Do not keep the container sealed.

Hygiene

Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. The times are approximate values from measurements at 22°C and permanent contact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effective layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred to substance mixtures, they may only be considered as a guide. Type of material: Butyl caoutchouc (butyl rubber). Material thickness: ≥ 0,3 mm. Breakthrough times of the glove material: >480 minutes (permeation: level 6).

Eyes

Use safety goggle with side protection.

Respiratory

Respiratory protection necessary at: Aerosol or mist formation. Type: B-P2 (combined filters for acidic gases and particles, colour code: Grey/White). Type: ABEK (combined filters against gases and vapours, colour code: Brown/Grey/Yellow/Green).

Skin/Body

Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended.

Environmental

Keep away from drains, surface and ground water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
colourless
Colour Intensity
---
Form
---
Odor
faintly perceptible
Odor Threshold
---
Ph
2 – 4 (20 °C)
Melting Point
-26 °C
Boiling Point
107 °C
Flash Point
not determined
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
18 hPa at 20 °C
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1,11 g/cm³
Flammability
non-combustible
Upper Explosive Limit
not determined
Lower Explosive Limit
not determined
Explosive Limits
---
Auto Ignition Temperature
not determined
Decomposition Temperature
>100 °C
Solubility
---
Partition Coefficient
-1,57 (calc.)
Solubility In Water
miscible in any proportion
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
1,08 mPa s at 20 °C
Kinematic Viscosity
0,973 mm²/s at 20 °C
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

May cause decomposition by long-term light influence.

Reactivity

This material is not reactive under normal ambient conditions.

Hazardous reactions

Violent reaction with: Acetone, Aldehydes, Alkalis, Alkali hydroxide (caustic alkali), Alkali metals, Alcohols, Amines, Ammonia (NH3), Aniline, Lead, Lead oxide, Alkaline earth metal, Acetic acid, Acetic anhydride, Ether, Hydrazine, Metals, Metal powder, Sodium, Organic substances, Permanganates, Phosphorus, Phosphorus oxides (e.g. P2O5), Reducing agents, Nitric acid, Sulphuric acid, Heavy metals, => Explosive properties

Avoid

Keep away from heat.

Incompatible

Acetone, Aldehydes, Alkalis, Alkali hydroxide (caustic alkali), Alkali metals, Alcohols, Amines, Ammonia (NH3), Aniline, Lead, Lead oxide, Alkaline earth metal, Acetic acid, Acetic anhydride, Ether, Hydrazine, Metals, Metal powder, Sodium, Organic substances, Permanganates, Phosphorus, Phosphorus oxides (e.g. P2O5), Reducing agents, Nitric acid, Sulphuric acid, Heavy metals

Decomposition

Decomposition takes place from temperatures above: >100 °C.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Shall not be classified as hazardous to the aquatic environment. Aquatic toxicity (acute) of components of the mixture | Name of sub-stance | CAS No | Endpoint | Value | Species | Exposure time | | --- | --- | --- | --- | --- | --- |

Shall not be classified as hazardous to the aquatic environment.

12.1 Toxicity

| Name of sub-stance | CAS No | Endpoint | Value | Species | Exposure time | | --- | --- | --- | --- | --- | --- | | Hydrogen peroxide solution ... % | 7722-84-1 | LC50 | 16,4 mg/l | fish | 96 h | | Hydrogen peroxide solution ... % | 7722-84-1 | ErC50 | 1,38 mg/l | algae | 72 h |

12.1 Toxicity

| Name of sub-stance | CAS No | Endpoint | Value | Species | Exposure time | | --- | --- | --- | --- | --- | --- | | Hydrogen peroxide solution ... % | 7722-84-1 | EC50 | 466 mg/l | microorganisms | 30 min |

12.2 Persistence and degradability

Not provided

12.3 Bioaccumulative potential

Not provided

12.4 Mobility in soil

Not provided

12.5 Results of PBT and vPvB assessment

Not provided

12.6 Endocrine disrupting properties

Not provided

12.7 Other adverse effects

Not provided

12.2 Persistence and degradability

Data are not available.

12.3 Bioaccumulative potential

Does not significantly accumulate in organisms.

12.4 Mobility in soil

Data are not available.

12.5 Results of PBT and vPvB assessment

Data are not available.

12.6 Endocrine disrupting properties

Does not contain an endocrine disruptor (EDC) in a concentration of ≥ 0,1%.

12.7 Other adverse effects

Data are not available.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of contents/container in accordance with local/regional/national/international regulations.

Disposal

This material and its container must be disposed of as hazardous waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2014
Shipping Name
HYDROGEN PEROXIDE, AQUEOUS SOLUTION
Transport Class
5.1 (8)
Packing Group
II
ADR

Provisions for dangerous goods (ADR) should be complied within the premises.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hydrogen peroxide ROTIPURAN® 30 %, p.a., ISO, stabilized?

The signal word is danger.

What is the physical form of Hydrogen peroxide ROTIPURAN® 30 %, p.a., ISO, stabilized?

Hydrogen peroxide ROTIPURAN® 30 %, p.a., ISO, stabilized is a liquid with colourless color. It has faintly perceptible odor.

What is Hydrogen peroxide ROTIPURAN® 30 %, p.a., ISO, stabilized used for?

Laboratory chemical Laboratory and analytical use

What are the hazard statements for Hydrogen peroxide ROTIPURAN® 30 %, p.a., ISO, stabilized?

This substance has 2 hazard statements:

  • H302 + H332: Harmful if swallowed or if inhaled
  • H318: Causes serious eye damage

What is the melting point of Hydrogen peroxide ROTIPURAN® 30 %, p.a., ISO, stabilized?

The melting point is -26 °C and the boiling point is 107 °C.